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Volumetric and Viscometric Study of Amino Acids in Aqueous Solution of Maltose at Different Temperatures
Corresponding Author(s) : Parvinder Khanuja
Asian Journal of Chemistry,
Vol. 25 No. 15 (2013): Vol 25 Issue 15
Abstract
Density and viscosity measurements were performed for amino acids in 0.05-0.25 M aqueous maltose at 293.15, 303.15 and 313.15 K. The measured values of density and viscosity were used to estimate some important parameters, such as the partial molal volume, the partial molal volume of transfer, the second derivative of the infinite dilution of the standard partial molal volume with temperature, the viscosity B-coefficients, variation of B with temperature, dB/dT, the free energy of activation per mole of solvent amino acid in a ternary system. These parameters were interpreted in terms of solute-solute and solute-solvent interactions and structure making/ breaking ability of solutes in the given solution.
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- S. Galema and A. Hoiland, J. Phys. Chem., 95, 5321 (1991).
- P.K. Banipal, T.S. Banipal, B.S. Lark and J.C. Ahluwalia, J. Chem. Soc. Faraday Trans., 93, 81 (1997).
- P.K. Banipal, T.S. Banipal, B.S. Lark and J.C. Ahluwalia, J. Chem. Thermodyn., 32, 1409 (2000).
- D.P. Kharakoz, J. Phys. Chem., 95, 5634 (1991).
- D.P. Kharakoz, Biophys. Chem., 34, 115 (1989).
- D. Lan, L. Liu, L. Dong, W. Li, Q. Li and L. Yan, Asian J. Chem., 25, 2709 (2013).
- A. Pal and S. Kumar, Indian J. Chem. Sci., 117, 267 (2005).
- A. Ali, S. Khan and F. Nabi, J. Serb Chem. Soc., 72, 495 (2007).
- J.A. Kitchner, Findlay, Practical Physical Chemistry, Longman, London, edn. 8, p. 70 (1954).
- C. Garland, J. Nibler and D. Shoemaker, Experiment In Physical Chemistry, McGraw Hill, New York, p. 131 (1967).
- B.B. Panda, G. Dixit and B. Behera, Bull. Chem. Soc Japan, 69, 301 (1996).
- D.O. Masson, Philos. Mag., 8, 218 (1929).
- R. Gupta and M. Singh, J. Indian Chem. Soc., 85, 176 (2008).
- B. Sinha, P.K. Roy and M.N. Roy, Acta Chim. Slov., 57, 651 (2010).
- A. Ali, R. Patel and S. Tasneem, Polish J. Chem., 83, 1353 (2009).
- J.J. Wang, Z.N. Yan and J.S. Lu, J. Chem. Thermodyn., 36, 281 (2004).
- H.L. Friedman and Krishnan, J. Sol. Chem., 2, 37 (1973).
- L. Hepler, Can. J. Chem., 47, 4613 (1969).
- G. Jones and M. Dole, J. Am. Chem. Soc., 51, 2950 (1929).
- H. Jenkins and Y. Marcus, Chem. Rev., 95, 2695 (1995).
- D. Feakins, F.M. Canning, W.E. Waghorne and K.G. Lawrence, J. Chem. Soc. Faraday Trans., 89, 3381 (1993).
- S. Glasstone, K.J. Laidler and H. Eyring, The Theory of Rate Processes, McGraw-Hill, New York (1941).
- M. Natrajan, R. Wadi and H. Gaur, J. Chem. Eng. Data, 35, 87 (1990).
- T. Ogawa, K. Mizutani and M. Yasuda, Bull. Chem. Soc. (Japan), 57, 2064 (1984).
- M.N. Roy, D. Ekka and R. Dewan, Acta Chim. Slov., 58, 792 (2010).
- I.N. Basumallick and R. Mohanty, Indian J. Chem., 29A, 647 (1990).
- T.S. Banipal, G. Singh, B.S. Lark, J. Solut. Chem., 30, 7 (2001).
- A. Pal and N. Chauhan, J. Indian Chem. Soc., 48A, 1069 (2009).
- A. Pal and S. Kumar, J. Indian Chem. Soc., 79, 866 (2002).
