Synthesis of a Bridged Tetraaza Macrocycle Cu(II) Complex and Its Molecular Magnetic Properties

Jian-Hong Bi; Wen-Tao Bi; Nai-Liang Hu

Issue

Vol. 24 No. 2 (2012): Vol 24 Issue 2

Issue Published : 27 September 2011

Synthesis of a Bridged Tetraaza Macrocycle Cu(II) Complex and Its Molecular Magnetic Properties

Jian-Hong Bi

Deparment of Chemistry and Chemical Engineering, Hefei Normal University, Hefei, P.R. China

Wen-Tao Bi

Hefei Training and Analysis Center, Institute of Petroleum Exploration and Development, SINOPEC, Hefei 230022, P.R. China

Nai-Liang Hu

School of Chemistry and Chemical Engineering, Anhui University, Hefei 230039, P.R. China

Corresponding Author(s) : Jian-Hong Bi

bi010101@126.com

Asian Journal of Chemistry, Vol. 24 No. 2 (2012): Vol 24 Issue 2
Article Published : 5 November 2011

Abstract

A novel self-assembled tetraaza macrocycle Cu(II) complex: [(CuL)₂Fe(SCN)₄](ClO₄)₂ (L = 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene) has been synthesized and characterized by IR spectra and elemental analysis. Its molecular magnetic properties investigation shows that weak antiferromagnetic interactions are mediated between the tetraaza macrocycle Cu(II) ions through the [Fe(SCN)₄]^2- bridged in the complex.

Keywords

Copper(II) complex Tetraza macrocycle Self-assemble Magnetic property

(1)

Bi, J.-H.; Bi, W.-T.; Hu, N.-L. Synthesis of a Bridged Tetraaza Macrocycle Cu(II) Complex and Its Molecular Magnetic Properties. ajc 2011, 24, 943-944.

Issue

Vol. 24 No. 2 (2012): Vol 24 Issue 2

Synthesis of a Bridged Tetraaza Macrocycle Cu(II) Complex and Its Molecular Magnetic Properties

Corresponding Author(s) : Jian-Hong Bi

Abstract

Keywords

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