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Vol. 24 No. 2 (2012): Vol 24 Issue 2

Synthesis of a Bridged Tetraaza Macrocycle Cu(II) Complex and Its Molecular Magnetic Properties

Jian-Hong Bi
Deparment of Chemistry and Chemical Engineering, Hefei Normal University, Hefei, P.R. China
Wen-Tao Bi
Hefei Training and Analysis Center, Institute of Petroleum Exploration and Development, SINOPEC, Hefei 230022, P.R. China
Nai-Liang Hu
School of Chemistry and Chemical Engineering, Anhui University, Hefei 230039, P.R. China

Corresponding Author(s) : Jian-Hong Bi

bi010101@126.com

Asian Journal of Chemistry, Vol. 24 No. 2 (2012): Vol 24 Issue 2

Abstract

A novel self-assembled tetraaza macrocycle Cu(II) complex: [(CuL)2Fe(SCN)4](ClO4)2 (L = 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene) has been synthesized and characterized by IR spectra and elemental analysis. Its molecular magnetic properties investigation shows that weak antiferromagnetic interactions are mediated between the tetraaza macrocycle Cu(II) ions through the [Fe(SCN)4]2- bridged in the complex.

Keywords

Copper(II) complex Tetraza macrocycle Self-assemble Magnetic property
Bi, J.-H., Bi, W.-T., & Hu, N.-L. (2011). Synthesis of a Bridged Tetraaza Macrocycle Cu(II) Complex and Its Molecular Magnetic Properties. Asian Journal of Chemistry, 24(2), 943–944. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/8684
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