Molecular Magnet Based on a Thiocyanato-Bridged Heterobimetallic Complex: Synthesis and Magnetic Properties

Jian-Hong Bi; Wen-Tao Bi; Nai-Liang Hu

Issue

Vol. 24 No. 2 (2012): Vol 24 Issue 2

Issue Published : 27 September 2011

Molecular Magnet Based on a Thiocyanato-Bridged Heterobimetallic Complex: Synthesis and Magnetic Properties

Jian-Hong Bi

Deparment of Chemistry and Chemical Engineering, Hefei Normal University, Hefei, P.R. China

Wen-Tao Bi

Hefei Training and Analysis Center, Institute of Petroleum Exploration and Development, SINOPEC, Hefei 230022, P.R. China

Nai-Liang Hu

School of Chemistry and Chemical Engineering, Anhui University, Hefei 230039, P.R. China

Corresponding Author(s) : Jian-Hong Bi

bi010101@126.com

Asian Journal of Chemistry, Vol. 24 No. 2 (2012): Vol 24 Issue 2
Article Published : 5 November 2011

Abstract

One new self-assembled heterobimetallic complex with the composition CuL-Co(SCN)₄ (L = 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene) has been prepared and characterized by IR spectra and elemental analysis. The molecular magnetic properties of the complex were characterized by magnetic susceptibility and presents a antiferromagnetic interaction between the tetraaza macrocycle Cu(II) ions and Co(SCN)₄^2- through the thiocyanatobridged in the complex.

Keywords

Heterobimetallic complex Tetraza macrocycle Self-assemble Synthesis Magnetic property

(1)

Bi, J.-H.; Bi, W.-T.; Hu, N.-L. Molecular Magnet Based on a Thiocyanato-Bridged Heterobimetallic Complex: Synthesis and Magnetic Properties. ajc 2011, 24, 941-942.

Issue

Vol. 24 No. 2 (2012): Vol 24 Issue 2

Molecular Magnet Based on a Thiocyanato-Bridged Heterobimetallic Complex: Synthesis and Magnetic Properties

Corresponding Author(s) : Jian-Hong Bi

Abstract

Keywords

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