Effect of Pt on Catalytic Activity of Al- and Zr-Pillared Smectite

Is Fatimah; Septian P. Yudha; Happy Bunga N.S.; Rodhotul Ulya; Dwiarso Rubiyanto

doi:10.14233/ajchem.2016.19879

Issue

Vol. 28 No. 11 (2016): Vol 28 Issue 11

Issue Published : August 10, 2016

This work is licensed under a Creative Commons Attribution 4.0 International License.

Effect of Pt on Catalytic Activity of Al- and Zr-Pillared Smectite

https://doi.org/10.14233/ajchem.2016.19879

Is Fatimah

Chemistry Department, Islamic University of Indonesia, Kampus Terpadu UII, Jl. Kaliurang Km 14, Sleman, Yogyakarta 55584, Indonesia

Septian P. Yudha

Chemistry Department, Islamic University of Indonesia, Kampus Terpadu UII, Jl. Kaliurang Km 14, Sleman, Yogyakarta 55584, Indonesia

Happy Bunga N.S.

Chemistry Department, Islamic University of Indonesia, Kampus Terpadu UII, Jl. Kaliurang Km 14, Sleman, Yogyakarta 55584, Indonesia

Rodhotul Ulya

Chemistry Department, Islamic University of Indonesia, Kampus Terpadu UII, Jl. Kaliurang Km 14, Sleman, Yogyakarta 55584, Indonesia

Dwiarso Rubiyanto

Chemistry Department, Islamic University of Indonesia, Kampus Terpadu UII, Jl. Kaliurang Km 14, Sleman, Yogyakarta 55584, Indonesia

Corresponding Author(s) : Is Fatimah

isfatimah@uii.ac.id

Asian Journal of Chemistry, Vol. 28 No. 11 (2016): Vol 28 Issue 11
Article Published : August 11, 2016

Abstract

This study aimed to investigate the physico-chemical properties of Pt dispersed in Al and Zr pillared saponite and montmorillonite. The chemical and morphological characteristics of prepared materials were carried out by using X-ray diffraction, scanning electron microscopy and Lewis to Brøensted acidity ratio (L/B) by pyridine adsorption followed by Fourier transform infrared analysis methods. The BET surface analysis results showed that the specific surface area of clays increased by Al and Zr pillarization and then reduced after Pt dispersion. Solid acidity and L/B as important features for the catalytic activity was increased significantly by modifications. The catalytic activity in citronellal conversion feasibility of the materials was examined systemically by evaluating the effects of pillarization and Pt dispersion on bifunctional catalytic activity of citronellal conversion by a tandem cyclization-hydrogenation conversion assisted by microwave irradiation. Bifunctionality of the catalysts in the catalytic testing was indicated from the total conversion parameter as well as selectivity to produce isopulegol and menthol from cyclization and cyclization-hydrogenation schemes. It is suggested that the presence of Pt in catalyst plays important role for hydrogenation step in producing menthol.

Keywords

Cyclization Hydrogenation Pillared clay Pillarization Platinum

Fatimah, I., Yudha, S. P., N.S., H. B., Ulya, R., & Rubiyanto, D. (2016). Effect of Pt on Catalytic Activity of Al- and Zr-Pillared Smectite. Asian Journal of Chemistry, 28(11), 2365–2370. https://doi.org/10.14233/ajchem.2016.19879

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References

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References

N.R. Sanabria, R. Molina and S. Moreno, Int. J. Photoenergy, Article ID 864104 (2012); doi:10.1155/2012/864104.

A. Aznárez, R. Delaigle, P. Eloy, E.M. Gaigneaux, S.A. Korili and A. Gil, Catal. Today, 246, 15 (2015); doi:10.1016/j.cattod.2014.07.024.

E.A. Emam, ARPN J. Sci., 3, 359 (2013).

H. Lu, X. Yang, G. Gao, K. Wang, Q. Shi, J. Wang, C. Han, J. Liu, M. Tong, X. Liang and C. Li, Int. J. Hydrogen Energy, 39, 18894 (2014); doi:10.1016/j.ijhydene.2014.09.076.

M.L. Pinto, J. Marques and J. Pires, Sep. Purif. Technol., 98, 337 (2012); doi:10.1016/j.seppur.2012.07.003.

M.L. Pinto and J. Pires, Micropor. Mesopor. Mater., 151, 403 (2012); doi:10.1016/j.micromeso.2011.10.002.

A.H. Pizarro, V.M. Monsalvo, C.B. Molina, A.F. Mohedano and J.J. Rodriguez, Chem. Eng. J., 273, 363 (2015); doi:10.1016/j.cej.2015.03.072.

N. Tangchupong, W. Khaodee, B. Jongsomjit, N. Laosiripojana, P. Praserthdam and S. Assabumrungrat, Fuel Process. Technol., 91, 121 (2010); doi:10.1016/j.fuproc.2009.09.003.

G.H. Wang, M.D. Sun, W.B. Li, Y.Z. Lu, X.Q. Liu, J. Wang, H. Hu, Q. Liu and T.T. Huang, Adv. Mater. Res., 581-582, 723 (2012); doi:10.4028/www.scientific.net/AMR.581-582.723.

J. Li, Z. Jiang, Z. Hao, X. Xu and Y. Zhuang, J. Mol. Catal. Chem., 225, 173 (2005); doi:10.1016/j.molcata.2004.08.040.

A. Gil, M.A. Vicente, J.-F. Lambert and L.M. Gandía, Catal. Today, 68, 41 (2001); doi:10.1016/S0920-5861(01)00321-2.

N.R. Sanabria, M.A. Centeno, R. Molina and S. Moreno, Appl. Catal. A, 356, 243 (2009); doi:10.1016/j.apcata.2009.01.013.

V. Ramaswamy, S. Malwadkar and S. Chilukur, Appl. Catal. B, 84, 21 (2008); doi:10.1016/j.apcatb.2008.02.023.

P. Mertens, F. Verpoort, A. Parvulescu and D. Devos, J. Catal., 243, 7 (2006); doi:10.1016/j.jcat.2006.06.017.

K.A. da Silva Rocha, P.A. Robles-Dutenhefner, E.M.B. Sousa, E.F. Kozhevnikova, I.V. Kozhevnikov and E.V. Gusevskaya, Appl. Catal. B, 317, 171 (2007); doi:10.1016/j.apcata.2006.10.019.

A.M. Balu, J.M. Campelo, R. Luque and A.A. Romero, Org. Biomol. Chem., 8, 2845 (2010); doi:10.1039/c003600e.

D.T. Yazici and C. Bilgiç, Surf. Interface Anal., 42, 959 (2010); doi:10.1002/sia.3474.

M. Yurdakoc, M. Akcay, Y. Tonbul and K. Yurdakoc, Turk. J. Chem., 23, 319 (1999).

B. Tyagi, C. Chudasama and R. Jasra, Appl. Clay Sci., 31, 16 (2006); doi:10.1016/j.clay.2005.07.001.

Issue

Vol. 28 No. 11 (2016): Vol 28 Issue 11

Effect of Pt on Catalytic Activity of Al- and Zr-Pillared Smectite

Corresponding Author(s) : Is Fatimah

Abstract

Keywords

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