Issue

Vol. 25 No. 15 (2013): Vol 25 Issue 15

Copyright (c) 2013 AJC

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Copper(II) Complex of 2-Hydroxy-4-oxyacetate-benzoic Acid: Synthesis, Structure and Photoluminescence

https://doi.org/10.14233/ajchem.2013.14769A
Wei-Ji Hu
Xingzhi College, Zhejiang Normal University, Jinhua 321004, P.R. China
Xiao-Ju Chen
College of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004, P.R. China
Yi Qin
Xingzhi College, Zhejiang Normal University, Jinhua 321004, P.R. China
Guo-Liang Zhao
Xingzhi College, Zhejiang Normal University, Jinhua 321004, P.R. China ; College of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004, P.R. China

Corresponding Author(s) : Guo-Liang Zhao

sky53@zjnu.cn

Asian Journal of Chemistry, Vol. 25 No. 15 (2013): Vol 25 Issue 15

Abstract

A novel copper(II) complex (1) Cu(L)·(phen)2·10H2O was synthesized from 2-hydroxy-4-oxyacetate-benzoic acid (HL), phenanthroline (phen) and Cu(NO3)2·2.5H2O and characterized by elemental analysis, IR and X-ray crystallographically. The single-crystal X-ray diffraction studies demonstrated that complex is crystallize in triclinic system, space group P1, with a = 0.9177(6) nm, b = 1.5123(5) nm, c = 1.5753(3) nm, a = 62.263º, b = 77.639º, g = 80.098º, V = 1.883(7) nm3, Z = 2, Mr = 814.25, F(000) = 850.0, Dc = 1.436 g·cm-3, μ (M0Ka) = 0.675 mm-1. It turned out that four N atoms and one carboxyl O atom coordinate to Cu(II), forming a five-coordination trigonal bipyramid geometry. The complex is luminescent in the solid state, which indicate that it may be an excellent candidate for potential photoactive material. CCDC: 883096.

Keywords

Copper compound 2-Hydroxy-4-oxyacetate-benzoic acid Crystal structure Luminescent
Hu, W.-J., Chen, X.-J., Qin, Y., & Zhao, G.-L. (2013). Copper(II) Complex of 2-Hydroxy-4-oxyacetate-benzoic Acid: Synthesis, Structure and Photoluminescence. Asian Journal of Chemistry, 25(15), 8415–8417. https://doi.org/10.14233/ajchem.2013.14769A
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. O.M. Yaghi, M. O'Keeffe, N.W. Ockwig, H.K. Chae, M. Eddaoudi and J. Kim, Nature, 423, 705 (2003).
  2. Y. Gurdal and S. Keskin, Ind. Eng. Chem. Res., 51, 7373 (2012).
  3. A.M. Shultz, O.K. Farha, J.T. Hupp and S.T. Nguyen, J. Am. Chem. Soc., 131, 4204 (2009).
  4. Y.N. Guo, G.F. Xu, P. Gamez, L. Zhao, S.Y. Lin, R. Deng, J. Tang and H.J. Zhang, J. Am. Chem. Soc., 132, 8538 (2010).
  5. K. Binnemans, Chem. Rev., 109, 4283 (2009).
  6. J.W. Steed, Chem. Soc. Rev., 38, 506 (2009).
  7. B.L. Chen, L.B. Wang, F. Zapata, G. Qian and E.B. Lobkovsky, J. Am. Chem. Soc., 130, 6718 (2008).
  8. L. Hou, Y.Y. Lin and X.M. Chen, Inorg. Chem., 47, 1346 (2008).
  9. P. Horcajada, C. Serre, G. Mauri, N.A. Ramsahye, F. Balas, M. ValletRegí, M. Sebban, F. Taulelle and G. Férey, J. Am. Chem. Soc., 130, 6774 (2008).
  10. C.Q. Wan, G.S. Li, X.D. Chen and T.C. W. Mak, Cryst. Growth Des., 8, 3897 (2008).
  11. G.M. Sheldrick, SHELXS-97. Program for the Solution of Crystal Structures. University of Götingen, Germany (1997).
  12. G.M. Sheldrick, SHELXL-97. Program for the Refinement of Crystal Structures. University of Götingen, Germany (1997).
  13. K. Nakamoto, Translated by D.R. Huang and R.Q. Wang, Infrared and Raman Spectra of Inorganic and Coordination Compounds, edn. 3, Beijing: Chemical Industrial Press, pp. 233, 236 (1986).
  14. L. Fabbrizzi, M. Lichelli, P. Pallavicini,A. Perotti and D. Sacchi, Angew. Chem. Int. Ed., 33, 1975 (1994).
  15. Z.C. Xu, X.H. Qian and J.N. Cui, Org. Lett., 7, 3029 (2005)
Read More
Author biographies is not available.
Download
PDF
Statistic
Read Counter : 0 Download : 0