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Mineralogy and Characterization of New Bentonite from Tahoua Region of Central Niger
Corresponding Author(s) : M. Gourouza
Asian Journal of Chemistry,
Vol. 31 No. 2 (2019): Vol. 31 No. 2
Abstract
Niger imports a huge quantity of bentonite, which it uses in mining and oil exploration, but also in village hydraulics. The objective of this study is the search for a bentonite-type clay deposit on the Nigerian territory. The clay fraction of a material collected on a clay deposit of the Paleocene Garadaoua Formation in the Ullemmeden basin (central Niger) was the subject of a series of analyzes: DRX; ICP-AES; ICP-MS; ATD-ATG; IR; Adsorption/desorption of N2 at 77 K; cation exchange capacity, granulometry. DRX results corroborated by those of IR and ATD-ATG indicate that the clay minerals constituting the collected material are: montmorillonite, kaolinite and illite, with a strong predominance of montmorillonite. The mineralogical and chemical composition, the specific surface and the cation exchange capacity obtained indicate that the analyzed material is similar to that of Maghnia bentonite in Algeria.
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- R.E. Grim and N. Güven, Bentonites-Geology, Mineralogy, Properties and Uses: Developments in Sedimentology, vol. 24, Elsevier: New York (1978).
- H.H. Murray, Appl. Clay Sci., 17, 207 (2000); https://doi.org/10.1016/S0169-1317(00)00016-8.
- F. Bergaya, B.K.G. Theng and G. Lagaly, Handbook of Clay Science. Development of Clay Science, vol. 1, Elsevier: Amsterdam (2006).
- R.E. Grim, Clay Mineralogy, McGraw-Hill: New York, edn 2 (1968).
- D.M. Moore and R.C. Reynolds, X-Ray Diffraction and the Identification and Analysis of Clay Minerals, Oxford University Press (1989).
- F. Bergaya, B.K.G. Theng and G. Lagaly, eds., Handbook of Clay Science. Development of Clay Science, vol. 1, Chap.1, Elsevier: Amsterdam (2006).
- M. Dikouma, Ph.D. Thesis, Fluctuations du niveau marin au Maastrichtien et au paléocène dans le bassin intracratonique des Iullemmeden, AderDoutchi, Niger Univ. Dijon-Niamey, p. 272 (1990).
- M. Dikouma, J. Lang and A. Pascal, Newsl. Stratigr., 29, 105 (1993); https://doi.org/10.1127/nos/29/1993/105.
- J. Greigert, Description des formations crétacées et tertiaires du bassin des Iullemmeden (Afrique occidentale), B.R.G.M. pp. 236 (1966).
- M. Hanon, Cartes géologiques au 1/100.000 de l’Ader Doutchi (16 feuilles). DRGM Niger. AGCD Belgique (1984).
- J. Soták, Geol. Carpathica, 61, 393 (2010); https://doi.org/10.2478/v10096-010-0024-1.
- G.W. Brindley and G. Brown, Crystal Structures of Clay Minerals and their X-ray Identification. Mineralogical Society, London (1980).
- H. Chamayou and J.P. Legros, Les bases physiques, chimiques et mine’ralogiques de la science du sol. Presses Universitaires de France: Paris (1989).
- K. Tan, Principles of Soil Chemistry, Marcel Dekker: New York, edn 2 (1991).
- F. Wolters and K. Emmerich, Thermochim. Acta, 462, 80 (2007); https://doi.org/10.1016/j.tca.2007.06.002.
- I. Mantin, C.R. Sci. Paris, 1, 815 (1969).
- F. Bergaya and M. Vayer, Appl. Clay Sci., 12, 275 (1997); https://doi.org/10.1016/S0169-1317(97)00012-4.
- P. Salerno and S. Mendioroz, Appl. Clay Sci., 22, 115 (2002); https://doi.org/10.1016/S0169-1317(02)00133-3.
- M.L. Occelli, J.A. Bertrand, S.A. Gould and J.M. Dominguez, Micropor. Mesopor. Mater., 34, 195 (2000); https://doi.org/10.1016/S1387-1811(99)00173-0.
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- A. Chakchouk, B. Samet and T. Mnif, Appl. Clay Sci., 33, 79 (2006); https://doi.org/10.1016/j.clay.2006.03.009.
- I.Th. Rosenquist, Nor. Geol. Tidsskr., 39, 350 (1959).
- Y.P. Hsieh, Clays Clay Miner., 37, 459 (1989); https://doi.org/10.1346/CCMN.1989.0370510.
- F.G. Alabarse, R.V. Conceição, N.M. Balzaretti, F. Schenato and A.M. Xavier, Appl. Clay Sci., 51, 202 (2011); https://doi.org/10.1016/j.clay.2010.11.017.
