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Adsorptive Behaviour, Isothermal and Kinetic Modeling Studies in Removal of Copper, Nickel, Zinc and Lead from Aqueous Solutions using Carissa carandas and Syzygium aromaticum: A Comparative Analysis
Corresponding Author(s) : Sanjay K. Sharma
Asian Journal of Chemistry,
Vol. 28 No. 9 (2016): Vol 28 Issue 9
Abstract
The present study focused on the use of Carissa carandas leaves and Syzygium aromaticum (clove) powder as biosorbents for the removal of copper(II), nickel(II), zinc(II) and lead(II) from aqueous solutions. Results were investigated in batch mode and the observations were correlated with the pH variation, agitation time, dose of the adsorbent and initial metal ion concentration in the solution. Biosorbent Carissa carandas leaf powder showed higher sorption efficiency than that of biosorbent Syzygium aromaticum powder under identical experimental conditions. Langmuir isotherm models observed best equilibrium data in all four metals and both biosorbents and pseudo second order kinetics model perfectly matched in both biosorbents in all four metal ions.
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- D. Hinrichsen and H. Tacio, The Coming Freshwater Crisis is Already Here. The Linkages Between Population and Water, Woodrow Wilson International Center for Scholars; Washington, DC (2002).
- S. Mahiya, G. Lofrano and S.K. Sharma, Int. J. Chem., 3, 132 (2014).
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- K. Schumann, Z. Ernahrungswiss, 29, 54 (1990); doi:10.1007/BF02019535.
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- USEPA, Drinking Water Criteria Document for Copper, US Environmental Protection Agency, Office of Health and Environmental Assessment, Environmental Criteria and Assessment Office, Cincinnati, OH, USA (1987).
- WHO (World Health Organization), Guidelines for Drinking-Water Quality, Incorporating First addendum to third Edition, World Health Organization, Geneva, Switzerland, edn 3, vol. 1 (2006).
- WHO (World Health Organization), Guidelines for Drinking-Water Quality, Recommendations, Geneva, Switzerland, Vol. 1, edn 2 (1993).
- WHO Guidelines for Drinking-water Quality (GDWQ), edn 4 (2011); ISBN: 978 92 4 154815 1.
- WHO, Environmental Health Criteria 108, Nickel, WHO, Geneva, Switzerland (1991).
- JECFA, Evaluation of Certain Food Additives and Contaminants: Sixty-First Meeting of the Joint FAO/WHO Expert Committee on Food Additives, Geneva, World Health Organization (WHO Technical Report Series No. 922), (2004).
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- P.S. Kumar, A. Saravanan, P.S. Rajan and M. Yashwanthraj, Textiles Clothing Sustain., 2:3, 1 (2016); doi:10.1186/s40689-016-0014-5.
- M.A. Barakat, Arabian J. Chem., 4, 361 (2011); doi:10.1016/j.arabjc.2010.07.019.
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- D. Mani and C. Kumar, Int. J. Environ. Sci. Technol., 11, 843 (2014); doi:10.1007/s13762-013-0299-8.
- A. Fatehizadeh, S. Rahimi, M. Ahmadian, R. Barati, N. Yousefi, S.P. Moussavi, K. Rahimi, S. Reshadat, S.R. Ghasemi and N.R. Gilan, Int. J. Environ. Health Eng., 3, 31 (2014); doi:10.4103/2277-9183.139756.
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- A. Hernández-Estévez and E. Cristiani-Urbina, Environ. Monit. Assess., 186, 7987 (2014); doi:10.1007/s10661-014-3981-5.
- J. Komkiene and E. Baltrenaite, Int. J. Environ. Sci. Technol., 13, 471 (2016);
- doi:10.1007/s13762-015-0873-3.
- M.N. Zafar, I. Aslam, R. Nadeem, S. Munir, U.A. Rana and S.U.-D. Khan, J. Taiwan Institute Chem. Eng., 46, 82 (2015); doi:10.1016/j.jtice.2014.08.034.
- K. Swarnalatha and S. Ayoob, Int. J. Sustainable Eng., 1 (2016); doi:10.1080/19397038.2016.1152323.
- Q. Li, B. Chen, P. Lin, J. Zhou, J. Zhan, Q. Shen and X. Pan, Int. J. Phytoremediation, 18, 103 (2016); doi:10.1080/15226514.2014.898017.
- G. Yuvaraja, S.M. Venkata, M. Naushad and A. Krishnaiah, Desalination Water Treat., 54, 200 (2015); doi:10.1080/19443994.2014.880160.
- T. Cerchiara, A. Chidichimo, A. Aloise and G. Chidichimo, J. Nat. Fibers, 13, 77 (2016); doi:10.1080/15440478.2014.984059.
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References
D. Hinrichsen and H. Tacio, The Coming Freshwater Crisis is Already Here. The Linkages Between Population and Water, Woodrow Wilson International Center for Scholars; Washington, DC (2002).
S. Mahiya, G. Lofrano and S.K. Sharma, Int. J. Chem., 3, 132 (2014).
F. Fu and Q. Wang, J. Environ. Manage.,92, 407 (2011); doi:10.1016/j.jenvman.2010.11.011.
L.M. Plum, L. Rink and H. Haase, Int. J. Environ. Res. Public Health, 7, 1342 (2010); doi:10.3390/ijerph7041342.
