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Abstract
This paper studies the acoustical properties of multicomponent solutions (sucrose-citric acid-water). The ultrasonic velocities of the ternary solution have been measured at different concentrations at 40 ºC. The experimental values of ultrasonic velocity have been utilized to calculate other acoustical parameters such as the adiabatic compressibility, acoustic impedance, molar sound velocity, intermolecular free length, apparent molar and molar sound compressibilities. The ultrasonic velocities of the multicomponent solutions increase with the increase in the concentration of its any individual component. The value of acoustical parameters also increases with the increase in total molarity of the ternary solutions.
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References
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References
K. Rajathi, S. J. Askar Ali and A. Rajendran, Ultrasonic Study of Molecular Dynamics in Some Binary Mixtures, J. Chem. Pharm. Res., 3, 348 (2011).
P.S. Nikam, T.R. Mahale and M. Hasan, Ultrasonic Study of Alkanols (C1–C4) in Binary Mixtures containing Ethyl Acetate as Common Component, Acustica Acta Acoust., 84, 579 (1998).
P.S. Nikam, M.C. Jadhav and M. Hasan, Volumetric, Viscometric and Ultrasonic Behaviour of Dimethyl Sulfoxide with Normal Alcohols (C1-C4) at 308.15 K, J. Mol. Liq., 76, 1 (1998);
https://doi.org/10.1016/S0167-7322(97)00051-2
L. Palaniappan, Ultrasonic Analysis of Intermolecular Interaction in the Mixtures of Benzene with Methanol, Ethanol, 1-propanol, Asian J. Mater. Sci., 4, 21 (2012); https://doi.org/10.3923/ajmskr.2012.21.27
V. Rajendran, Volumetric, Viscometric and Ultrasonic Behaviour of
n-Heptane with Isomeric Alcohols at 298.15 K, Indian J. Pure and Appl. Phys., 34, 52 (1996).
G.G. Rao, M.V.K. Mehar, K.V. Prasad, K. Samatha, Ultrasonic Studies and Excess Properties of Binary Mixtures of Ethylmethylketone and Chlorobenzene at 308.15K, Inter. J. Innov. Res. Sci., Eng. Technol., 4, 5512 (2015).
P.S. Nikam, B.S. Jagdale, A.B. Sawant and M. Hasan, Densities and Viscosities for Binary Mixtures of Benzonitrile with Methanol, Ethanol, Propan-1-ol, Butan-1-ol, Pentan-1-ol and 2-Methylpropan-2-ol at (303.15, 308.15, and 313.15) K, J. Chem. Eng. Data, 45, 214 (2000); https://doi.org/10.1021/je990237e
D. Geetha and C. Rakkappan, Ultrasonic Studies on Solutions of Hydroxy Propyl Methyl Cellulose Phthalate in Alcohols and Acetone Mixture, Indian J. Phys., 77B, 519 (2003).
W.R. Moore and M.A. Uddin, Dilute Solution Properties of Bisphenol a Polycarbonate-III: Adiabatic Compressibility of Polymer Solutions, Eur. Polym. J., 6, 547 (1970); https://doi.org/10.1016/0014-3057(70)90123-0
J.E. Enderby and G.W. Neilson, Rep. Prog. Phys., 44, 593 (1981); https://doi.org/10.1088/0034-4885/44/6/001
A. Soto, A. Arce and M.K. Khoshkbarchi, Biophys. Chem., 76, 73 (1999); https://doi.org/10.1016/s0301-4622(98)00223-3
S. Mirikar, P.P. Pawar and G.K. Bichile, Excess Thermodynamical Properties of Electrolytes Solution with Aqueous Amino Acids at 303.15, 308.15 and 313.15 K, J. Chem. Pharm. Res., 5, 51 (2013).