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Vol. 30 No. 9 (2018): Vol 30 Issue 9

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Intermolecular Interactions and Refractive Indices: Experimental Data and Prediction of Oxygenated Fuel Additives with Hydrocarbons

https://doi.org/10.14233/ajchem.2018.21436
Rekha Devi
Department of Chemistry, Deenbandhu Chhotu Ram University of Science and Technology, Murthal-131 039, India
Suman Gahlyan
Department of Chemistry, Deenbandhu Chhotu Ram University of Science and Technology, Murthal-131 039, India
Manju Rani
Department of Chemical Engineering, Deenbandhu Chhotu Ram University of Science and Technology, Murthal-131 039, India
Sanjeev Maken
Department of Chemistry, Deenbandhu Chhotu Ram University of Science and Technology, Murthal-131 039, India

Corresponding Author(s) : Sanjeev Maken

sanjeevmakin@gmail.com

Asian Journal of Chemistry, Vol. 30 No. 9 (2018): Vol 30 Issue 9

Abstract

Oxygen containing compounds specifically alkanol and ether are being used as oxygenate fuel additives. The refractive indices (nD) of oxygenated fuel additive, aliphatic and aromatic hydrocarbon and their mixtures were measured at 298.15 K to 318.15 K. The mixtures selected were diisopropyl ether (DIPE) + benzene, toluene, n-alkane (C6-C8) or benzene, toluene (1) + alkane (2) and all possible combinations of alkanes at 298.15 K to 318.15 K. Various mixing rules like Gladstone-Dale, Arago-Biot, Heller, Weiner, Newton and Erying–John were applied for the theoretical estimation of refractive index and compared with experimental refractive indices of binary mixtures. Polynomial equation was applied to the measured data to calculate standard deviation. The Dn were further interpreted in terms of intermolecular interactions between the oxygenated fuel additive, aliphatic and aromatic hydrocarbons.

Keywords

Oxygenate Refractive index Diisopropyl ether Hydrocarbons Intermolecular interactions
Devi, R., Gahlyan, S., Rani, M., & Maken, S. (2018). Intermolecular Interactions and Refractive Indices: Experimental Data and Prediction of Oxygenated Fuel Additives with Hydrocarbons. Asian Journal of Chemistry, 30(9), 2054–2062. https://doi.org/10.14233/ajchem.2018.21436
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