Kinetic Spectrophotometric Determination of Copper in Food
Corresponding Author(s) : Qing-Zhou Zhai
Asian Journal of Chemistry,
Vol. 24 No. 7 (2012): Vol 24 Issue 7
Abstract
Copper is an important metallic element in nature. It is also one kind of important trace element for life body. The study and establishment of a method for the determination of copper has important significance. A new kinetic-spectrophotometric method is proposed for the determination of copper in present study. The method is based on the catalytic effect of copper(II) on the oxidation of dibromo-p-chloro-chlorophosphonazo (DBC-CPA) by hydrogen peroxide in 1 mol L-1 phosphoric acid medium. Copper can be spectrophotometrically determined by measuring the decrease in the absorbance of dibromo-p-chloro-chlorophosphonazo at the wavelength of 550 nm using the fixed-time method. The linear range of the present method is 0.1-2.0 μg in 10 mL of solution and the limit of detection is 9.05 ng mL-1. The method has been successfully applied to the determination of copper in apple and banana. The relative standard deviations of 13 determinations of the method were 0.82-1.03 %. The recoveries of the present method were 101.3-103.6 %.
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