- F.J. Millero, In ed: R.A.Horne, Structure and Transport Process in Water and Aqueous Solution, Wiley Interscience, New York (1971).
- M.S.I. Lampreia and J.M.S.T. Neves, J. Chem. Soc. Faraday Trans., 93, 2277 (1997).
- P. Dey, M.A. Motin and E.M. Huque, Monatsh. Chem., 134, 797 (2003).
- S. Li, X. Hu, R. Lin and H. Zong, Thermochim. Acta, 342, 1 (1999).
References
S. Galema and A. Hoiland, J. Phys. Chem., 95, 5321 (1991).
P.K. Banipal, T.S. Banipal, B.S. Lark and J.C. Ahluwalia, J. Chem. Soc. Faraday Trans., 93, 81 (1997).
P.K. Banipal, T.S. Banipal, B.S. Lark and J.C. Ahluwalia, J. Chem. Thermodyn., 32, 1409 (2000).
D.P. Kharakoz, J. Phys. Chem., 95, 5634 (1991).
D.P. Kharakoz, Biophys. Chem., 34, 115 (1989).
D. Lan, L. Liu, L. Dong, W. Li, Q. Li and L. Yan, Asian J. Chem., 25, 2709 (2013).
A. Pal and S. Kumar, Indian J. Chem. Sci., 117, 267 (2005).
A. Ali, S. Khan and F. Nabi, J. Serb Chem. Soc., 72, 495 (2007).
J.A. Kitchner, Findlay, Practical Physical Chemistry, Longman, London, edn. 8, p. 70 (1954).
C. Garland, J. Nibler and D. Shoemaker, Experiment In Physical Chemistry, McGraw Hill, New York, p. 131 (1967).
B.B. Panda, G. Dixit and B. Behera, Bull. Chem. Soc Japan, 69, 301 (1996).
D.O. Masson, Philos. Mag., 8, 218 (1929).
R. Gupta and M. Singh, J. Indian Chem. Soc., 85, 176 (2008).
B. Sinha, P.K. Roy and M.N. Roy, Acta Chim. Slov., 57, 651 (2010).
A. Ali, R. Patel and S. Tasneem, Polish J. Chem., 83, 1353 (2009).
J.J. Wang, Z.N. Yan and J.S. Lu, J. Chem. Thermodyn., 36, 281 (2004).
H.L. Friedman and Krishnan, J. Sol. Chem., 2, 37 (1973).
L. Hepler, Can. J. Chem., 47, 4613 (1969).
G. Jones and M. Dole, J. Am. Chem. Soc., 51, 2950 (1929).
H. Jenkins and Y. Marcus, Chem. Rev., 95, 2695 (1995).
D. Feakins, F.M. Canning, W.E. Waghorne and K.G. Lawrence, J. Chem. Soc. Faraday Trans., 89, 3381 (1993).
S. Glasstone, K.J. Laidler and H. Eyring, The Theory of Rate Processes, McGraw-Hill, New York (1941).
M. Natrajan, R. Wadi and H. Gaur, J. Chem. Eng. Data, 35, 87 (1990).
T. Ogawa, K. Mizutani and M. Yasuda, Bull. Chem. Soc. (Japan), 57, 2064 (1984).
M.N. Roy, D. Ekka and R. Dewan, Acta Chim. Slov., 58, 792 (2010).
I.N. Basumallick and R. Mohanty, Indian J. Chem., 29A, 647 (1990).
T.S. Banipal, G. Singh, B.S. Lark, J. Solut. Chem., 30, 7 (2001).
A. Pal and N. Chauhan, J. Indian Chem. Soc., 48A, 1069 (2009).
A. Pal and S. Kumar, J. Indian Chem. Soc., 79, 866 (2002).
F.J. Millero, In ed: R.A.Horne, Structure and Transport Process in Water and Aqueous Solution, Wiley Interscience, New York (1971).
M.S.I. Lampreia and J.M.S.T. Neves, J. Chem. Soc. Faraday Trans., 93, 2277 (1997).
P. Dey, M.A. Motin and E.M. Huque, Monatsh. Chem., 134, 797 (2003).
S. Li, X. Hu, R. Lin and H. Zong, Thermochim. Acta, 342, 1 (1999).