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Kinetic and Isothermal Biosorption Studies of Co(II), Cu(II) and Ni(II) Using Polyalthia longifolia Leaf Powder
Corresponding Author(s) : Rabia Rehman
Asian Journal of Chemistry,
Vol. 25 No. 15 (2013): Vol 25 Issue 15
Abstract
Kinetic and isothermal biosorption studies of cobalt, copper and nickel ions using Polyalthia longifolia leaf powder has been carried out in this study on batch scale. Various factors like adsorbent dose, pH, initial concentration of metal ion and agitation time were optimized. Maximum biosorption of Cu(II), Co(II) and Ni(II) occurred at pH 6, 6 and 5, respectively. Isothermal models like Langmuir, Freundlich and Temkin were studied and observed to fit well. The maximum removing capacity of Polyalthia longifolia leaves was found to be 1.74, 3.99 and 4.08 mg/g for copper, cobalt and nickel ions, respectively following pseudo-second-order model. So, Polyalthia longifolia leaves found to besuitable for amputation of cobalt, copper and nickel ions in an environmentally benign way.
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- M.M. Montazer-Rahmati, P. Rabbani, A. Abdolali and A.R. Keshtkar, J. Hazard. Mater., 185, 401 (2011).
- R.M. Hlihor and M. Gavrilescu, Environ. Eng. Manage. J., 8, 353 (2009).
- M. Gavrilescu, Eng. Life Sci., 4, 219 (2004).
- M.R. Fagundes-Klen, L.G.L. Vaz, M.T. Veit, C.E. Borba, E.A. Silva and A.D. Kroumov, Int. J. Bioautomation, 7, 23 (2007).
- H. Pahlavanzadeh, A.R. Keshtkar, J. Safdari and Z. Abadi, J. Hazard. Mater., 175, 304 (2010).
- Y. Bayrak and R. Uzgör, Asian J. Chem., 25, 71 (2013).
- W.S.W. Ngah and M.A.K.M. Hanafiah, Biochem. Eng. J., 39, 521 (2008).
- J. Anwar, U. Shafique, M. Salman, W. uz-Zaman, Z. un-Nisa, M.A. Munawar, N. Jamil, A. Dar, R. Rehman, J. Saif, H. Gul and T. Iqbal, Int. J. Phytoremed., 13, 410 (2011).
- A. Javaid, R. Bajwa, U. Shafique and J. Anwar, Biomass Bioenerg., 35, 1675 (2011).
- S. Özdemir, E. Kilinc, A. Poli, B. Nicolaus and K. Güven, Chem. Eng. J., 152, 195 (2009).
- A. Sari and M. Tuzen, J. Hazard. Mater., 171, 973 (2009).
- V.T.P. Vinod, R.B. Sashidhar and B. Sreedhar, J. Hazard. Mater., 178, 851 (2010).
- N. Feng, X. Guo, S. Liang, Y. Zhu and J. Liu, J. Hazard. Mater., 185, 49 (2011).
- Z. Chen, W. Ma and M. Han, J. Hazard. Mater., 155, 327 (2008).
- Y.S. Ho and G. Mckay, Process Biochem., 34, 451 (1999).
- M.H. Jnr and A.I. Spiff, Acta Chim. Slov., 52, 174 (2005).
References
M.M. Montazer-Rahmati, P. Rabbani, A. Abdolali and A.R. Keshtkar, J. Hazard. Mater., 185, 401 (2011).
R.M. Hlihor and M. Gavrilescu, Environ. Eng. Manage. J., 8, 353 (2009).
M. Gavrilescu, Eng. Life Sci., 4, 219 (2004).
M.R. Fagundes-Klen, L.G.L. Vaz, M.T. Veit, C.E. Borba, E.A. Silva and A.D. Kroumov, Int. J. Bioautomation, 7, 23 (2007).
H. Pahlavanzadeh, A.R. Keshtkar, J. Safdari and Z. Abadi, J. Hazard. Mater., 175, 304 (2010).
Y. Bayrak and R. Uzgör, Asian J. Chem., 25, 71 (2013).
W.S.W. Ngah and M.A.K.M. Hanafiah, Biochem. Eng. J., 39, 521 (2008).
J. Anwar, U. Shafique, M. Salman, W. uz-Zaman, Z. un-Nisa, M.A. Munawar, N. Jamil, A. Dar, R. Rehman, J. Saif, H. Gul and T. Iqbal, Int. J. Phytoremed., 13, 410 (2011).
A. Javaid, R. Bajwa, U. Shafique and J. Anwar, Biomass Bioenerg., 35, 1675 (2011).
S. Özdemir, E. Kilinc, A. Poli, B. Nicolaus and K. Güven, Chem. Eng. J., 152, 195 (2009).
A. Sari and M. Tuzen, J. Hazard. Mater., 171, 973 (2009).
V.T.P. Vinod, R.B. Sashidhar and B. Sreedhar, J. Hazard. Mater., 178, 851 (2010).
N. Feng, X. Guo, S. Liang, Y. Zhu and J. Liu, J. Hazard. Mater., 185, 49 (2011).
Z. Chen, W. Ma and M. Han, J. Hazard. Mater., 155, 327 (2008).
Y.S. Ho and G. Mckay, Process Biochem., 34, 451 (1999).
M.H. Jnr and A.I. Spiff, Acta Chim. Slov., 52, 174 (2005).