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Vol. 24 No. 11 (2012): Vol 24 Issue 11

Synthesis, Characterization, Thermal Stability and Decomposition Mechanism of [Ru(C12H8N2)3](C4H2O4)(C4H3O4)(C4H4O4)·4H2O

Miao Shui
The State Key Laboratory Base of Novel Functional Materials and Preparation Science, Faculty of Materials Science and Chemical Engineering, Ningbo 315211, P.R. China
Jie Shu
The State Key Laboratory Base of Novel Functional Materials and Preparation Science, Faculty of Materials Science and Chemical Engineering, Ningbo 315211, P.R. China
Rongsheng Li
The State Key Laboratory Base of Novel Functional Materials and Preparation Science, Faculty of Materials Science and Chemical Engineering, Ningbo 315211, P.R. China
Yue Song
The State Key Laboratory Base of Novel Functional Materials and Preparation Science, Faculty of Materials Science and Chemical Engineering, Ningbo 315211, P.R. China
Yuanlong Ren
The State Key Laboratory Base of Novel Functional Materials and Preparation Science, Faculty of Materials Science and Chemical Engineering, Ningbo 315211, P.R. China
Qingchun Wang
The State Key Laboratory Base of Novel Functional Materials and Preparation Science, Faculty of Materials Science and Chemical Engineering, Ningbo 315211, P.R. China

Corresponding Author(s) : Miao Shui

shuimiao@nbu.edu.cn

Asian Journal of Chemistry, Vol. 24 No. 11 (2012): Vol 24 Issue 11

Abstract

A new type of Ru(III) complex [Ru(C12H8N2)3](C4H2O4)(C4H3O4)(C4H4O4)·4H2O is synthesized and characterized. Single-crystal X-ray diffraction shows that the complex belongs to triclinic system, space group P-1, Mr =1058.94 and the cell parameters are a = 12.057(2) Å, b = 12.450(3) Å, c =17.110(3) Å, a = 76.95(3)º, b = 89.87(3)º, g = 63.82(3)º, V = 2231.5(8) Å3, Z = 2, Dc = 1.576 g/cm3, F(000) = 1086. The thermal stability and decomposition behaviour of the complex is intensively investigated by the method of masterplot, Coats and Redfern and Achar, Brindley and Sharp.

Keywords

Masterplot Ru(III) complex Crystal structure Thermal analysis
Shui, M., Shu, J., Li, R., Song, Y., Ren, Y., & Wang, Q. (2012). Synthesis, Characterization, Thermal Stability and Decomposition Mechanism of [Ru(C12H8N2)3](C4H2O4)(C4H3O4)(C4H4O4)·4H2O. Asian Journal of Chemistry, 24(11), 4858–4862. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/9781
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