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Preparation and Application of Hydroxyacetic Acid Esters as Methanol-Gasoline Additives
Corresponding Author(s) : Ying Tang
Asian Journal of Chemistry,
Vol. 25 No. 15 (2013): Vol 25 Issue 15
Abstract
In this paper, hydroxyacetic acid esters (glycolic esters) were synthesized and used as phase stabilizer and saturation vapour pressure depressor of methanol-gasoline. The results show that the stabilities of the blends depend on the length of the glycolic esters’ alkoxy group. Among these glycolic esters, hexyl glycolic ester and octyl glycolic ester were found to be the most effective in various gasoline-methanol blends. Besides, the glycolic esters display high capacity to depress the saturation vapour pressure of methanol-gasoline and decyl glycolic ester is the most effective one. According to the results, it can be concluded that the glycolic esters have the great potential to be used as bifunctional gasoline-methanol additives.
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- J.J. Yang and H.B. Huang, J. Internal Combustion Engine Power Equip., 4, 40 (2007).
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- Y.B. Qiao, J. Contemp. Petroleum Petrochem., 11, 7 (2003).
- G.Z. Cao and S.Y. Tan, Research on Application of Methanol Gasoline, Chong Qing University, pp. 1-2 (2008).
- Y.Z. Wang, Physical and Chemical Properties of the Vehicle of Methanol Gasoline, Chang’an University, pp. 28-31 (2006).
- S.X. Song and Z.F. Wang, Chinese Patent 1332227 (2002).
- M.Q. Zhang, Chinese Patent 1400290 (2003)
- S.S. Xiang, Chinese Patent 1364856 (2002).
- M.Q. Wang and Y.B. Hu, J. Guang Zhou Chem., 39, 87 (2010).
- T.T. Luo and L. Yang, J. Times J. Chem., 19, 1 (2005).
- H.J. Guo, J. Polym. Mater. Sci. Eng., 18, 171 (2002).
- H.R. He and R. Zhang, Chinese Patent 1429893 (2003).
- J.P. Hu, Chinese Patent 86104230 (1987).
- L. Chen and S. Yang, Chinese Patent 1410520 (2003).
- Q.F. Chen and J.Y. Wang, Chinese Patent 1821359 (2006).
- B. Jiang, Chinese Patent 1743432 (2006).
- G. Zhao, Chinese Patent 101033418 (2007).
- C.R. Zhang, Chinese Patent 101705122 (2010).
- S.S. Xiang, Chinese Patent 1364856 (2002).
- B. Li, Chinese Patent 101787311 (2010).
- H.Y. Shang and Y.P. Lin, Chinese Patent 102031104 (2011).
- D.L. Chen, Q. Li and W. Chu, J. Nat. Gas Chem., 25, 5 (2000).
- W.R. Zhu, J.G. Li and Y. Chen, J. Yulin Teachers College, 24, 46 (2003).
- J. Zhang, C.C. Yang and Y. Tang, J. Speciality Petrochem., 28, 66 (2011).
- X.J. Yang and J. Zhu, J. Chem. Eng., 8 (1995).
- Q. Xi, C.G. Li and F.L. Xu, Times J. Chem., 21, 10 (2007).
- B. Yuan and X.M. Dou, J. Spectrosc. Spectral Anal., 24, 1320 (2004).
References
W. Liang, J. Chin. Foreign Energy, 11, 95 (2006).
X.L. He, Y. H. Zhan and S.S. Li, China Petrochemical Press: Fuel of Internal Ombustion Engine, Beijing, pp. 11/352-11/392 (1999).
J.J. Yang and H.B. Huang, J. Internal Combustion Engine Power Equip., 4, 40 (2007).
W.H. Fu, J. Learned J. Petroleum, 2, 69 (1986).
P. He, Research and Application of the Additive of Methanol Gasoline, Liao Ning Normal University, pp. 9-10 (2010).
Y.B. Qiao, J. Contemp. Petroleum Petrochem., 11, 7 (2003).
G.Z. Cao and S.Y. Tan, Research on Application of Methanol Gasoline, Chong Qing University, pp. 1-2 (2008).
Y.Z. Wang, Physical and Chemical Properties of the Vehicle of Methanol Gasoline, Chang’an University, pp. 28-31 (2006).
S.X. Song and Z.F. Wang, Chinese Patent 1332227 (2002).
M.Q. Zhang, Chinese Patent 1400290 (2003)
S.S. Xiang, Chinese Patent 1364856 (2002).
M.Q. Wang and Y.B. Hu, J. Guang Zhou Chem., 39, 87 (2010).
T.T. Luo and L. Yang, J. Times J. Chem., 19, 1 (2005).
H.J. Guo, J. Polym. Mater. Sci. Eng., 18, 171 (2002).
H.R. He and R. Zhang, Chinese Patent 1429893 (2003).
J.P. Hu, Chinese Patent 86104230 (1987).
L. Chen and S. Yang, Chinese Patent 1410520 (2003).
Q.F. Chen and J.Y. Wang, Chinese Patent 1821359 (2006).
B. Jiang, Chinese Patent 1743432 (2006).
G. Zhao, Chinese Patent 101033418 (2007).
C.R. Zhang, Chinese Patent 101705122 (2010).
S.S. Xiang, Chinese Patent 1364856 (2002).
B. Li, Chinese Patent 101787311 (2010).
H.Y. Shang and Y.P. Lin, Chinese Patent 102031104 (2011).
D.L. Chen, Q. Li and W. Chu, J. Nat. Gas Chem., 25, 5 (2000).
W.R. Zhu, J.G. Li and Y. Chen, J. Yulin Teachers College, 24, 46 (2003).
J. Zhang, C.C. Yang and Y. Tang, J. Speciality Petrochem., 28, 66 (2011).
X.J. Yang and J. Zhu, J. Chem. Eng., 8 (1995).
Q. Xi, C.G. Li and F.L. Xu, Times J. Chem., 21, 10 (2007).
B. Yuan and X.M. Dou, J. Spectrosc. Spectral Anal., 24, 1320 (2004).