Issue

Vol. 30 No. 2 (2018): Vol 30 Issue 2

Copyright (c) 2018 AJC

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Growth, Spectral, Thermal, Linear and Non-Linear Optical Characteristics of an Efficient Organic Crystal: L-Lysinium 5-Sulfosalicylate

https://doi.org/10.14233/ajchem.2018.20957
R. Usha
PG & Research Department of Physics, Queen Mary’s College, Chennai-600 004, India
N. Hema
PG & Research Department of Physics, Queen Mary’s College, Chennai-600 004, India
V. Revathi Ambika
PG & Research Department of Physics, Queen Mary’s College, Chennai-600 004, India
D. Shalini
PG & Research Department of Physics, Queen Mary’s College, Chennai-600 004, India
D. Jayalakshmi
PG & Research Department of Physics, Queen Mary’s College, Chennai-600 004, India

Corresponding Author(s) : D. Jayalakshmi

djayalakshmi2016@gmail.com

Asian Journal of Chemistry, Vol. 30 No. 2 (2018): Vol 30 Issue 2

Abstract

L-Lysinium 5-sulfosalicylate (LL5SS) has been synthesized and grown by solution growth method at room temperature using deionized water as a solvent. The crystal structure of the materials was solved by single crystal X-ray diffraction analysis and it was found that the material has monoclinic system with the space group P21. Fourier transform infrared spectral study was carried out to confirm functional groups present in the crystal. The optical absorption study shows that the crystal is transparent in the entire visible region with a cut-off wavelength of 324 nm. Photoluminescence studies were also carried out to identify the excitation emission of the grown LL5SS crystal. Dielectric study was performed on the single crystal to study the power dissipation of the material in the presence of alternating electric field. Thermal stability has been assessed by thermo gravimetric analysis. Mechanical parameters were calculated. The laser damage threshold value of LL5SS crystal was estimated to be 5.6 GW/cm2 using a Nd:YAG laser. The Kurtz and Perry powder SHG efficiencies were measured. Non-linear refractive index (n2), non-linear absorption coefficient (b) and third-order non-linear optical susceptibility (c3) values of LL5SS were found from Z scan technique.

