Synthesis, Crystal Structure and Luminescent Property of Cadmium(II) Complex Assembled by Sebacic Acid

Yi Qin; Xiao-Ju Chen; Wei-Ji Hu; Guo-Liang Zhao

doi:10.14233/ajchem.2013.14769

Issue

Vol. 25 No. 15 (2013): Vol 25 Issue 15

Issue Published : September 15, 2013

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis, Crystal Structure and Luminescent Property of Cadmium(II) Complex Assembled by Sebacic Acid

https://doi.org/10.14233/ajchem.2013.14769

Yi Qin

Xingzhi College, Zhejiang Normal University, Jinhua 321004, P.R. China

Xiao-Ju Chen

College of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004, P.R. China

Wei-Ji Hu

Xingzhi College, Zhejiang Normal University, Jinhua 321004, P.R. China

Guo-Liang Zhao

Xingzhi College, Zhejiang Normal University, Jinhua 321004, P.R. China ; College of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004, P.R. China

Corresponding Author(s) : Guo-Liang Zhao

sky53@zjnu.cn

Asian Journal of Chemistry, Vol. 25 No. 15 (2013): Vol 25 Issue 15
Article Published : September 10, 2013

Abstract

A cadmium(II) complex [Cd₂L₂(phen)₄(H₂O)]·5H₂O (1) assembled by flexible ligand sebacic acid (C₁₀H₁₈O₄, H₂L) and neutral N-based ligand 1,10-phenanthroline (phen), has been hydrothermally synthesized and characterized by elemental analysis, IR and TG. The single-crystal X-ray diffraction studies demonstrated that the complex is crystallize in triclinic, P_i space group, with a = 1.15341(2), b = 1.34483(2), c = 2.10931(3) nm, a = 92.0120(10)º, b = 94.1770(10)º, g = 91.8060(10)º, V = 3.2592(3) nm³, Z = 2, C₆₈H₇₆N₈O₁₄Cd₂, M_r = 1454.17, F₍₀₀₀₎ = 1496, D_c = 1.482 g/cm^-3, μ(M₀K_a) = 0.724 mm^-1. The final R = 0.0433 and wR = 0.1122 for 11469 observed reflections with I > 2s(I). The dual-nuclei bridge structure complex was formed by sebacic acid. The water dimer stay at the lattice space firmly through the hydrogen bonding. The luminescent property in solid state of complex 1 was also studied and discussed. CCDC: 877979.

Keywords

Sebacic acid Flexible ligand Cadmium complex Crystal structure Luminescent property

Qin, Y., Chen, X.-J., Hu, W.-J., & Zhao, G.-L. (2013). Synthesis, Crystal Structure and Luminescent Property of Cadmium(II) Complex Assembled by Sebacic Acid. Asian Journal of Chemistry, 25(15), 8411–8414. https://doi.org/10.14233/ajchem.2013.14769

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References

S. Kitagawa, R. Kitaura and S.I. Noro, Angew. Chem. Int. Ed., 43, 2334 (2004).
C.T. Chen and K.S. Suslick, Coord. Chem. Rev., 128, 293 (1993).
O. Kahn, Molecular Magnetism. New York: VCH Publishers (1993).
K. Nakatani, P. Bergeral and E. Codjovi, Inorg. Chem., 30, 3977 (1991).
R. Kumar, V.B. Taxak, Dayawati and S.P. Khatkar, Asian J. Chem., 26, (2014) (In press).
M. Fujita, Y.J. Kwon, S. Washizu and K. Ogura, J. Am. Chem. Soc., 116, 1151 (1994).
M. Fujita, Y.J. Kwon, O. Sasaki, K. Yaguchi and K. Ogura, J. Am. Chem. Soc., 117, 7287 (1995).
S.R. Batten, B.F. Hoskins, B. Moubaraki, K.S. Murray and R. Robson, Chem. Commun., 13, 1095 (2000).
O.R. Evans, R.G. Xiong and Z.Y. Wang, Angew. Chem. Int. Ed., 38, 4 (1999).
M.L. Tong, Y.M. Wu, J. Ru, X.-M. Chen, H.-C. Chang and S. Kitagawa, Inorg. Chem., 41, 4846 (2002).
L. Carlucci, G. Ciani, D.W. Gudenberg and D.M. Proserpio, Inorg. Chem., 36, 3812 (1997).
Y. Cui, H.L. Ngo and W.B. Lin, Chem. Commun., 1388 (2003).
L. Carlucci, G. Ciani and D.M. Proserpio, Cryst. Growth Des., 5, 37 (2005).
M. Seitz and A. Kaiser, J. Am. Chem. Soc., 126, 11426 (2004).
C.L. Chen, C.Y. Su, Y. P. Cai, H.-X. Zhang, A.-W. Xu, B.-S. Kang and H.-C. zur Loye, Inorg. Chem., 42, 3738 (2003).
H.D. Xian, J.F. Liu and G.L. Zhao, Sci. China Chem., 53, 2539 (2010).
G.L. Zhao, J.B. Shen and H.D. Xian, Sci. China Chem., 42, 983 (2012).
H.D. Xian, H.Q. Li, X. Shi, J.-F. Liu and G.-L. Zhao, Inorg. Chem. Commun., 12, 177 (2009).
M. Li, J.F. Xiang, L.J. Yuan, S.M. Wu, S.P. Chen and J.T. Sun, Cryst. Growth Des., 6, 2034 (2006).
S.L. Zheng, J.H. Yang, X.L. Yu, X.-M. Chen and W.-T. Wong, Inorg. Chem., 43, 830 (2004).
X.L. Wang, C. Qin, E.B. Wang, Y.G. Li, N. Hao, C.W. Hu and L. Xu, Inorg. Chem., 43, 1850 (2004).
G.M. Sheldrick, SHELXS-97, Program for the Solution of Crystal Structures, University of Göttingen, Germany (1997).
G.M. Sheldrick, SHELXL-97, Program for the Refinement of Crystal Structures, University of Göttingen, Germany (1997).
X. Nie, J.N. Qu and M.S. Chen, Chin. J. Inorg. Chem., 27, 2267 (2011).
M. Altmann and U.H.F. Bunz, Angew. Chem., 34, 569 (1995).
J.E. McGarrah, Y.J. Kim, M. Hissler and R. Eisenberg, Inorg. Chem., 40, 4510 (2001).
F.F. Li, J.F. Ma, S.Y. Song, J. Yang, Y.-Y. Liu and Z.-M. Su, Inorg. Chem., 44, 9374 (2005).

