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Vol. 28 No. 9 (2016): Vol 28 Issue 9

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Analysis of Chlorpyrifos in Water, Soil and Cabbage Samples by Solid Phase Microextraction and Gas Chromatography/Mass Spectrometry

https://doi.org/10.14233/ajchem.2016.19864
Hui Xie
Key Laboratory of Agricultural Environment in Universities of Shandong, Shandong Agricultural University, Taian 271018, P.R. China; College of Resources and Environment, Shandong Agricultural University, Taian 271018, P.R. China
Xiaomin Du
College of Resources and Environment, Shandong Agricultural University, Taian 271018, P.R. China

Corresponding Author(s) : Hui Xie

huixie@sdau.edu.cn

Asian Journal of Chemistry, Vol. 28 No. 9 (2016): Vol 28 Issue 9

Abstract

The feasibility of solid phase microextraction combined gas chromatography/mass spectrometry for determination of organo phosphorus pesticide chlorpyrifos in the water, soil and cabbage samples is evaluated. Solid phase microextraction analyses were carried out with polydimethylsiloxane and polyacrylate fibers. The chlorpyrifos was extracted with direct solid phase microextraction by inserting the fiber through the cap and exposing it to the sample for 1 h. The extraction efficiency of polydimethylsiloxane fiber is 1.5 times in the water and 2 times in the soil comparing to polyacrylate fiber. Good linearity (r > 0.9985) is observed in the 0.05-10 mg L-1 concentration range in the water sample, the limit of detection using the proposed method in the water was 0.05 mg L-1; linearity range (r > 0.9982) was better in the 0.01-5 mg kg-1 concentration range in the soil sample, the limit of detection was 0.01 mg kg-1; linearity range in the cabbage sample (r > 0.9979) was better also in the 0.01-5 mg kg-1 concentration range, detection limit of chlorpyrifos in the cabbage was 0.01 mg kg-1. Experimental results confirmed the usefulness of the proposed method.

Keywords

Organophosphate insecticide SPME GC/MS
Xie, H., & Du, X. (2016). Analysis of Chlorpyrifos in Water, Soil and Cabbage Samples by Solid Phase Microextraction and Gas Chromatography/Mass Spectrometry. Asian Journal of Chemistry, 28(9), 1992–1996. https://doi.org/10.14233/ajchem.2016.19864
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References
  1. D. Simon, S. Helliwell and K. Robards, Anal. Chim. Acta, 360, 1 (1998); doi:10.1016/S0003-2670(97)00680-6.
  2. M.A. Randhawa, F.M. Anjum, A. Ahmed and M.S. Randhawa, Food Chem., 103, 1016 (2007); doi:10.1016/j.foodchem.2006.10.001.
  3. R. Li, L. He, W. Wei, L.L. Hao, X.F. Ji, Y. Zhou and Q. Wang, Food Contr., 51, 212 (2015); doi:10.1016/j.foodcont.2014.11.023.
  4. J.L. Schardein and A.R. Scialli, Reprod. Toxiocol., 13, 1 (1999); doi:10.1016/S0890-6238(98)00065-3.
  5. S.C. Gupta, M. Mishra, A. Sharma, T.G.R. Deepak Balaji, R. Kumar, R.K. Mishra and D.K. Chowdhuri, Ecotoxicol. Environ. Saf., 73, 1415 (2010); doi:10.1016/j.ecoenv.2010.05.013.
  6. V. Sotomayor, C. Lascano, A.M.P. de D’Angelo and A. Venturino, Environ. Toxicol. Chem., 31, 2052 (2012); doi:10.1002/etc.1921.
  7. S.S. Ali, R.U. Haq, M. Khaliq and A.R. Shakoori, Punjab Univ. J. Zool., 12, 31 (1997).
  8. Y. He, Q.C. Wang and J. Yu, Shanghai Environ. Sci., 22, 687 (2003).
  9. Q.M. Zhang, L.S. Zhu and C. Han, J. Wang, H. Xie, J. Wang and S. Sun, J. Food Agric. Environ., 9, 659 (2011).
  10. H. Xie, L.S. Zhu, J. Wang and J.H. Wang, Environ. Chem., 31, 1268 (2012).
  11. S. Samadi, H. Sereshti and Y. Assadi, J. Chromatogr. A, 1219, 61 (2012); doi:10.1016/j.chroma.2011.11.019.
  12. M.M. Sanagi, S. Salleh, W.A.W. Ibrahim, A.A. Naim, D. Hermawan, M. Miskam, I. Hussain and H.Y. Aboul-Enein, J. Food Compos. Anal., 32, 155 (2013); doi:10.1016/j.jfca.2013.09.001.
  13. Z. Wang, X. Zhao, X. Xu, L. Wu, R. Su, Y. Zhao, C. Jiang, H. Zhang, Q. Ma, C. Lu and D. Dong, Anal. Chim. Acta, 760, 60 (2013); doi:10.1016/j.aca.2012.11.031.
  14. J. He, L.X. Song, S. Chen, Y. Li, H. Wei, D. Zhao, K. Gu and S. Zhang, Food Chem., 187, 331 (2015); doi:10.1016/j.foodchem.2015.04.069.
  15. K. Ahmadi, Y. Abdollahzadeh, M. Asadollahzadeh, A. Hemmati, H. Tavakoli and R. Torkaman, Talanta, 137, 167 (2015); doi:10.1016/j.talanta.2015.01.031.
  16. C.H. Jia, X.D. Zhu, E.C. Zhao, P. Yu, M. He and L. Chen, Chromatographia, 72, 1219 (2010); doi:10.1365/s10337-010-1766-8.
  17. Y.P. Zhang, J. Yang and R.H. Shi, Q. Su, Y. Gao and X. Zhu, Chromatographia, 73, 385 (2011); doi:10.1007/s10337-010-1885-2.
  18. J.M. Keller, R.F. Swarthout, B.K.R. Carlson, J. Yordy, A. Guichard, M.M. Schantz and J.R. Kucklick, Anal. Bioanal. Chem., 393, 747 (2009); doi:10.1007/s00216-008-2453-6.
  19. M.H. Naeeni, Y. Yamini and M. Rezaee, J. Supercrit. Fluids, 57, 219 (2011); doi:10.1016/j.supflu.2011.03.005.
  20. G. Wu, X.X. Bao, S.H. Zhao, J. Wu, A. Han and Q. Ye, Food Chem., 126, 646 (2011); doi:10.1016/j.foodchem.2010.10.105.
  21. F. Hernández, E. Pitarch, J. Beltran and F.J. López, J. Chromatogr. B Analyt. Technol. Biomed. Life Sci., 769, 65 (2002); doi:10.1016/S1570-0232(01)00627-4.
  22. J. Castro, R.A. Perez, C. Sanchez-Brunete and J.L. Tadeo, Chromatographia, 53(S1), 361 (2001); doi:10.1007/BF02490357.
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