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Vol. 32 No. 1 (2020): Vol 32 Issue 1

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Growth and Characterization of Adipic Acid Doped Potassium Hydrogen Phthalate: A Nonlinear Optical Single Crystal

https://doi.org/10.14233/ajchem.2020.22273
R. Manimekalai
Department of Physics, A.V.V.M. Sri Pushpam College (Autonomous), Poondi-613503, India
S. Chidambaram
Department of Physics, A.V.V.M. Sri Pushpam College (Autonomous), Poondi-613503, India

Corresponding Author(s) : R. Manimekalai

maniabi64@gmail.com

Asian Journal of Chemistry, Vol. 32 No. 1 (2020): Vol 32 Issue 1

Abstract

Adipic acid doped potassium hydrogen phthalate (AAKHP) and pure potassium hydrogen phthalate single crystals were grown by slow evaporation method. Single crystal X-ray diffraction analysis was carried out to determine the lattice parameters in a = 6.47 Å, b = 9.59 Å, c = 13.25 Å and space group of Pca21. This confirms the grown AAKHP belongs to the orthorhombic system. Various diffracting planes of the grown crystal were indexed using powder X-ray diffraction study. Fourier-transform infrared studies confirm the presence of various functional groups in the grown crystal. The transmittance spectrum shows that the lower cutoff wavelength is around 290 nm. The nonlinear optical property of the grown crystal has been studied by Kurtz powder second harmonic generation (SHG) analysis. EDAX analysis confirms the presence of various elements in the AAKHP crystal. Vickers micro-hardness studies are used for the analysis of mechanical behaviour of the grown crystal. The paramagnetic nature of the grown crystal was confirmed by vibration spectrum magnetometer technique.

Keywords

Potassium hydrogen phthalate Adipic acid Crystal X-Ray diffraction Optical materials Mechanical properties
Manimekalai, R., & Chidambaram, S. (2019). Growth and Characterization of Adipic Acid Doped Potassium Hydrogen Phthalate: A Nonlinear Optical Single Crystal. Asian Journal of Chemistry, 32(1), 79–83. https://doi.org/10.14233/ajchem.2020.22273
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