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Chemical Constituents of Exoecaria agallocha Linn.
Corresponding Author(s) : Consolacion Y. Ragasa
Asian Journal of Chemistry,
Vol. 31 No. 2 (2019): Vol. 31 No. 2
Abstract
Chemical investigation of the dichloromethane extracts of the mangrove, Exoecaria agallocha Linn. has led to the isolation of alkyl ferulates (1), lupeol (2), a mixture of 3-epi-α-amyrin (3) and 3-epi-β- amyrin (4) in about 2:3 ratio, and agallochaol K (5) from the bark; taraxerol (6), epi-taraxerol (7) and chlorophyll a from the leaves; and a mixture of compounds 3 and 4 in about 1:2 ratio, squalene, olean-12-en-3-one (8) and fully epoxidized linoleic acid from the twigs. The structures of compounds 5 and 7 were elucidated by extensive 1D and 2D NMR spectroscopy and confirmed by comparison of their NMR data with those reported in the literature. The structures of the other compounds were identified by comparison of their NMR data with literature data.
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- Buta-buta, Excoecaria Agallocha Linn., BLINDING TREE, Hai qi Downloaded from www.stuartxchange.com/Buta-buta.html on September 10, 2018.
- W.-H. Lin and Q.-S. Li, Chin. Tradit. Herbal Drugs, 40, 1704 (2009).
- T.M. Tran, T.H. Tran, T.T.H. Dinh and D.T. Vu, Malaysian J. Chem., 17, 20 (2015).
- J.-H. Zou, J. Dai, X. Chen and J.-Q. Yuan, Chem. Pharm. Bull. (Tokyo), 54, 920 (2006); https://doi.org/10.1248/cpb.54.920.
- M.-Q. Tian, G.-M. Bao, N.-Y. Ji, X.-M. Li and B.-G. Wang, China J. Chin. Materia Med., 33, 405 (2008).
- M. Gowri Ponnapalli, M. Ankireddy, S.C.A. Rao Annam, S. Ravirala, S. Sukki and V.R. Tuniki, Tetrahedron Lett., 54, 2942 (2013); https://doi.org/10.1016/j.tetlet.2013.03.105.
- T. Konishi, K. Yamazoe, T. Konoshima and Y. Fujiwara, Phytochemistry, 64, 835 (2003); https://doi.org/10.1016/j.phytochem.2003.09.001.
- Z.C. Wang, Y.M. Lin, D.Q. Feng, C.H.H. Ke, P. Lin, C.L. Yan and J.D. Chen, Molecules, 14, 414 (2009); https://doi.org/10.3390/molecules14010414.
- A.S.R. Anjaneyulu and V. Lakshmana Rao, Phytochemistry, 62, 585 (2003); https://doi.org/10.1016/S0031-9422(02)00269-8.
- T. Konishi, T. Konoshima, Y. Fujiwara, S. Kiyosawa, K. Miyahara and M. Nishi, Chem. Pharm. Bull. (Tokyo), 47, 456 (1999); https://doi.org/10.1248/cpb.47.456.
- J. Kang, R.Y. Chen and D.Q. Yu, J. Asian Nat. Prod. Res., 7, 729 (2005); https://doi.org/10.1080/1028602042000324943.
- T. Konishi, M. Takasaki, H. Tokuda, S. Kiyosawa and T. Konoshima, Biol. Pharm. Bull., 21, 993 (1998); https://doi.org/10.1248/bpb.21.993.
- T. Konishi, K. Yamazoe, T. Konoshima, T. Maoka, Y. Fujiwara and K. Miyahara, J. Nat. Prod., 66, 108 (2003); https://doi.org/10.1021/np020321j.
- Y. Li, J. Liu, S. Yu, P. Proksch, J. Gu and W. Lin, Phytochemistry, 71, 2124 (2010); https://doi.org/10.1016/j.phytochem.2010.08.011.
- C.Y. Ragasa, O.B. Torres, J.M.P. Gutierrez, H.P.B.C. Kristiansen and C.-C. Shen, J. Appl. Pharm. Sci., 5, 94 (2015); https://doi.org/10.7324/JAPS.2015.50416.
- M.A. Bernards and N.G. Lewis, Phytochemistry, 31, 3409 (1992); https://doi.org/10.1016/0031-9422(92)83695-U.
- V.D. Ebajo Jr., C.-C. Shen and C.Y. Ragasa, J. Appl. Pharm. Sci., 5, 33 (2015).
- S.B. Mahato and A.P. Kundu, Phytochemistry, 37, 1517 (1994); https://doi.org/10.1016/S0031-9422(00)89569-2.
- P.-W. Tsai, K.A. de Castro-Cruz, C.-C. Shen and C.Y. Ragasa, Phcog. J., 4, 1 (2012); https://doi.org/10.5530/pj.2012.31.1.
- T. Nakane, Y. Maeda, H. Ebihara, Y. Arai, K. Masuda, A. Takano, H. Ageta, K. Shiojima, S.-Q. Cai and O.B. Abdel-Halim, Chem. Pharm. Bull. (Tokyo), 50, 1273 (2002); https://doi.org/10.1248/cpb.50.1273.