- E. Eslinger and D. Peaver, Clay Minerals for Petroleum Geologists and Engineers, SEPM Short course 22. Soc. Economic Paleontologists and Mineralogists, Tulsa, USA (1988).
- L. Chen, Y. Huang, L. Huang, B. Liu, G. Wang and S. Yu, J. Radioanal. Nucl. Chem., 290, 675 (2011); https://doi.org/10.1007/s10967-011-1337-y.
- J. Pan, C. Wang, S. Guo, J. Li and Z. Yang, Catal. Commun., 9, 176 (2008); https://doi.org/10.1016/j.catcom.2007.06.001.
- J. Madejova, J. Bujdak, M. Janek and P. Komadel, Spectrochim. Acta A Mol. Biomol. Spectrosc., 54, 1397 (1998); https://doi.org/10.1016/S1386-1425(98)00040-7.
- S. Caillére, S. Hénin and M. Rautureau, Minéralogie des Argiles. 1: structure et propriétés physico- chimiques. Masson: Paris (1982).
- G.A. Borchardt, eds.: J.B. Dixon and S.B. Weed, Montmorillonite and Other Smectite Minerals. In: Minerals in Soil Environments. Soil Science Society of America, Madison: Wisconsin (1977).
- S. Wang, Y. Dong, M. He, L. Chen and X. Yu, Appl. Clay Sci., 43, 164 (2009); https://doi.org/10.1016/j.clay.2008.07.028.
- S. Aytas, M. Yurtlu and R. Donat, J. Hazard. Mater., 172, 667 (2009); https://doi.org/10.1016/j.jhazmat.2009.07.049.
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- P. Salerno, M.B. Asenjo and S. Mendioroz, Thermochim. Acta, 379, 101 (2001); https://doi.org/10.1016/S0040-6031(01)00608-6.
- V.C. Farmer, The Infrared Spectra of Minerals, Mineralogical Society, Monograph 4, London (1974).
- J.D. Russel and A.R. Fraser, ed.: M.J. Wilson, Infrared Methods in Clay Mineralogy: Spectroscopic and Chemical Determinative Methods Chapman and Hall: London (1996).
- J. Madejova, Vib. Spectrosc., 31, 1 (2003); https://doi.org/10.1016/S0924-2031(02)00065-6.
- R.L. Ledoux and J.L.J. White, J. Colloid Interface Sci., 21, 127 (1966); https://doi.org/10.1016/0095-8522(66)90029-8.
- H.W. Van der Marel and H. Beutelspacher, Atlas of Infrared Spectroscopy of Clay Minerals and Their Admixtures; Elsevier: Amsterdam, The Netherlands (1976).
- H. Van Olphen and J.J. Fripiat, Data Handbook for Clay Materials and Other Nonmetallic Minerals, Pergamon Press: Oxford (1979).
- S. Guggenheim and A.F. Koster van Groos, Clays Clay Miner., 49, 433 (2001); https://doi.org/10.1346/CCMN.2001.0490509.
- E. Srasra, Thèse de 3ème cycle. Fac. Sc. Tunis. Univ. Tunis II (1987).
- M.F. Brigatti, Clay Miner., 18, 177 (1983); https://doi.org/10.1180/claymin.1983.018.2.06.
- F. Ayari, E. Srasra and M. Trabelsi-Ayadi, Desalination, 185, 391 (2005); https://doi.org/10.1016/j.desal.2005.04.046.
- M. Yurdakoc¸, M. Akçay, Y. Tonbul, F. Ok and K. Yurdakoc¸, Micropor. Mesopor. Mater., 111, 211 (2008); https://doi.org/10.1016/j.micromeso.2007.07.032.
- M. Alkan, B. Kalay, M. Dogan and Ö. Demirbas, J. Hazard. Mater., 153, 867 (2008); https://doi.org/10.1016/j.jhazmat.2007.09.047.
- Turkif, Ph.D. Thèsis, Université Louis Pasteur, Strasbourg, France (1987).
- L.G. Berg, Introduction in Thermography, Publishing House of the Academy of Sciences of the USSR: Moscow (1961).
- I. Kostov, Mineralogy, Tehnika Publishing House: Sofia (1993).
- S. Brunauer, L.S. Deming, D.M. Deming and E. Teller, J. Am. Chem. Soc., 62, 1723 (1940); https://doi.org/10.1021/ja01864a025.
- S. Kaufhold, R. Dohrmann, M. Klinkenberg, S. Siegesmund and K. Ufer, J. Colloid Interface Sci., 349, 275 (2010); https://doi.org/10.1016/j.jcis.2010.05.018.
