Synthesis and Toxicity Test of M/Zn(II) Complexes [M = Mn(II), Co(II)] with Pyridine-2,6-dicarboxylic Acid Ligand

F. Martak; W.P. Utomo; Z.V. Nugraheni; P. Budi

doi:10.14233/ajchem.2016.19818

Issue

Vol. 28 No. 8 (2016): Vol 28 Issue 8

Issue Published : April 30, 2016

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis and Toxicity Test of M/Zn(II) Complexes [M = Mn(II), Co(II)] with Pyridine-2,6-dicarboxylic Acid Ligand

https://doi.org/10.14233/ajchem.2016.19818

F. Martak

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Institut Teknologi Sepuluh Nopember, Surabaya 60111, Indonesia

W.P. Utomo

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Institut Teknologi Sepuluh Nopember, Surabaya 60111, Indonesia

Z.V. Nugraheni

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Institut Teknologi Sepuluh Nopember, Surabaya 60111, Indonesia

P. Budi

Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Hasanuddin, Makassar, Indonesia

Corresponding Author(s) : F. Martak

fahima_riza@yahoo.com; fahimahm@chem.its.ac.id

Asian Journal of Chemistry, Vol. 28 No. 8 (2016): Vol 28 Issue 8
Article Published : April 30, 2016

Abstract

Heterodinuclear complexes of Co(II)/Zn(II) and Mn(II)/Zn(II) with pyridine-2,6-dicarboxylic acid as a ligand (H2dipic, dipicolinate) have been synthesized yielding of reddish purple colour of Co(II)/Zn(II) dipicolinic crystal and reddish colour of Mn(II)/Zn(II) dipicolinic crystal. The determination of elements composition (%) of complex compound using atomic absorption spectroscopy and CHN elemental analyzer (C = 28.96; H = 3.47; N = 5.42; Co = 10.15 Mn = 9.47 and Zn = 11.26) showed that the molecular formula of Co(II) complex compound is [Zn(H₂O)₅Co(dipic)₂]·2H₂O, while that of Mn(II) complex compounds is [Zn(H₂O)₅Mn(dipic)₂]·2H₂O. The IR spectrum of the Co(II) and Mn(II) complexes showed a typical vibration absorption in the wavenumber of 3082 cm^-1 indicating of Co(II)/Zn(II) dipicolinic and Mn(II)/Zn(II) dipicolinic have been formed. A brine shrimp lethality test (BSLT), used to determine the toxicity of complexes showed that LC₅₀ of Co(II) complex and Mn(II) complexes were 283.71 and 354.94 mg/L, respectively.

Keywords

Complex compounds Toxicity Paramagnetic H2dipic Zn(II) Mn(II) Co(II) Heterodinuclear

Martak, F., Utomo, W., Nugraheni, Z., & Budi, P. (2016). Synthesis and Toxicity Test of M/Zn(II) Complexes [M = Mn(II), Co(II)] with Pyridine-2,6-dicarboxylic Acid Ligand. Asian Journal of Chemistry, 28(8), 1773–1776. https://doi.org/10.14233/ajchem.2016.19818

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M. Tabatabaee, M. Tahriri, M. Tahriri, Y. Ozawa, B. Neumüller, H. Fujioka and K. Toriumi, Polyhedron, 33, 336 (2012); doi:10.1016/j.poly.2011.11.056.

D. Das and J.B. Baruah, Polyhedron, 31, 361 (2012); doi:10.1016/j.poly.2011.09.039.

Y.G. Huang, D. Yuan, Y. Gong, L.F. Jiang and M. Hong, J. Mol. Struct., 872, 99 (2008); doi:10.1016/j.molstruc.2007.02.020.

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M. Alwathoni, Ph.d. Thesis, Sepuluh Nopember Institute of Technology, Surabaya, Indonesia (2011).

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A.B. Kassegne, Graduate Project (Chem. 774), Template Synthesis and Characterization of Ni(II) and Zn(II) Complexes Derived from Ninhydrin and Ethylenediamine, Department of Chemistry, Addis Ababa University Addis Ababas, Ethiopia (2009).

M. Kalanithi, M.P. Rajarajan, P. Tharmaraj and C.D. Sheela, Spectrochim. Acta A, 87, 155 (2012); doi:10.1016/j.saa.2011.11.031.

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K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compound, John Wiley & Sons Inc., New York, edn 3 (1986)

Issue

Vol. 28 No. 8 (2016): Vol 28 Issue 8

Synthesis and Toxicity Test of M/Zn(II) Complexes [M = Mn(II), Co(II)] with Pyridine-2,6-dicarboxylic Acid Ligand

Corresponding Author(s) : F. Martak

Abstract

Keywords

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