Issue

Vol. 24 No. 7 (2012): Vol 24 Issue 7

Molten Salt Synthesis and Crystal Structure of a Novel Quinary Metal Chalcogenide

Han-Mao Kuang
School of Chemistry and Chemical Engineering, Institute of Applied Chemistry, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University, Ji'an, Jiangxi, 343009, P.R. China
Zhi-Gang Luo
School of Chemistry and Chemical Engineering, Institute of Applied Chemistry, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University, Ji'an, Jiangxi, 343009, P.R. China
Hua-Long Chen
School of Chemistry and Chemical Engineering, Institute of Applied Chemistry, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University, Ji'an, Jiangxi, 343009, P.R. China
Kun-Yu Wei
School of Chemistry and Chemical Engineering, Institute of Applied Chemistry, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University, Ji'an, Jiangxi, 343009, P.R. China
Wen-Tong Chen
School of Chemistry and Chemical Engineering, Institute of Applied Chemistry, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University, Ji'an, Jiangxi, 343009, P.R. China

Corresponding Author(s) : Wen-Tong Chen

wtchen_2000@yahoo.cn

Asian Journal of Chemistry, Vol. 24 No. 7 (2012): Vol 24 Issue 7

Abstract

An unprecedented quinary metal chalcogenide HgZnCl15Se3S3 (1) has been prepared via a molten salt synthesis method and structurally characterized by X-ray diffractions. Compound 1 crystallizes in the space group P3c1 of the hexagonal system with two formula units in a cell: a = b = 9.3909(3), c = 10.3540(6) Å, V = 790.78(6) Å3, Cl15HgS3Se3Zn, Mr = 1130.77, Dc = 4.749 g/cm3, T = 293(2) K, F(000) = 1030 and R1/wR2 = 0.0500/0.1422 for 3383 observed reflections (I > 2s(I)) and 925 unique reflections. Compound 1 features a novel three-dimensional (3-D) framework structure.

Keywords

Chalcogenide Halide Mercury Selenium Zinc
Kuang, H.-M., Luo, Z.-G., Chen, H.-L., Wei, K.-Y., & Chen, W.-T. (2012). Molten Salt Synthesis and Crystal Structure of a Novel Quinary Metal Chalcogenide. Asian Journal of Chemistry, 24(7), 3022–3024. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/9285
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
Author biographies is not available.
Download
PDF
Statistic
Read Counter : 0 Download : 0