- M. Hayati-Ashtiani, Part. Syst. Charact., 28, 71 (2011); https://doi.org/10.1002/ppsc.201100030.
- O. Bouras, T. Chami, M. Houari, H. Khalaf, J.-C. Bollinger and M. Baudu, Environ. Technol., 23, 405 (2002); https://doi.org/10.1080/09593332508618397.
References
R.E. Grim and N. Güven, Bentonites-Geology, Mineralogy, Properties and Uses: Developments in Sedimentology, vol. 24, Elsevier: New York (1978).
H.H. Murray, Appl. Clay Sci., 17, 207 (2000); https://doi.org/10.1016/S0169-1317(00)00016-8.
F. Bergaya, B.K.G. Theng and G. Lagaly, Handbook of Clay Science. Development of Clay Science, vol. 1, Elsevier: Amsterdam (2006).
R.E. Grim, Clay Mineralogy, McGraw-Hill: New York, edn 2 (1968).
D.M. Moore and R.C. Reynolds, X-Ray Diffraction and the Identification and Analysis of Clay Minerals, Oxford University Press (1989).
F. Bergaya, B.K.G. Theng and G. Lagaly, eds., Handbook of Clay Science. Development of Clay Science, vol. 1, Chap.1, Elsevier: Amsterdam (2006).
M. Dikouma, Ph.D. Thesis, Fluctuations du niveau marin au Maastrichtien et au paléocène dans le bassin intracratonique des Iullemmeden, AderDoutchi, Niger Univ. Dijon-Niamey, p. 272 (1990).
M. Dikouma, J. Lang and A. Pascal, Newsl. Stratigr., 29, 105 (1993); https://doi.org/10.1127/nos/29/1993/105.
J. Greigert, Description des formations crétacées et tertiaires du bassin des Iullemmeden (Afrique occidentale), B.R.G.M. pp. 236 (1966).
M. Hanon, Cartes géologiques au 1/100.000 de l’Ader Doutchi (16 feuilles). DRGM Niger. AGCD Belgique (1984).
J. Soták, Geol. Carpathica, 61, 393 (2010); https://doi.org/10.2478/v10096-010-0024-1.
G.W. Brindley and G. Brown, Crystal Structures of Clay Minerals and their X-ray Identification. Mineralogical Society, London (1980).
H. Chamayou and J.P. Legros, Les bases physiques, chimiques et mine’ralogiques de la science du sol. Presses Universitaires de France: Paris (1989).
K. Tan, Principles of Soil Chemistry, Marcel Dekker: New York, edn 2 (1991).
F. Wolters and K. Emmerich, Thermochim. Acta, 462, 80 (2007); https://doi.org/10.1016/j.tca.2007.06.002.
I. Mantin, C.R. Sci. Paris, 1, 815 (1969).
F. Bergaya and M. Vayer, Appl. Clay Sci., 12, 275 (1997); https://doi.org/10.1016/S0169-1317(97)00012-4.
P. Salerno and S. Mendioroz, Appl. Clay Sci., 22, 115 (2002); https://doi.org/10.1016/S0169-1317(02)00133-3.
M.L. Occelli, J.A. Bertrand, S.A. Gould and J.M. Dominguez, Micropor. Mesopor. Mater., 34, 195 (2000); https://doi.org/10.1016/S1387-1811(99)00173-0.
L.V. Amorim, C.M. Gomes, H.L. Lira, K.B. França and H.C. Ferreira, Mater. Res., 7, 583 (2004); https://doi.org/10.1590/S1516-14392004000400012.
A. Chakchouk, B. Samet and T. Mnif, Appl. Clay Sci., 33, 79 (2006); https://doi.org/10.1016/j.clay.2006.03.009.
I.Th. Rosenquist, Nor. Geol. Tidsskr., 39, 350 (1959).
Y.P. Hsieh, Clays Clay Miner., 37, 459 (1989); https://doi.org/10.1346/CCMN.1989.0370510.
F.G. Alabarse, R.V. Conceição, N.M. Balzaretti, F. Schenato and A.M. Xavier, Appl. Clay Sci., 51, 202 (2011); https://doi.org/10.1016/j.clay.2010.11.017.
E. Eslinger and D. Peaver, Clay Minerals for Petroleum Geologists and Engineers, SEPM Short course 22. Soc. Economic Paleontologists and Mineralogists, Tulsa, USA (1988).
L. Chen, Y. Huang, L. Huang, B. Liu, G. Wang and S. Yu, J. Radioanal. Nucl. Chem., 290, 675 (2011); https://doi.org/10.1007/s10967-011-1337-y.
