Copyright (c) 2019 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Spectral and Biological Studies of Ni(II), Pd(II), Pt(IV) and Cu(II) Complexes with Novel Azamacrocyclic Ligand
Corresponding Author(s) : Archana Gautam
Asian Journal of Chemistry,
Vol. 31 No. 2 (2019): Vol. 31 No. 2
Abstract
Complexes of Ni(II), Pd(II), Pt(IV) and Cu(II) with a novel azamacrocyclic ligand viz. 5,7,12,14- tetramethyl-1,2,4,8,10,11-hexaazacyclotetradeca-4,7,11,14-tetraene-3,9-dione (L) were synthesized and characterized by elemental analysis, molar conductance, magnetic susceptibitity, mass spectra, 1H NMR (L), FT-IR and electronic spectral studies. In molecular modeling, the geometry of ligand (L) was fully optimized with respect to the energy using the 6-31g(d,p) basis set. On the basis of these spectral studies a distorted octahedral geometry was assigned for Ni(II) complex, square planar for Pd(II), octahedral and tetragonal geometry for Pt(IV) and Cu(II) complexes respectively. The ligand and its metal complexes were screened in vitro against some species of bacteria and plant pathogenic fungi. Electrochemical behaviour of nickel and copper complexes were studied by cyclic voltammetry.
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- Z.H. Chohan and C.T. Supuran, Main Group Met. Chem., 24, 399 (2001); https://doi.org/10.1515/MGMC.2001.24.7.399.
- M.A.D. Becke, Phys. Rev. A, 38, 3098 (1988); https://doi.org/10.1103/PhysRevA.38.3098.
- C. Lee, W. Yang and R.G. Parr, Phys. Rev. B, 37, 785 (1988); https://doi.org/10.1103/PhysRevB.37.785.
- S.H. Vosko, L. Wilk and M. Nusair, Can. J. Chem., 58, 1200 (1980); https://doi.org/10.1139/p80-159.
- K. Nakamoto, Infrared and Raman Spectra of Coordination Compounds, Wiley/Interscience: New York (1970).
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- S. Ilhan, H. Temel, I. Yilmaz and M. Sekerci, Polyhedron, 26, 2795 (2007); https://doi.org/10.1016/j.poly.2007.01.015.
References
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M. Tyagi and S. Chandra, J. Saudi Chem. Soc., 18, 53 (2014); https://doi.org/10.1016/j.jscs.2011.05.013.
K.L. Haas and K.J. Franz, Chem Rev., 109, 4921 (2009); https://doi.org/10.1021/cr900134a.
D.P. Singh, K. Kumar and C. Sharma, Eur. J. Med. Chem., 45, 1230 (2010); https://doi.org/10.1016/j.ejmech.2009.12.009.
S. Chandra and A. Gautam, Spectrochim. Acta A, Mol. Biomol. Spectrosc., 70A, 1001 (2008); https://doi.org/10.1016/j.saa.2007.08.027.
V. Diez, J.V. Cuevas, G. García-Herbosa, G. Aullón, J.P.H. Charmant, A. Carbayo and A. Muñoz, Inorg. Chem., 46, 568 (2007); https://doi.org/10.1021/ic061060u.
G.A. Melson, Coordination Chemistry of Macrocyclic Compounds, Plenum: New York (1979).
N.V. Gerbeleu, V.B. Arion and J. Burges, Template Synthesis of Macrocyclic Compounds, Wiely-VCH: Weinheim (1999).
R. Hernandez-Molina and A. Mederos, ed.: J.A. McCleverty and T.J. Meyer, Comprehensive Coordination Chemistry II, Elsevier, vol. 1, Chap. 9 (2004).
S. Chandra, S. Raizada and S. Rani, Spectrochim. Acta A, Mol. Biomol. Spectrosc., 71A, 720 (2008); https://doi.org/10.1016/j.saa.2007.12.051.
S. Chandra, M. Tyagi, S. Rani and S. Kumar, Spectrochim. Acta A, Mol. Biomol. Spectrosc., 75A, 835 (2010); https://doi.org/10.1016/j.saa.2009.12.009.
M. Tyagi and S. Chandra, J. Saudi Chem. Soc., 18, 53 (2014); https://doi.org/10.1016/j.jscs.2011.05.013.
G. Hu, Z.D. Zhang, L. Hu and J.M. Song, Transition Met. Chem., 30, 856 (2005); https://doi.org/10.1007/s11243-005-6259-5.
S. Chandra, M. Tyagi and K. Sharma, J. Iranian Chem. Soc., 6, 310 (2009); https://doi.org/10.1007/BF03245839.
S.G. Shankarwar, B.B. Nagolkar, V.A. Shelke and T.K. Chondhekar, Spectrochim. Acta A, Mol. Biomol. Spectrosc., 145A, 188 (2015); https://doi.org/10.1016/j.saa.2015.02.006.
A.A. Abou-Hussein and W. Linert, Spectrochim. Acta A, Mol. Biomol. Spectrosc., 141A, 223 (2015); https://doi.org/10.1016/j.saa.2015.01.063.
