Synthesis and Characterization of 5,5',6,6'-Tetrahydroxy-2,2'-[ethylene-1,2-diyldioxy)bis(nitrilomethylidyne)]diphenol and its Copper(II) Complexes

Feng-Ying Chai; Zheng-Kun Wang; Meng-Meng Zhao; Xin-Ying Zhang; Jiao-Long Meng; Li-Sha Zhang; Ke-Tai Wang

doi:10.14233/ajchem.2013.15636

Issue

Vol. 25 No. 16 (2013): Vol 25 Issue 16

Issue Published : 9 October 2013

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis and Characterization of 5,5',6,6'-Tetrahydroxy-2,2'-[ethylene-1,2-diyldioxy)bis(nitrilomethylidyne)]diphenol and its Copper(II) Complexes

https://doi.org/10.14233/ajchem.2013.15636

Feng-Ying Chai

School of Chemical Engineering, Lanzhou University of Arts and Sciences, Lanzhou 730000, P.R. China

Zheng-Kun Wang

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Meng-Meng Zhao

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Xin-Ying Zhang

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Jiao-Long Meng

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Li-Sha Zhang

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Ke-Tai Wang

School of Chemical Engineering, Lanzhou University of Arts and Sciences, Lanzhou 730000, P.R. China

Corresponding Author(s) : Ke-Tai Wang

wang_kt@126.com

Asian Journal of Chemistry, Vol. 25 No. 16 (2013): Vol 25 Issue 16
Article Published : 9 October 2013

Abstract

A series of copper(II) complexes have been synthesized by the reaction of several Cu(II) salts with a Salen-type bisoxime chelating ligand (H₆L = 5,5',6,6'-tetrahydroxy-2,2'-[ethylene-1,2-diyldioxy)bis(nitrilomethylidyne)]diphenol) in anhydrous ethanol medium. All the copper(II) complexes were characterized by elemental analyses, IR spectra, UV-visible spectra and molar conductance measurements.

Keywords

Salen-type bisoxime ligand Cu(II) complex Synthesis

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Chai, F.-Y.; Wang, Z.-K.; Zhao, M.-M.; Zhang, X.-Y.; Meng, J.-L.; Zhang, L.-S.; Wang, K.-T. Synthesis and Characterization of 5,5’,6,6’-Tetrahydroxy-2,2’-[ethylene-1,2-diyldioxy)bis(nitrilomethylidyne)]diphenol and Its Copper(II) Complexes. ajc 2013, 25, 9368-9370.