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Vol. 24 No. 10 (2012): Vol 24 Issue 10

Structural Aspects of Diaquotetrakis(imidazole)cobalt(II) Chloride

P. Meera
Post Graduate & Research Department of Chemistry, Loyola College (Autonomous), Chennai600 034, India
M. Amutha Selvi
Post Graduate & Research Department of Chemistry, Loyola College (Autonomous), Chennai600 034, India
A. Dayalan
Post Graduate & Research Department of Chemistry, Loyola College (Autonomous), Chennai600 034, India

Corresponding Author(s) : A. Dayalan

dayalan77@gmail.com

Asian Journal of Chemistry, Vol. 24 No. 10 (2012): Vol 24 Issue 10

Abstract

A pink coloured cobalt(II) complex viz., [Co(Imi)4(H2O)2]Cl2 was prepared by mixing cobalt(II) chloride with imidazole in 1:4 molar ratio in acetone. The complex was characterized by UV, IR, TG-DTA and single crystal XRD studies. The EPR spectrum of the complex proved its paramagnetic nature which was further analyzed by magnetic susceptibility studies. Susceptibility measurements showed the presence of three unpaired electrons accounting for the high spin nature of the complex.

Keywords

Imidazole EPR Magnetic susceptibility Cobalt(II) complexes
Meera, P., Amutha Selvi, M., & Dayalan, A. (2012). Structural Aspects of Diaquotetrakis(imidazole)cobalt(II) Chloride. Asian Journal of Chemistry, 24(10), 4576–4578. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/9709
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