Keywords

Single crystal XRD Photoluminesence Dielectric measurement Third order non-linear optical property Micro hardness
Usha, R., Hema, N., Ambika, V. R., Shalini, D., & Jayalakshmi, D. (2017). Growth, Spectral, Thermal, Linear and Non-Linear Optical Characteristics of an Efficient Organic Crystal: L-Lysinium 5-Sulfosalicylate. Asian Journal of Chemistry, 30(2), 343–350. https://doi.org/10.14233/ajchem.2018.20957
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. J. Zyss, Molecular Non-Linear Optics, Academic Press, Boston (1994).
  2. D.R. Yuan, D. Xu, N. Zhang, M.G. Liu and M.H. Jiang, Chin. Phys. Lett., 13, 841 (1996); https://doi.org/10.1088/0256-307X/13/11/011.
  3. I. Ledoux, Synth. Met., 54, 123 (1993); https://doi.org/10.1016/0379-6779(93)91051-3.
  4. H.A. Petrosyan, H.A. Karapetyan, M.Y. Antipin and A.M. Petrosyan, J. Cryst. Growth, 275, 1919 (2005); https://doi.org/10.1016/j.jcrysgro.2004.11.258.
  5. H.O. Marcy, L.A. DeLoach, J.-H. Liao, M.G. Kanatzidis, S.P. Velsko, M.J. Rosker, L.F. Warren, C.A. Ebbers, P.H. Cunningham and C.A. Thomas, Opt. Lett., 20, 252 (1995); https://doi.org/10.1364/OL.20.000252.
  6. S.R. Marder, J.E. Sohn and G.D. Stucky, Materials for Non-linear Optics, ACS Symposium Series, p. 455 (1991).
  7. S.S. Gupte, A. Marcano O, R.D. Pradhan, C.F. Desai and N. Melikechi, J. Appl. Phys., 89, 4939 (2001); https://doi.org/10.1063/1.1358325.
  8. D. Arthi, E. Ilango, M. Mercina, D. Jayaraman and V. Joseph, J. Mol. Struct., 1127, 156 (2017); https://doi.org/10.1016/j.molstruc.2016.07.030.
  9. K. Ramya, N.T. Saraswathi and C.R. Raja, Opt. Laser Technol., 90, 222 (2017); https://doi.org/10.1016/j.optlastec.2016.12.002.
  10. N. Rani, N. Vijayan, K. Thukral, K.K. Maurya, G. Bhagavannarayana, D. Haranath, S. Verma and M.A. Wahab, Spectrochim. Acta A Mol. Biomol. Spectrosc., 105, 192 (2013); https://doi.org/10.1016/j.saa.2012.12.030.
  11. V.S. Shankar, R. Sankar, R. Siddheswaran, R. Jayavel and P. Murugakoothan, Mater. Chem. Phys., 109, 119 (2008); https://doi.org/10.1016/j.matchemphys.2007.11.008.
  12. J.-F. Ma, J. Yang, Li, S.-Y. Song, H.-J. Zhang, H.-S. Wang and K.-Y. Yang, Cryst. Growth Des., 5, 807 (2005); https://doi.org/10.1021/cg049723a.
  13. A. Cote and G.K.H. Shimizu, Coord. Chem. Rev., 245, 49 (2003); https://doi.org/10.1016/S0010-8545(03)00033-X.
  14. O.M. Yaghi, C.E. Davis, G. Li and H. Li, J. Am. Chem. Soc., 119, 2861 (1997); https://doi.org/10.1021/ja9639473.
  15. C. Swiegers and T. Malefetse, Chem. Rev., 100, 3483 (2000); https://doi.org/10.1021/cr990110s.
  16. S.A.M.B. Dhas and S. Natarajan, Cryst. Res. Technol., 43, 869 (2008); https://doi.org/10.1002/crat.200711152.
  17. L. Kumari and W.Z. Li, Cryst. Res. Technol., 45, 311 (2010); https://doi.org/10.1002/crat.200900600.
  18. M. Jose, R. Uthrakumar, A.J. Rajendran and S.J. Das, Spectrochim. Acta Part A: Mol. Biomol. Spectrosc., 86, 495 (2012); https://doi.org/10.1016/j.saa.2011.11.002.
  19. A. Aravindan, P. Srinivasan, N. Vijayan, R.G. Krishnan and P. Ramasamy, Spectrochim. Acta Part A: Mol. Biomol. Spectrosc., 71, 297 (2008); https://doi.org/10.1016/j.saa.2007.12.023.
  20. M. Roman and W.T. Winter, Biomacromolecules, 5, 1671 (2004); https://doi.org/10.1021/bm034519+.
  21. R.R. Babu, K. Sethuraman, N. Vijayan, G. Bhagavannarayana, R. Gopalakrishnan and P. Ramasamy, Cryst. Res. Technol., 41, 906 (2006); https://doi.org/10.1002/crat.200510693.
  22. T.H. Wei, D.J. Hagan, M.J. Sence, E.W. Van Stryland, J.W. Perry and D.R. Coulter, Appl. Phys. B, 54, 46 (1992); https://doi.org/10.1007/BF00331733.
  23. A.J. Kiran, D. Udayakumar, K. Chandrasekharan, A.V. Adhikari and H.D. Shashikala, J. Phys. At. Mol. Opt. Phys., 39, 3747 (2006); https://doi.org/10.1088/0953-4075/39/18/005.
  24. C. He, Y. Wu, G. Shi, W. Duan, W. Song and Y. Song, Org. Electron., 8, 198 (2007); https://doi.org/10.1016/j.orgel.2007.01.002.
  25. N. Sivakumar and G. Anbalagan, Opt. Mater., 60, 533 (2016); https://doi.org/10.1016/j.optmat.2016.09.010.
Read More
Author biographies is not available.
Download
PDF
Statistic
Read Counter : 0 Download : 0