Growth, Thermal and Spectroscopic Studies of Bis-thiourea Nickel Barium Chloride Single Crystals

Rakesh R. Hajiyani; Chetankumar K. Chauhan; Mihir J. Joshi

doi:10.14233/ajchem.2018.20869

Issue

Vol. 30 No. 2 (2018): Vol 30 Issue 2

Issue Published : December 31, 2017

This work is licensed under a Creative Commons Attribution 4.0 International License.

Growth, Thermal and Spectroscopic Studies of Bis-thiourea Nickel Barium Chloride Single Crystals

https://doi.org/10.14233/ajchem.2018.20869

Rakesh R. Hajiyani

Crystal Growth Laboratory, Department of Physics, Saurashtra University, Rajkot-360 005, India

Chetankumar K. Chauhan

Department of Physics, Government Science College, Sector-15, Gandhinagar-382 016, India

Mihir J. Joshi

Crystal Growth Laboratory, Department of Physics, Saurashtra University, Rajkot-360 005, India

Corresponding Author(s) : Rakesh R. Hajiyani

hajiyanirakesh@gmail.com

Asian Journal of Chemistry, Vol. 30 No. 2 (2018): Vol 30 Issue 2
Article Published : December 31, 2017

Abstract

Bis-thiourea nickel barium chloride was synthesized and crystals were grown by slow aqueous solvent evaporation technique. The powder XRD analysis of grown crystal was suggested to have orthorhombic crystal structure. The unit cell parameters of grown crystal as: a = 9.70 Å, b = 10.68 Å and c = 17.95 Å. The contents of nickel and barium in the grown crystals was analyzed using EDAX. The presence of various functional groups was confirmed by FTIR spectroscopy studies. From the UV-visible spectrum, the material has about 90 % optical transparency in the entire visible region. From the thermogravimetric analysis, it was found that the crystals remained stable up to 170 ºC. The endothermic reactions were identified from the differential thermal analysis.

Keywords

Bis-thiourea nickel barium chloride Crystal growth Slow evaporation technique Powder X-ray diffraction

Hajiyani, R. R., Chauhan, C. K., & Joshi, M. J. (2017). Growth, Thermal and Spectroscopic Studies of Bis-thiourea Nickel Barium Chloride Single Crystals. Asian Journal of Chemistry, 30(2), 257–259. https://doi.org/10.14233/ajchem.2018.20869

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References

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References

J.P. Morrall, G.T. Dalton, M.G. Humphery and M. Samoc, in eds.: R. West, A.F. Hill and M.J. Fink, Advances in Organometallic Chemistry, Academic Press, Orlando, edn 1, p. 6 (2011).

X.Q. Wang, J.G. Zhang, D. Xu, M.K. Lu, D.R. Yuan, S.X. Xu, J. Huang, G.H. Zhang, S.Y. Guo, S.L. Wang, X. Duan, Q. Ren and G. Lu, J. Cryst. Growth, 235, 340 (2002); https://doi.org/10.1016/S0022-0248(01)01811-5.

P.M. Ushasree, R. Muralidharan, R. Jayavel and P. Ramasamy, J. Cryst. Growth, 218, 365 (2000); https://doi.org/10.1016/S0022-0248(00)00593-5.

K. Selvaraju, R. Valluvan and S. Kumararaman, Mater. Lett., 61, 751 (2007); https://doi.org/10.1016/j.matlet.2006.05.054.

P. Sagayaraj and S. Selvakumar, J. Mater. Sci. Mater. Electron., 20(S1), 299 (2009); https://doi.org/10.1007/s10854-008-9592-6.

V. Venkataramanan, S. Maheswaran, J.N. Sherwood and H.L. Bhat, J. Cryst. Growth, 179, 605 (1997); https://doi.org/10.1016/S0022-0248(97)00137-1.

L.R. Nirmala and J.T.J. Prakash, Spectrochim. Acta A Mol. Biomol. Spectrosc., 110, 249 (2013); https://doi.org/10.1016/j.saa.2013.03.050.

R.R. Hajiyani, D.J. Dave, C.K. Chauhan, P.M. Vyas and M.J. Joshi, Mod. Phys. Lett. B, 24, 735 (2010); https://doi.org/10.1142/S0217984910022810.

C. Ramachandraraja, A.A. Joseph, R.S. Sundararajan, V.S. Shankar and P. Murugakoothan, Spectrochim. Acta A Mol. Biomol. Spectrosc., 74, 1005 (2009); https://doi.org/10.1016/j.saa.2009.07.007.

M.M. Kumari, P.I. Ramachandran, C. Ravikumar, I.H. Joe and I. Nemec, J. Raman Spectrosc., 42, 1462 (2011); https://doi.org/10.1002/jrs.2854.

K. Nakamoto, IR Spectra of Inorganic and Coordination Compounds Wiley & Sons, New York, edn 2 (1978).

Issue

Vol. 30 No. 2 (2018): Vol 30 Issue 2

Growth, Thermal and Spectroscopic Studies of Bis-thiourea Nickel Barium Chloride Single Crystals

Corresponding Author(s) : Rakesh R. Hajiyani

Abstract

Keywords

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