CuCl2 and FeCl3 as a New and Efficient Catalyst for the Oxidative Coupling of Aryl amines into 1‚1′′′-Binaphthalene-2‚2′′′-diamines in the Ionic Liquid Media
Corresponding Author(s) : Naser Montazeri
montazer50@toniau.ac.ir
Asian Journal of Chemistry,
Vol. 24 No. 2 (2012): Vol 24 Issue 2
Abstract
A practical synthesis of 1‚1'-binaphthalene-1‚1'-diamines (BINAM) from a-naphthylamine is described here. The facile purification procedure of the method makes it amenable to gram scale synthesis of 1‚1'-binaphthalene-1‚1'-diamines with fairly high optical purity and yield of product.
Keywords
Oxidative coupling
Aryl amines
Chiral amino acid
1‚1'-Binaphthalene-2‚2'-diamines
Ionic liquid
Montazeri, N., Tavana, M., Yousefian, S., & Taj Firooz, F. (2011). CuCl2 and FeCl3 as a New and Efficient Catalyst for the Oxidative Coupling of Aryl amines into 1‚1′′′-Binaphthalene-2‚2′′′-diamines in the Ionic Liquid Media. Asian Journal of Chemistry, 24(2), 840–842. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/8615
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