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Enzymatic Synthesis of Biodiesel from Jatropha tanjorensis Ellis and Saroja and its Potential as Biodiesel Feedstock
Corresponding Author(s) : K.P. Arun
Asian Journal of Chemistry,
Vol. 28 No. 8 (2016): Vol 28 Issue 8
Abstract
21st century has almost become "Green century" with an increased demand for plant products (bioenergy-oil). Hence, to develop a natural biodiesel feedstock, common species of Jatropha in and around Thanjavur is selected based on its enriched monoalkyl ester content which could be a good source for generating biofuels. Tanjorensis seed oil were extracted and analyzed for its physico-chemical properties such as % free fatty acid, acid value iodine, peroxide, saponification values. P. aeruginosa crude lipase treated transesterification followed by GC-MS analysis of oil proved that oleic acid (37.3 %) and linoleic acid (33.3 %) were the principal fatty acids while palmitic acid and stearic acid being the major saturated fatty acids. Oil contents of Tanjorensis seed oil were comparable with the oil extracted from other species of Jatropha and were found to be close to oil from Jatropha curcas. Tanjorensis seed oil extracts could be useful in industrial applications and as a biodiesel feedstock.
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- A.E. Atabani, A.S. Silitonga, H.C. Ong, T.M.I. Mahlia, H.H. Masjuki, I.A. Badruddin and H. Fayaz, Renew. Sustain. Energy Rev., 18, 211 (2013); doi:10.1016/j.rser.2012.10.013.
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- G. Knothe, J.V. Gerpen and J. Krahl, The Biodiesel Handbook, AOCS Press, Champaign, USA (2005).
- G. Knothe, J. Am. Oil Chem. Soc., 83, 823 (2006); doi:10.1007/s11746-006-5033-y.
- L.A. Nelson, T.A. Foglia and W.N. Marmer, J. Am. Oil Chem. Soc., 73, 1191 (1996); doi:10.1007/BF02523383.
- E.T. Akintayo, Bioresour. Technol., 92, 307 (2004); doi:10.1016/S0960-8524(03)00197-4.
- S. Shah, A. Sharma and M.N. Gupta, Ind. Crops Prod., 20, 275 (2004); doi:10.1016/j.indcrop.2003.10.010.
- K.M. Mathew, An Excursion Flora of Central Tamil Nadu, The Raphinet Herbarium, St Joseph's College, Trichy, Tamilnadu, INDIA, p. 463 (1991).
- K.P. Arun, N. Ravichandran, R. Vajrai and P. Brindha. Int. J. Pharm. Pharm. Sci., 4 (Suppl. 2), 139 (2012).
- R.M. Berka and M.L. Vasil, J. Bacteriol., 152, 239 (1982).
- I. Ohkawa, S. Shiga and M. Kageyama, J. Biochem., 86, 643 (1979).
- O.H. Lowry, N.S. Rosenbrough, A.L. Farr and R.J. Randall, J. Biol. Chem., 193, 1083 (1951).
- Y. Xu, W. Du, J. Zeng and D. Liu, Biocatal. Biotransform., 22, 45 (2004); doi:10.1080/10242420410001661222.
- K. Ainie, W.L. Siew, Y.A. Tan, A.I. Nor, Y. Mohtar, T.S. Tang and A.I. Nurul, Compendium of Test on Palm Oil Products, Palm Kernel Products, Fatty Acids, Food Related Products and Others, Malaysian Palm Oil Board (MPOB), Selangor, Malaysia (2004).
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- F.D. Gunstone, The Chemistry of Oils and Fats: Sources, Composition, Properties and Uses, Blackwell Publishing Ltd., London (1994).
- M.M. Azam, A. Waris and N.M. Nahar, Biomass Bioenergy, 29, 293 (2005); doi:10.1016/j.biombioe.2005.05.001.
- N.B. Kyriakidis and T. Katsiloulis, J. Am. Oil Chem. Soc., 77, 1235 (2000); doi:10.1007/s11746-000-0193-3.
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- M. Mittelbach, The High Flexibility of Small Scale Bio-Diesel Plants Production of methyl esters in High Quality using Various Feedstocks, Proc. 2nd European Motor Biofuels Forum, Graz, Austria, pp. 183-187 (1996).
- J. Goodrum, Biomass Bioenergy, 22, 205 (2002); doi:10.1016/S0961-9534(01)00074-5.
- M. Mittelbach and C. Remschmidt, Biodiesel–The Comprehensive Handbook, edn 2, (2004).
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- M. Rodríguez-Acosta, K. Vega-Flores, V.H. De Gante-Cabrera and J. Jiménez-Ramírez, Polibotánica, 28, 37 (2009).
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References
A.E. Atabani, A.S. Silitonga, H.C. Ong, T.M.I. Mahlia, H.H. Masjuki, I.A. Badruddin and H. Fayaz, Renew. Sustain. Energy Rev., 18, 211 (2013); doi:10.1016/j.rser.2012.10.013.
