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Vol. 30 No. 2 (2018): Vol 30 Issue 2

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Ultrasonic Studies on Ion-Solvent Interactions of Tetra-n-butylammonium Bromide in Aqueous Solution of 1,3-Dioxolane and 2,2-Dimethoxypropane at Different Temperatures

https://doi.org/10.14233/ajchem.2018.20946
Dayananda Sarangi
Department of Chemistry, KIIT University, Bhubaneswar-751 024, India
Jagannath Panda
Department of Chemistry, KIIT University, Bhubaneswar-751 024, India
Rojalin Sahu
Department of Chemistry, KIIT University, Bhubaneswar-751 024, India
Braja B. Nanda
Department of Chemistry, Vikram Deb Autonomous College, Jeypore-764 001, India

Corresponding Author(s) : Rojalin Sahu

Asian Journal of Chemistry, Vol. 30 No. 2 (2018): Vol 30 Issue 2

Abstract

Tetra-n-butylammonium bromide (TBAB) is made soluble in different solvents like 10 % 1,3-dioxolane-water and 10 % dimethoxypropane-water. Ultrasonic velocity (U), density (r) and coefficient of viscosity (h) are determined at different temperatures i.e. at 298.15, 303.15, 308.15 and 313.15 K. These values of ultrasonic velocity (U), density (r) and co-efficient of viscosity (h) are used to calculate the thermo acoustic properties like isentropic compressibility (bs), molar compressibility (W), acoustic impedance (Z), molar sound velocity (R), relative association (RA), intermolecular free length (Lf), free volume (Vf), internal pressure (pi), isothermal compressibility (bT). The results obtained were analyzed to interpret the ion-ion and ion-solvent interactions occurring in the solutions.

Keywords

Tetra-n-butylammonium bromide 1,3-Dioxolane 2,2-Dimethoxy propane Ion-solvent interaction Ultrasonic
Sarangi, D., Panda, J., Sahu, R., & Nanda, B. B. (2017). Ultrasonic Studies on Ion-Solvent Interactions of Tetra-n-butylammonium Bromide in Aqueous Solution of 1,3-Dioxolane and 2,2-Dimethoxypropane at Different Temperatures. Asian Journal of Chemistry, 30(2), 323–328. https://doi.org/10.14233/ajchem.2018.20946
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References
  1. A. Apelblat, J. Solution Chem., 36, 1437 (2007); https://doi.org/10.1007/s10953-007-9195-5.
  2. F.J. Millero, in ed.: R.A. Horne, Water and Aqueous Solutions: Structure, Thermodynamics, and Transport Processes, Wiley-Interscience, New York, p. 519 (1972).
  3. H.J. Ledon, Org. Synth., 59, 66 (1979); https://doi.org/10.15227/orgsyn.059.0066.
  4. S.R. Aswale and S.S. Aswale, J. Chem. Res., 3, 233 (2011).
  5. W.Y. Wen, ed.: R.A. Horne, Water and Aqueous Solutions, John Wile & Sons: New York, Chap. 15, p. 613 (1972).
  6. E.R. Nightingale Jr., J. Phys. Chem., 66, 894 (1962); https://doi.org/10.1021/j100811a032.
  7. H.S. Frank and W.Y. Wen, Discuss. Faraday Soc., 24, 133 (1957); https://doi.org/10.1039/df9572400133.
  8. H. Rueterjans, F. Schreiner, U. Sage and T. Ackermann, J. Phys. Chem., 73, 986 (1969); https://doi.org/10.1021/j100724a038.
  9. W.Y. Wen and S. Saito, J. Phys. Chem., 68, 2639 (1964); https://doi.org/10.1021/j100791a042.
  10. R.A. Daignault and E.L. Eliel, Organic Synthesis Collections, vol. 5, p. 303 (1973).
  11. G. Douheret and A. Pal, J. Chem. Eng. Data, 33, 40 (1988); https://doi.org/10.1021/je00051a014.
  12. T.S. Murthy, B. Rambabu and K. Laxminarayana, Acoust. Lett., 17, 111 (1993).
  13. E.R. Nightingale Jr., Phys. Chem., 66, 894 (1962); https://doi.org/10.1021/j100811a032.
  14. P.S. Nikam and A.B. Nikumbh, J. Chem. Eng. Data, 47, 400 (2002); https://doi.org/10.1021/je0102762.
  15. P.S. Nikam, H. Mehdi, T.B. Pawar and A.B. Sawant, Indian J. Pure Appl. Phys., 42, 172 (2004).
  16. Y. Nagano, M. Sakiyama, T. Fujiwara and Y. Kondo, J. Phys. Chem., 92, 5823 (1988); https://doi.org/10.1021/j100331a054.
  17. H. Hooshyar and B. Khezri, Phys. Chem. Liq., 54, 663 (2016); https://doi.org/10.1080/00319104.2016.1140762.
  18. T.G. Coker, J. Ambrose and G.J. Janz, J. Am. Chem. Soc., 92, 5293 (1970); https://doi.org/10.1021/ja00721a001.
  19. J.A. Kitchner, Findlay Practical Physical Chemistry, Longman: London, edn 8, p. 70 (1954).
  20. M.N. Roy and B. Sinha, J. Mol. Liq., 133, 89 (2007); https://doi.org/10.1016/j.molliq.2006.07.009.
  21. B. Sinha, B.K. Sarkar and M.N. Roy, J. Chem. Thermodyn., 40, 394 (2008); https://doi.org/10.1016/j.jct.2007.09.012.
  22. B.B. Nanda, B. Nanda and P.C. Mohanty, J. Mol. Liq., 171, 50 (2012); https://doi.org/10.1016/j.molliq.2012.03.011.
  23. B. Jacobson, P.A. Heedman, R. Pesola,A.I. Virtanen and N.A. Sörensen, Acta Chem. Scand., 7, 705 (1953); https://doi.org/10.3891/acta.chem.scand.07-0705.
  24. D.O. Masson, Philos. Mag., 8, 218 (1929); https://doi.org/10.1080/14786440808564880.
  25. B.B. Nanda, Indian J. Pure Appl. Phys., 54, 471 (2016).
  26. G. Nath and R. Paikaray, Indian J. Phys., 83, 1309 (2009); https://doi.org/10.1007/s12648-009-0111-2.
  27. B.B. Nanda, Int. J. Res. Rev. Pharm. Appl. Sci., 6, 1290 (2016).
  28. J.F. Kincaid and H. Eyring, J. Chem. Phys., 6, 620 (1938); https://doi.org/10.1063/1.1750134.
  29. S. Thirumaran and K.J. Sabu, Indian J. Pure Appl. Phys., 47, 87 (2009).
  30. T.M. Aminabhavi, M.I. Aralaguppi, S.S. Joshi, S.B. Harogopped, R.S. Khinnavar and R.H. Balungi, Indian J. Technol., 30, 303 (1992).
  31. C.V. Suryanarayana, J. Acoust. Soc. Ind., 7, 131 (1979).
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