References

S. Kitagawa, R. Kitaura and S.I. Noro, Angew. Chem. Int. Ed., 43, 2334 (2004).

C.T. Chen and K.S. Suslick, Coord. Chem. Rev., 128, 293 (1993).

O. Kahn, Molecular Magnetism. New York: VCH Publishers (1993).

K. Nakatani, P. Bergeral and E. Codjovi, Inorg. Chem., 30, 3977 (1991).

R. Kumar, V.B. Taxak, Dayawati and S.P. Khatkar, Asian J. Chem., 26, (2014) (In press).

M. Fujita, Y.J. Kwon, S. Washizu and K. Ogura, J. Am. Chem. Soc., 116, 1151 (1994).

M. Fujita, Y.J. Kwon, O. Sasaki, K. Yaguchi and K. Ogura, J. Am. Chem. Soc., 117, 7287 (1995).

S.R. Batten, B.F. Hoskins, B. Moubaraki, K.S. Murray and R. Robson, Chem. Commun., 13, 1095 (2000).

O.R. Evans, R.G. Xiong and Z.Y. Wang, Angew. Chem. Int. Ed., 38, 4 (1999).

M.L. Tong, Y.M. Wu, J. Ru, X.-M. Chen, H.-C. Chang and S. Kitagawa, Inorg. Chem., 41, 4846 (2002).

L. Carlucci, G. Ciani, D.W. Gudenberg and D.M. Proserpio, Inorg. Chem., 36, 3812 (1997).

Y. Cui, H.L. Ngo and W.B. Lin, Chem. Commun., 1388 (2003).

L. Carlucci, G. Ciani and D.M. Proserpio, Cryst. Growth Des., 5, 37 (2005).

M. Seitz and A. Kaiser, J. Am. Chem. Soc., 126, 11426 (2004).

C.L. Chen, C.Y. Su, Y. P. Cai, H.-X. Zhang, A.-W. Xu, B.-S. Kang and H.-C. zur Loye, Inorg. Chem., 42, 3738 (2003).

H.D. Xian, J.F. Liu and G.L. Zhao, Sci. China Chem., 53, 2539 (2010).

G.L. Zhao, J.B. Shen and H.D. Xian, Sci. China Chem., 42, 983 (2012).

H.D. Xian, H.Q. Li, X. Shi, J.-F. Liu and G.-L. Zhao, Inorg. Chem. Commun., 12, 177 (2009).

M. Li, J.F. Xiang, L.J. Yuan, S.M. Wu, S.P. Chen and J.T. Sun, Cryst. Growth Des., 6, 2034 (2006).

S.L. Zheng, J.H. Yang, X.L. Yu, X.-M. Chen and W.-T. Wong, Inorg. Chem., 43, 830 (2004).

X.L. Wang, C. Qin, E.B. Wang, Y.G. Li, N. Hao, C.W. Hu and L. Xu, Inorg. Chem., 43, 1850 (2004).

G.M. Sheldrick, SHELXS-97, Program for the Solution of Crystal Structures, University of Göttingen, Germany (1997).

G.M. Sheldrick, SHELXL-97, Program for the Refinement of Crystal Structures, University of Göttingen, Germany (1997).

X. Nie, J.N. Qu and M.S. Chen, Chin. J. Inorg. Chem., 27, 2267 (2011).

M. Altmann and U.H.F. Bunz, Angew. Chem., 34, 569 (1995).

J.E. McGarrah, Y.J. Kim, M. Hissler and R. Eisenberg, Inorg. Chem., 40, 4510 (2001).

F.F. Li, J.F. Ma, S.Y. Song, J. Yang, Y.-Y. Liu and Z.-M. Su, Inorg. Chem., 44, 9374 (2005).

Issue

Vol. 25 No. 15 (2013): Vol 25 Issue 15

Synthesis, Crystal Structure and Luminescent Property of Cadmium(II) Complex Assembled by Sebacic Acid

Corresponding Author(s) : Guo-Liang Zhao

Abstract

Keywords

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