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Vol. 24 No. 6 (2012): Vol 24 Issue 6

One-Pot, Solvent-Free Allylation or Propargylation of Carbonyl Compounds Mediated by the in situ Generated Zn-Ag Couple

Changquan Yu
Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou, P.R. China
Jian Yang
Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou, P.R. China
Lingjie Xia
Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou, P.R. China
Xiuyang Lu
Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou, P.R. China

Corresponding Author(s) : Jian Yang

luck4227@zju.edu.cn

Asian Journal of Chemistry, Vol. 24 No. 6 (2012): Vol 24 Issue 6

Abstract

Zn-Ag couple which was in situ generated by zinc being oxidized with catalytic silver acetate was successfully applied to the one-pot and solvent-free allylation or propargylation of carbonyl compounds, in which high yields, regioselective addition, waste minimization and simple operation can be achieved.

Keywords

Allylation Propargylation Zn-Ag couple One-pot Solvent-free
(1)
Yu, C.; Yang, J.; Xia, L.; Lu, X. One-Pot, Solvent-Free Allylation or Propargylation of Carbonyl Compounds Mediated by the in Situ Generated Zn-Ag Couple. ajc 2012, 24, 2484-2486.
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