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Vol. 31 No. 2 (2019): Vol. 31 No. 2

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Synthesis of Ion-Imprinted Polymer for Selective Separation of Copper(II) from Metal Ions Mixture

https://doi.org/10.14233/ajchem.2019.21544
Nor Asiken Abdul Wahab
Faculty of Industrial Sciences & Technology, Universiti Malaysia Pahang, 26300, Gambang, Kuantan, Pahang, Malaysia
Mohd Sani Sarjadi
Faculty of Science and Natural Resources, Universiti Malaysia Sabah, 88400 Kota Kinabalu, Sabah, Malaysia
Sazmal Effendi Arshad
Faculty of Science and Natural Resources, Universiti Malaysia Sabah, 88400 Kota Kinabalu, Sabah, Malaysia
Mashitah Mohd Yusoff
Faculty of Industrial Sciences & Technology, Universiti Malaysia Pahang, 26300, Gambang, Kuantan, Pahang, Malaysia
Md Lutfor Rahman
Faculty of Science and Natural Resources, Universiti Malaysia Sabah, 88400 Kota Kinabalu, Sabah, Malaysia

Corresponding Author(s) : Md Lutfor Rahman

lutfor73@gmail.com

Asian Journal of Chemistry, Vol. 31 No. 2 (2019): Vol. 31 No. 2

Abstract

Ion imprinted polymers (IIPs) draw great attention in various fields because of powerful selectivity to the target metal ions. Thus, the synthesis of copper-ion imprinted polymer (Cu-IIP) was performed by using copper ion and complexing agent rufigallol with ethylene glycol dimethacrylate (EGDMA) and 2,2-azobisisobutyronitrile (AIBN). Aqueous HCl was used to leach Cu2+ ions from the imprinted polymer for creation of cavities of template, which is utilized for cooper ions adsorption with high selectivity. The IIP were characterized using ICP-MS, FE-SEM and also solid state analysis by UV-visible NIR spectroscopy. FT-IR study confirmed the successful complexation of Cu-IIP. The optimum pH was found to be 6 and highest adsorption capacity was estimated about 112.5 mg g-1. Thus, IIP gave good selectivity to copper ions in presence of other transition metals and also IIP can be regenerated for eight times without a substantial loss in adsorption capacity.

