Synthesis and Characterization of New vic-Dioximes with Benzo-15-crown-5 Derivatives and Their Nickel(II), Copper(II), Cobalt(II) Complexes
Corresponding Author(s) : Rifat Battaloglu
rbattaloglu@nigde.edu.tr
Asian Journal of Chemistry,
Vol. 24 No. 6 (2012): Vol 24 Issue 6
Abstract
Benzo-15-crown-5-p-toluidino-glyoxime (1) and N(1-naphthyl)amino-benzo-15-crown-5- glyoxime (2) were synthesized by classical methods. Their structures were confirmed by spectral techniques. Both of them were capable of forming complexes with various metal ions (Co2+, Cu2+ and Ni2+). The structure of the complexes was confirmed by FT-IR, mass spectra and elemental analyses.
Keywords
Macrocyclic ether
Cation binding
NMR spectroscopy
Glyoxime
Cation complexes
Solubility
(1)
Battaloglu, R.; Ihsan Pekacar, A.; Kemal Yildiz, Y. Synthesis and Characterization of New Vic-Dioximes With Benzo-15-Crown-5 Derivatives and Their Nickel(II), Copper(II), Cobalt(II) Complexes. ajc 2012, 24, 2377-2379.
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