S.A. Galal, K.H. Hegab, A.S. Kassab, M.L. Rodriguez, S.M. Kerwin, A.-M.A. El-Khamry and H.I. El Diwani, Eur. J. Med. Chem., 44, 1500 (2009); https://doi.org/10.1016/j.ejmech.2008.07.013.
M. Albrecht, S. Mirtschin, O. Osetska, S. Dehn, D. Enders, R. Fröhlich, T. Pape and E.F. Hahn, Eur. J. Inorg. Chem., 2007, 3276 (2007); https://doi.org/10.1002/ejic.200700222.
I.L. Eremenko, S.E. Nefedov, A.A. Sidorov, M.A. Golubnichaya, P.V. Danilov, V.N. Ikorskii, Y.G. Shvedenkov, V.M. Novotortsev and I.I. Moiseev, Inorg. Chem., 38, 3764 (1999); https://doi.org/10.1021/ic981292w.
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J.M. Tercero, A. Matilla, M.A. Sanjuan, C.F. Moreno, J.D. Martín and J.A. Walmsley, Inorg. Chim. Acta, 342, 77 (2003); https://doi.org/10.1016/S0020-1693(02)01071-X.
L. Tripathi, P. Kumar and A.K. Singhai, Indian J. Cancer, 44, 62 (2007); https://doi.org/10.4103/0019-509X.35813.
J. Sandercock, M.K.B. Parmar, V. Torri and W. Qian, Br. J. Cancer, 87, 815 (2002); https://doi.org/10.1038/sj.bjc.6600567.
J.-L. Roh, B.J. Moon, J.S. Kim, J.H. Lee, K.-J. Cho, S.-H. Choi, S.Y. Nam, B.-J. Lee and S.Y. Kim, Clin. Exp. Otorhinolaryngol., 1, 103 (2008); https://doi.org/10.3342/ceo.2008.1.2.103.
G.K. Hagos, R.E. Carroll, T. Kouznetsova, Q. Li, V. Toader, P.A. Fernandez, S.M. Swanson and G.R.J. Thatcher, Mol. Cancer Ther., 6, 2230 (2007); https://doi.org/10.1158/1535-7163.MCT-07-0069.
N. Fahmi, M.K. Biyala and R.V. Singh, Transition Met. Chem., 29, 681 (2004); https://doi.org/10.1007/s11243-004-6580-4.
R.K. Agarwal and S. Prasad, Bioinorg. Chem. Appl., 3, 271 (2005); https://doi.org/10.1155/BCA.2005.271.
S. Chandra and S. Verma, Russ. J. Coord. Chem., 34, 499 (2008); https://doi.org/10.1134/S107032840807004X.
J.R. Anacona and G.D. Sillva, J. Chil. Chem. Soc., 50, 447 (2005).
N. Raman, A. Kulandaisamy, C. Thangaraja and K. Jeyasubramanian, Transition Met. Chem., 28, 29 (2003); https://doi.org/10.1023/A:1022544126607.
R.F.F. Costa, A.P. Rebolledo, T. Matencio, H.D.R. Calado, J.D. Ardisson, M.E. Cortés, B.L. Rodrigues and H. Beraldo, J. Coord. Chem., 58, 1307 (2005); https://doi.org/10.1080/00958970500213307.
R.V. Singh, M.K. Biyala and N. Fahmi, Phosphorus Sulfur Silicon Rel. Elem., 180, 425 (2005); https://doi.org/10.1080/104265090509225.
S. Chandra, A. Gautam and M. Tyagi, Russ. J. Coord. Chem., 35, 25 (2009); https://doi.org/10.1134/S1070328409010060.
S. Zivanovic, S. Chi and A.F. Draughon, J. Food Sci., 70, 45 (2005); https://doi.org/10.1111/j.1365-2621.2005.tb09045.x.
Z.H. Chohan, A. Munawar and C.T. Supuran, Met. Based Drugs, 8, 137 (2001); https://doi.org/10.1155/MBD.2001.137.
Z.H. Chohan and C.T. Supuran, Main Group Met. Chem., 24, 399 (2001); https://doi.org/10.1515/MGMC.2001.24.7.399.
M.A.D. Becke, Phys. Rev. A, 38, 3098 (1988); https://doi.org/10.1103/PhysRevA.38.3098.
C. Lee, W. Yang and R.G. Parr, Phys. Rev. B, 37, 785 (1988); https://doi.org/10.1103/PhysRevB.37.785.
S.H. Vosko, L. Wilk and M. Nusair, Can. J. Chem., 58, 1200 (1980); https://doi.org/10.1139/p80-159.
K. Nakamoto, Infrared and Raman Spectra of Coordination Compounds, Wiley/Interscience: New York (1970).
S. Chandra and M. Tyagi, J. Serb. Chem. Soc., 73, 727 (2008); https://doi.org/10.2298/JSC0807727C.
S. Ilhan, H. Temel, I. Yilmaz and A. Kilic, Transition Met. Chem., 32, 344 (2007); https://doi.org/10.1007/s11243-006-0174-2.
S. Ilhan, H. Temel, I. Yilmaz and M. Sekerci, Polyhedron, 26, 2795 (2007); https://doi.org/10.1016/j.poly.2007.01.015.