J. Pan, C. Wang, S. Guo, J. Li and Z. Yang, Catal. Commun., 9, 176 (2008); https://doi.org/10.1016/j.catcom.2007.06.001.
J. Madejova, J. Bujdak, M. Janek and P. Komadel, Spectrochim. Acta A Mol. Biomol. Spectrosc., 54, 1397 (1998); https://doi.org/10.1016/S1386-1425(98)00040-7.
S. Caillére, S. Hénin and M. Rautureau, Minéralogie des Argiles. 1: structure et propriétés physico- chimiques. Masson: Paris (1982).
G.A. Borchardt, eds.: J.B. Dixon and S.B. Weed, Montmorillonite and Other Smectite Minerals. In: Minerals in Soil Environments. Soil Science Society of America, Madison: Wisconsin (1977).
S. Wang, Y. Dong, M. He, L. Chen and X. Yu, Appl. Clay Sci., 43, 164 (2009); https://doi.org/10.1016/j.clay.2008.07.028.
S. Aytas, M. Yurtlu and R. Donat, J. Hazard. Mater., 172, 667 (2009); https://doi.org/10.1016/j.jhazmat.2009.07.049.
S.T. Yang, D.L. Zhao, H. Zhang, S.S. Lu, L. Chen and X.J. Yu, J. Hazard. Mater., 183, 632 (2010); https://doi.org/10.1016/j.jhazmat.2010.07.072.
P. Salerno, M.B. Asenjo and S. Mendioroz, Thermochim. Acta, 379, 101 (2001); https://doi.org/10.1016/S0040-6031(01)00608-6.
V.C. Farmer, The Infrared Spectra of Minerals, Mineralogical Society, Monograph 4, London (1974).
J.D. Russel and A.R. Fraser, ed.: M.J. Wilson, Infrared Methods in Clay Mineralogy: Spectroscopic and Chemical Determinative Methods Chapman and Hall: London (1996).
J. Madejova, Vib. Spectrosc., 31, 1 (2003); https://doi.org/10.1016/S0924-2031(02)00065-6.
R.L. Ledoux and J.L.J. White, J. Colloid Interface Sci., 21, 127 (1966); https://doi.org/10.1016/0095-8522(66)90029-8.
H.W. Van der Marel and H. Beutelspacher, Atlas of Infrared Spectroscopy of Clay Minerals and Their Admixtures; Elsevier: Amsterdam, The Netherlands (1976).
H. Van Olphen and J.J. Fripiat, Data Handbook for Clay Materials and Other Nonmetallic Minerals, Pergamon Press: Oxford (1979).
S. Guggenheim and A.F. Koster van Groos, Clays Clay Miner., 49, 433 (2001); https://doi.org/10.1346/CCMN.2001.0490509.
E. Srasra, Thèse de 3ème cycle. Fac. Sc. Tunis. Univ. Tunis II (1987).
M.F. Brigatti, Clay Miner., 18, 177 (1983); https://doi.org/10.1180/claymin.1983.018.2.06.
F. Ayari, E. Srasra and M. Trabelsi-Ayadi, Desalination, 185, 391 (2005); https://doi.org/10.1016/j.desal.2005.04.046.
M. Yurdakoc¸, M. Akçay, Y. Tonbul, F. Ok and K. Yurdakoc¸, Micropor. Mesopor. Mater., 111, 211 (2008); https://doi.org/10.1016/j.micromeso.2007.07.032.
M. Alkan, B. Kalay, M. Dogan and Ö. Demirbas, J. Hazard. Mater., 153, 867 (2008); https://doi.org/10.1016/j.jhazmat.2007.09.047.
Turkif, Ph.D. Thèsis, Université Louis Pasteur, Strasbourg, France (1987).
L.G. Berg, Introduction in Thermography, Publishing House of the Academy of Sciences of the USSR: Moscow (1961).
I. Kostov, Mineralogy, Tehnika Publishing House: Sofia (1993).
S. Brunauer, L.S. Deming, D.M. Deming and E. Teller, J. Am. Chem. Soc., 62, 1723 (1940); https://doi.org/10.1021/ja01864a025.
S. Kaufhold, R. Dohrmann, M. Klinkenberg, S. Siegesmund and K. Ufer, J. Colloid Interface Sci., 349, 275 (2010); https://doi.org/10.1016/j.jcis.2010.05.018.
M. Hayati-Ashtiani, Part. Syst. Charact., 28, 71 (2011); https://doi.org/10.1002/ppsc.201100030.
O. Bouras, T. Chami, M. Houari, H. Khalaf, J.-C. Bollinger and M. Baudu, Environ. Technol., 23, 405 (2002); https://doi.org/10.1080/09593332508618397.