- C.Y. Ragasa and J. de Jesus, Res. J. Pharm. Biol. Chem. Sci., 5, 701 (2014).
- C.Y. Ragasa, J. Caro and C.-C. Shen, Der Pharm. Chem., 7, 178 (2015).
- Q. Wei, Y. Wei, H. Wu, X. Yang, H. Chen and H. Zhang, J. Am. Oil Chem. Soc., 93, 1173 (2016); https://doi.org/10.1007/s11746-016-2867-9.
References
Buta-buta, Excoecaria Agallocha Linn., BLINDING TREE, Hai qi Downloaded from www.stuartxchange.com/Buta-buta.html on September 10, 2018.
W.-H. Lin and Q.-S. Li, Chin. Tradit. Herbal Drugs, 40, 1704 (2009).
T.M. Tran, T.H. Tran, T.T.H. Dinh and D.T. Vu, Malaysian J. Chem., 17, 20 (2015).
J.-H. Zou, J. Dai, X. Chen and J.-Q. Yuan, Chem. Pharm. Bull. (Tokyo), 54, 920 (2006); https://doi.org/10.1248/cpb.54.920.
M.-Q. Tian, G.-M. Bao, N.-Y. Ji, X.-M. Li and B.-G. Wang, China J. Chin. Materia Med., 33, 405 (2008).
M. Gowri Ponnapalli, M. Ankireddy, S.C.A. Rao Annam, S. Ravirala, S. Sukki and V.R. Tuniki, Tetrahedron Lett., 54, 2942 (2013); https://doi.org/10.1016/j.tetlet.2013.03.105.
T. Konishi, K. Yamazoe, T. Konoshima and Y. Fujiwara, Phytochemistry, 64, 835 (2003); https://doi.org/10.1016/j.phytochem.2003.09.001.
Z.C. Wang, Y.M. Lin, D.Q. Feng, C.H.H. Ke, P. Lin, C.L. Yan and J.D. Chen, Molecules, 14, 414 (2009); https://doi.org/10.3390/molecules14010414.
A.S.R. Anjaneyulu and V. Lakshmana Rao, Phytochemistry, 62, 585 (2003); https://doi.org/10.1016/S0031-9422(02)00269-8.
T. Konishi, T. Konoshima, Y. Fujiwara, S. Kiyosawa, K. Miyahara and M. Nishi, Chem. Pharm. Bull. (Tokyo), 47, 456 (1999); https://doi.org/10.1248/cpb.47.456.
J. Kang, R.Y. Chen and D.Q. Yu, J. Asian Nat. Prod. Res., 7, 729 (2005); https://doi.org/10.1080/1028602042000324943.
T. Konishi, M. Takasaki, H. Tokuda, S. Kiyosawa and T. Konoshima, Biol. Pharm. Bull., 21, 993 (1998); https://doi.org/10.1248/bpb.21.993.
T. Konishi, K. Yamazoe, T. Konoshima, T. Maoka, Y. Fujiwara and K. Miyahara, J. Nat. Prod., 66, 108 (2003); https://doi.org/10.1021/np020321j.
Y. Li, J. Liu, S. Yu, P. Proksch, J. Gu and W. Lin, Phytochemistry, 71, 2124 (2010); https://doi.org/10.1016/j.phytochem.2010.08.011.
C.Y. Ragasa, O.B. Torres, J.M.P. Gutierrez, H.P.B.C. Kristiansen and C.-C. Shen, J. Appl. Pharm. Sci., 5, 94 (2015); https://doi.org/10.7324/JAPS.2015.50416.
M.A. Bernards and N.G. Lewis, Phytochemistry, 31, 3409 (1992); https://doi.org/10.1016/0031-9422(92)83695-U.
V.D. Ebajo Jr., C.-C. Shen and C.Y. Ragasa, J. Appl. Pharm. Sci., 5, 33 (2015).
S.B. Mahato and A.P. Kundu, Phytochemistry, 37, 1517 (1994); https://doi.org/10.1016/S0031-9422(00)89569-2.
P.-W. Tsai, K.A. de Castro-Cruz, C.-C. Shen and C.Y. Ragasa, Phcog. J., 4, 1 (2012); https://doi.org/10.5530/pj.2012.31.1.
T. Nakane, Y. Maeda, H. Ebihara, Y. Arai, K. Masuda, A. Takano, H. Ageta, K. Shiojima, S.-Q. Cai and O.B. Abdel-Halim, Chem. Pharm. Bull. (Tokyo), 50, 1273 (2002); https://doi.org/10.1248/cpb.50.1273.
C.Y. Ragasa and J. de Jesus, Res. J. Pharm. Biol. Chem. Sci., 5, 701 (2014).
C.Y. Ragasa, J. Caro and C.-C. Shen, Der Pharm. Chem., 7, 178 (2015).
Q. Wei, Y. Wei, H. Wu, X. Yang, H. Chen and H. Zhang, J. Am. Oil Chem. Soc., 93, 1173 (2016); https://doi.org/10.1007/s11746-016-2867-9.