Copyright (c) 2016 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Adsorption of Crystal Violet Dye on Modified Bentonites
Corresponding Author(s) : N.R.E. Radwan
Asian Journal of Chemistry,
Vol. 28 No. 8 (2016): Vol 28 Issue 8
Abstract
The adsorption of basic crystal violet dye on bentonite and four modified bentonite with different fatty acids (bentonite FA1, bentonite FA2, bentonite FA3 and bentonite FA4) was investigated. The surface of each bentonite samples was examined before and after adsorption of dyes by FTIR technique. The effect of pH solution, initial concentration of dye and contact time on the adsorption of basic dye onto bentonites was studied. The results showed that the adsorption capacity of basic crystal violet was high on bentonites and modified bentonites with different degree. The Langmuir and Freundlich adsorption models were used to describe the adsorption process and to determine the isotherm constant. Based on the equilibrium data, which analyzed by two models and correlation coefficient, the Langmuir model was a good fit of experimental data than Freundlich model. This referred to the homogeneous surface for adsorption process.
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M. Turabik, J. Hazard. Mater., 158, 52 (2008); doi:10.1016/j.jhazmat.2008.01.033.
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Q. Li, Q.-Y. Yue, Y. Su, B.-Y. Gao and H.-J. Sun, Chem. Eng. J., 158, 489 (2010); doi:10.1016/j.cej.2010.01.033.
A.S. Özcan, B. Erdem and A. Özcan, J. Colloid Interf. Sci., 280, 44 (2004); doi:10.1016/j.jcis.2004.07.035.
A.S. Özcan, B. Erdem and A. Özcan, Colloids Surf. A, 266, 73 (2005); doi:10.1016/j.colsurfa.2005.06.001.
L. Zhu and J. Ma, Chem. Eng. J., 139, 503 (2008); doi:10.1016/j.cej.2007.08.023.
S. Qiao, Q. Hu, F. Haghseresht, X. Hu and G.Q.M. Lu, Sep. Purif. Technol., 67, 218 (2009); doi:10.1016/j.seppur.2009.03.012.
Q.-Y. Yue, Q. Li, B.-Y. Gao and Y. Wang, Sep. Purif. Technol., 54, 279 (2007); doi:10.1016/j.seppur.2006.10.024.
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C. Leodopoulos, D. Doulia and K. Gimouhopoulos, Sep. Purif. Revs., 44, 74 (2015); doi:10.1080/15422119.2013.823622.
M. Visa, Appl. Surf. Sci., 263, 753 (2012); doi:10.1016/j.apsusc.2012.09.156.
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S. Tahir and N. Rauf, Chemosphere, 63, 1842 (2006); doi:10.1016/j.chemosphere.2005.10.033.
Q.-Y. Yue, Q. Li, B.-Y. Gao, A.-J. Yuan and Y. Wang, Appl. Clay Sci., 35, 268 (2007); doi:10.1016/j.clay.2006.09.008.
J. Guo, S. Chen, L. Liu, B. Li, P. Yang, L. Zhang and Y. Feng, J. Colloid Interf. Sci., 382, 61 (2012); doi:10.1016/j.jcis.2012.05.044.
E. Bulut, M. Özacar and İ.A. Şengil, Micropor. Mesopor. Mater., 115, 234 (2008); doi:10.1016/j.micromeso.2008.01.039.
B. Benguella and A. Yacouta-Nour, Desalination, 235, 276 (2009); doi:10.1016/j.desal.2008.01.016.
Ö. Gök, A.S. Özcan and A. Özcan, Appl. Surf. Sci., 256, 5439 (2010); doi:10.1016/j.apsusc.2009.12.134.
Y.- Hao, L.- Yan, H.- Yu, K. Yang, S.- Yu, R.- Shan and B. Du, J. Mol. Liq., 199, 202 (2014); doi:10.1016/j.molliq.2014.09.005.
L. Lian, L. Guo and A. Wang, Desalination, 249, 797 (2009); doi:10.1016/j.desal.2009.02.064.
D. Shen, J. Fan, W. Zhou, B. Gao, Q. Yue and Q. Kang, J. Hazard. Mater., 172, 99 (2009); doi:10.1016/j.jhazmat.2009.06.139.
A. Özcan, Ç. Ömeroglu, Y. Erdogan and A.S. Özcan, J. Hazard. Mater., 140, 173 (2007); doi:10.1016/j.jhazmat.2006.06.138.
E. Eren and B. Afsin, Dyes Pigments, 76, 220 (2008); doi:10.1016/j.dyepig.2006.08.019.
E. Eren, J. Hazard. Mater., 166, 88 (2009); doi:10.1016/j.jhazmat.2008.11.011.
T. Anirudhan and M. Ramachandran, Process Saf. Environ. Prot., 95, 215 (2015); doi:10.1016/j.psep.2015.03.003.
Y. Gao, Y. Guo and H. Zhang, J. Hazard. Mater., 302, 105 (2016); doi:10.1016/j.jhazmat.2015.09.036.
A.S. Özcan and A. Özcan, J. Colloid Interf. Sci., 276, 39 (2004); doi:10.1016/j.jcis.2004.03.043.