Molecular Magnet Based on a Thiocyanato-Bridged Heterobimetallic Complex: Synthesis and Magnetic Properties
Corresponding Author(s) : Jian-Hong Bi
bi010101@126.com
Asian Journal of Chemistry,
Vol. 24 No. 2 (2012): Vol 24 Issue 2
Abstract
One new self-assembled heterobimetallic complex with the composition CuL-Co(SCN)4 (L = 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene) has been prepared and characterized by IR spectra and elemental analysis. The molecular magnetic properties of the complex were characterized by magnetic susceptibility and presents a antiferromagnetic interaction between the tetraaza macrocycle Cu(II) ions and Co(SCN)42- through the thiocyanatobridged in the complex.
Keywords
Heterobimetallic complex
Tetraza macrocycle
Self-assemble
Synthesis
Magnetic property
Bi, J.-H., Bi, W.-T., & Hu, N.-L. (2011). Molecular Magnet Based on a Thiocyanato-Bridged Heterobimetallic Complex: Synthesis and Magnetic Properties. Asian Journal of Chemistry, 24(2), 941–942. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/8683
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