Synthesis, Characterization and Photocatalytic Activity of Fe3+ Doped Mesoporous TiO2 Prepared by a Modified Sol-Gel Process

Abstract

Fe³⁺ doped mesoporous TiO₂ was prepared by a modified sol-gel process. The obtained samples were characterized by X-ray diffraction, N₂ adsorption, FT-IR, UV-VIS spectroscopy and XPS analysis. The prepared TiO₂ samples were around 10-15 nm in size with narrow particle size distribution. The Ti-O-Si bond formed between TiO₂ and MCM-41 fixed the TiO₂ on the MCM-41 surface which restricted the agglomeration and growth of the TiO₂ particles. The performance in photocatalytic degradation of methylene blue under visible light indicated that the addition of MCM-41 greatly improved the photocatalytic activity of prepared TiO₂ catalysts. The doping content of Fe³⁺ and calcination temperature significantly influenced the photocatalytic activity of TiO₂ catalysts.