Keywords

Ion imprinted polymer Copper ion Rufigallol Selective separation
Abdul Wahab, N. A., Sarjadi, M. S., Arshad, S. E., Yusoff, M. M., & Rahman, M. L. (2018). Synthesis of Ion-Imprinted Polymer for Selective Separation of Copper(II) from Metal Ions Mixture. Asian Journal of Chemistry, 31(2), 427–432. https://doi.org/10.14233/ajchem.2019.21544
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References
  1. L. Ye and K. Mosbach, Chem. Mater., 20, 859 (2008); https://doi.org/10.1021/cm703190w.
  2. X. Shi, A. Wu, G. Qu, R. Li and D. Zhang, Biomater., 28, 3741 (2007); https://doi.org/10.1016/j.biomaterials.2007.04.036.
  3. L. Chen, X. Wang, W. Lu, X. Wu and J. Li, Chem. Soc. Rev., 45, 2137 (2016); https://doi.org/10.1039/C6CS00061D.
  4. F. Puoci, G. Cirillo, M. Curcio, F. Iemma, O.I. Parisi, U.G. Spizzirri and N. Picci, ed.: M. Elnashar, Molecularly Imprinted Polymers (PIMs) in Biomedical Applications; In: Biopolymers, Chap. 28, pp. 547-574, InTech (2010).
  5. H. Nishide, J. Deguchi and E. Tsuchida, Chem. Lett., 5, 169 (1976); https://doi.org/10.1246/cl.1976.169.
  6. Ö. Saatçilar, N. Satiroglu, R. Say, S. Bekta and A. Denizli, J. Appl. Polym. Sci., 101, 3520 (2006); https://doi.org/10.1002/app.24591.
  7. C. Branger, W. Meouche and A. Margaillan, React. Funct. Polym., 73, 859 (2013); https://doi.org/10.1016/j.reactfunctpolym.2013.03.021.
  8. E. Birlik, A. Ersöz, A. Denizli and R. Say, Anal. Chim. Acta, 565, 145 (2006); https://doi.org/10.1016/j.aca.2006.02.051.
  9. E. Birlik, A. Ersöz, E. Açikkalp, A. Denizli and R. Say, J. Hazard. Mater., 140, 110 (2007); https://doi.org/10.1016/j.jhazmat.2006.06.141.
  10. M. Shamsipur, J. Fasihi and K. Ashtari, Anal. Chem., 79, 7116 (2007); https://doi.org/10.1021/ac070968e.
  11. S. Tokonami, H. Shiigi and T. Nagaoka, Anal. Chim. Acta, 641, 7 (2009); https://doi.org/10.1016/j.aca.2009.03.035.
  12. I. Dakova, I. Karadjova, I. Ivanov, V. Georgieva, B. Evtimova and G. Georgiev, Anal. Chim. Acta, 584, 196 (2007); https://doi.org/10.1016/j.aca.2006.10.050.
  13. M. Shamsipur, J. Fasihi, A. Khanchi, R. Hassani, K. Alizadeh and H. Shamsipur, Anal. Chim. Acta, 599, 294 (2007); https://doi.org/10.1016/j.aca.2007.08.013.
  14. X. Chang, N. Jiang, H. Zheng, Q. He, Z. Hu, Y. Zhai and Y. Cui, Talanta, 71, 38 (2007); https://doi.org/10.1016/j.talanta.2006.03.012.
  15. M. Karabörk, A. Ersoz, E. Birlik and R. Say, Hacettepe J. Biol. Chem., 35, 135 (2007).
  16. K.M. Onesios, J.T. Yu and E.J. Bouwer, Biodegrad., 20, 441 (2009); https://doi.org/10.1007/s10532-008-9237-8.
  17. S.A. Snyder, E.C. Wert, D.J. Rexing, R.E. Zegers and D.D. Drury, Ozone Sci. Eng., 28, 445 (2006); https://doi.org/10.1080/01919510601039726.
  18. D.L. Huang, R.Z. Wang, Y.G. Liu, G.M. Zeng, C. Lai, P. Xu, B.A. Lu, J.J. Xu, C. Wang and C. Huang, Environ. Sci. Pollut. Res. Int., 22, 963 (2015); https://doi.org/10.1007/s11356-014-3599-8.
  19. P. Metilda, K. Prasad, R. Kala, J.M. Gladis, T.P. Rao and G.R.K. Naidu, Anal. Chim. Acta, 582, 147 (2007); https://doi.org/10.1016/j.aca.2006.08.052.
  20. G.E. Southard, K.A.E. Van Houten Jr., E.W. Ott Jr. and G.M. Murray, Anal. Chim. Acta, 581, 202 (2007); https://doi.org/10.1016/j.aca.2006.08.027.
  21. N. Zhang, B. Hu and C. Huang, Anal. Chim. Acta, 597, 12 (2007); https://doi.org/10.1016/j.aca.2007.06.045.
  22. S. Shirvani-Arani, S.J. Ahmadi, A. Bahrami-Samani and M. GhannadiMaragheh, Anal. Chim. Acta, 623, 82 (2008); https://doi.org/10.1016/j.aca.2008.05.071.
  23. D.K. Singh and S. Mishra, Chromatographia, 70, 1539 (2009); https://doi.org/10.1365/s10337-009-1379-2.
  24. M. Shamsipur, A. Siroueinejad, B. Hemmateenejad, A. Abbaspour, H. Sharghi, K. Alizadeh and S. Arshadi, J. Electroanal. Chem., 600, 345 (2007); https://doi.org/10.1016/j.jelechem.2006.09.006.
  25. S. Buyuktiryaki, R. Say, A. Denizli and A. Ersoz, Talanta, 71, 699 (2007); https://doi.org/10.1016/j.talanta.2006.05.026.
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