A. Demirbas, Energy Convers. Manage., 44, 2093 (2003); doi:10.1016/S0196-8904(02)00234-0.
G. Knothe, J.V. Gerpen and J. Krahl, The Biodiesel Handbook, AOCS Press, Champaign, USA (2005).
G. Knothe, J. Am. Oil Chem. Soc., 83, 823 (2006); doi:10.1007/s11746-006-5033-y.
L.A. Nelson, T.A. Foglia and W.N. Marmer, J. Am. Oil Chem. Soc., 73, 1191 (1996); doi:10.1007/BF02523383.
E.T. Akintayo, Bioresour. Technol., 92, 307 (2004); doi:10.1016/S0960-8524(03)00197-4.
S. Shah, A. Sharma and M.N. Gupta, Ind. Crops Prod., 20, 275 (2004); doi:10.1016/j.indcrop.2003.10.010.
K.M. Mathew, An Excursion Flora of Central Tamil Nadu, The Raphinet Herbarium, St Joseph's College, Trichy, Tamilnadu, INDIA, p. 463 (1991).
K.P. Arun, N. Ravichandran, R. Vajrai and P. Brindha. Int. J. Pharm. Pharm. Sci., 4 (Suppl. 2), 139 (2012).
R.M. Berka and M.L. Vasil, J. Bacteriol., 152, 239 (1982).
I. Ohkawa, S. Shiga and M. Kageyama, J. Biochem., 86, 643 (1979).
O.H. Lowry, N.S. Rosenbrough, A.L. Farr and R.J. Randall, J. Biol. Chem., 193, 1083 (1951).
Y. Xu, W. Du, J. Zeng and D. Liu, Biocatal. Biotransform., 22, 45 (2004); doi:10.1080/10242420410001661222.
K. Ainie, W.L. Siew, Y.A. Tan, A.I. Nor, Y. Mohtar, T.S. Tang and A.I. Nurul, Compendium of Test on Palm Oil Products, Palm Kernel Products, Fatty Acids, Food Related Products and Others, Malaysian Palm Oil Board (MPOB), Selangor, Malaysia (2004).
H.E. Cox and D. Pearson, The Chemical Analysis of Foods, Chemical Publishing Co. Inc., New York, p. 420 (1962).
J. Martinezherrera, P. Siddhuraju, G. Francis, G. Davilaortiz and K. Becker, Food Chem., 96, 80 (2006); doi:10.1016/j.foodchem.2005.01.059.
M.K. Naik, L.C. Meher, A.K. Dalai and S.N. Naik, in ed.: A. Pandey, Biodiesel Production using Karanja (Pongamia pinnata) and Jatropha (Jatropha curcas) Seed Oil, In: Handbook of Plant-Based Biofuels, CRC Press: Boca Raton, Chap. 18, p. 255-266 (2008).
F.D. Gunstone, The Chemistry of Oils and Fats: Sources, Composition, Properties and Uses, Blackwell Publishing Ltd., London (1994).
M.M. Azam, A. Waris and N.M. Nahar, Biomass Bioenergy, 29, 293 (2005); doi:10.1016/j.biombioe.2005.05.001.
N.B. Kyriakidis and T. Katsiloulis, J. Am. Oil Chem. Soc., 77, 1235 (2000); doi:10.1007/s11746-000-0193-3.
G. Knothe, J. Am. Oil Chem. Soc., 79, 847 (2002); doi:10.1007/s11746-002-0569-4.
M. Mittelbach, The High Flexibility of Small Scale Bio-Diesel Plants Production of methyl esters in High Quality using Various Feedstocks, Proc. 2nd European Motor Biofuels Forum, Graz, Austria, pp. 183-187 (1996).
J. Goodrum, Biomass Bioenergy, 22, 205 (2002); doi:10.1016/S0961-9534(01)00074-5.
M. Mittelbach and C. Remschmidt, Biodiesel–The Comprehensive Handbook, edn 2, (2004).
M.J. Ramos, C.M. Fernández, A. Casas, L. Rodríguez and Á. Pérez, Bioresour. Technol., 100, 261 (2009); doi:10.1016/j.biortech.2008.06.039.
M. Rodríguez-Acosta, K. Vega-Flores, V.H. De Gante-Cabrera and J. Jiménez-Ramírez, Polibotánica, 28, 37 (2009).
M. Rodríguez-Acosta, J. Sandoval-Ramírez and R. Zeferino-Díaz, J. Mex. Chem. Soc., 54, 88 (2010).
F.D. Gunstone, Rapeseed and Canola Oil: Production, Processing, Properties and Uses, Blackwell Publishing Ltd., London (2004).
D.O. Edem, Plant Foods Hum. Nutr., 57, 319 (2002); doi:10.1023/A:1021828132707.