R.K. Gautam, S.K. Sharma, S. Mahiya and M.C. Chattopadhyay, Contamination of Heavy Metals in Aquatic Media: Transport, Toxicity and Technologies for Remediation, Royal Society of Chemistry Publications, UK (2014).
C.K. Jain, D.C. Singhal and M.K. Sharma, J. Hazard. Mater., 114, 231 (2004); doi:10.1016/j.jhazmat.2004.09.001.
C.M.A. Ademorati, Environmental Chemistry and Toxicology, Foludex Press Ltd., Ibadan (1996).
K. Schumann, Z. Ernahrungswiss, 29, 54 (1990); doi:10.1007/BF02019535.
USEPA (United States Environmental Protection Agency), Mercury Study Report to Congress, Volume VII: Characterization of Human Health and Wildlife Risks from Mercury Exposure in the United States. p. 19; http://www.epa.gov/ttn/oarpg/t3/reports/volume7.pdf accessed 8 November (2006).
USEPA, Drinking Water Criteria Document for Copper, US Environmental Protection Agency, Office of Health and Environmental Assessment, Environmental Criteria and Assessment Office, Cincinnati, OH, USA (1987).
WHO (World Health Organization), Guidelines for Drinking-Water Quality, Incorporating First addendum to third Edition, World Health Organization, Geneva, Switzerland, edn 3, vol. 1 (2006).
WHO (World Health Organization), Guidelines for Drinking-Water Quality, Recommendations, Geneva, Switzerland, Vol. 1, edn 2 (1993).
WHO Guidelines for Drinking-water Quality (GDWQ), edn 4 (2011); ISBN: 978 92 4 154815 1.
WHO, Environmental Health Criteria 108, Nickel, WHO, Geneva, Switzerland (1991).
JECFA, Evaluation of Certain Food Additives and Contaminants: Sixty-First Meeting of the Joint FAO/WHO Expert Committee on Food Additives, Geneva, World Health Organization (WHO Technical Report Series No. 922), (2004).
JECFA, Methylmercury, In: Safety Evaluation of Certain Food Additives and Contaminants, Report of the 61st Joint FAO/WHO Expert Committee on Food Additives. Geneva, World Health Organization, International Programme on Chemical Safety, WHO Technical Report Series, pp 132-139 (2004); http://whqlibdoc.who.int/trs/WHO_TRS_922.pdf.
P.S. Kumar, A. Saravanan, P.S. Rajan and M. Yashwanthraj, Textiles Clothing Sustain., 2:3, 1 (2016); doi:10.1186/s40689-016-0014-5.
M.A. Barakat, Arabian J. Chem., 4, 361 (2011); doi:10.1016/j.arabjc.2010.07.019.
M.A. Jayasri and K. Suthindhiran, Appl. Water Sci., 1 (2016); doi:10.1007/s13201-015-0376-x.
S. Mahiya, G. Lofrano and S.K. Sharma, Chem. Sci. Transac., 3, 1228 (2014); doi:10.7598/cst2014.884.
D. Mani and C. Kumar, Int. J. Environ. Sci. Technol., 11, 843 (2014); doi:10.1007/s13762-013-0299-8.
A. Fatehizadeh, S. Rahimi, M. Ahmadian, R. Barati, N. Yousefi, S.P. Moussavi, K. Rahimi, S. Reshadat, S.R. Ghasemi and N.R. Gilan, Int. J. Environ. Health Eng., 3, 31 (2014); doi:10.4103/2277-9183.139756.
R.A.K. Rao and S. Ikram, Int. J. Environ. Eng., 7, 179 (2015); doi:10.1504/IJEE.2015.069809.
A. Razzaz, S. Ghorban, L. Hosayni, M. Irani and M. Aliabadi, J. Taiwan Institute Chem. Eng., 58, 333 (2016); doi:10.1016/j.jtice.2015.06.003.
A. Hernández-Estévez and E. Cristiani-Urbina, Environ. Monit. Assess., 186, 7987 (2014); doi:10.1007/s10661-014-3981-5.
J. Komkiene and E. Baltrenaite, Int. J. Environ. Sci. Technol., 13, 471 (2016);
doi:10.1007/s13762-015-0873-3.
M.N. Zafar, I. Aslam, R. Nadeem, S. Munir, U.A. Rana and S.U.-D. Khan, J. Taiwan Institute Chem. Eng., 46, 82 (2015); doi:10.1016/j.jtice.2014.08.034.
K. Swarnalatha and S. Ayoob, Int. J. Sustainable Eng., 1 (2016); doi:10.1080/19397038.2016.1152323.
Q. Li, B. Chen, P. Lin, J. Zhou, J. Zhan, Q. Shen and X. Pan, Int. J. Phytoremediation, 18, 103 (2016); doi:10.1080/15226514.2014.898017.
G. Yuvaraja, S.M. Venkata, M. Naushad and A. Krishnaiah, Desalination Water Treat., 54, 200 (2015); doi:10.1080/19443994.2014.880160.
T. Cerchiara, A. Chidichimo, A. Aloise and G. Chidichimo, J. Nat. Fibers, 13, 77 (2016); doi:10.1080/15440478.2014.984059.
S.K. Sharma, S. Mahiya and G. Lofrano, Appl. Water Sci., 1 (2015); doi:10.1007/s13201-015-0359-y.