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Optimization of Chemical Kinetics for Base Catalyzed Transesterification of Eruca sativa Oil
Corresponding Author(s) : Muhammad Asam Raza
Asian Journal of Chemistry,
Vol. 25 No. 15 (2013): Vol 25 Issue 15
Abstract
Current study describes the optimization of time line kinetics for the base catalyzed transesterification of Eruca sativa oil for biodiesel production. Monitoring of transesterification was carried out using high performance liquid chromatography whereas optimization of kinetic was performed with the help of MATLAB-7. The observed order in terms of rate constants for the forward base catalyzed transesterification reactions of Eruca sativa oil was k3 > k2 > k1 whereas for the backward reactions the order of rate constant was k-3 > k-1 > k-2.
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- J. Tickell, From the Fryer to the Fuel Tank: The Complete Guide to Using Vegetable Oil as an Alternative Fuel, Tickell Energy Consultants, edn. 3, p. 162 (2003)
- A.B. Chhetri and M.R. Islam, Energy Sources A, 30, 754 (2008).
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- M.J. Haas, K.M. Scott, T.L. Alleman and R.L. McCormcik, Energy Fuels, 15, 1207 (2001).
- C.M. Simone, R. Elizabeth, R.S.V. Lachter, J.A. Nascimento, J. Rodrigues and G.R. Marcelli, J. Am. Oil Chem. Soc., 82, 9 (2005).
- F. Ma and M.A. Hanna, Bioresour. Technol., 70, 1 (1999).
- D. de Oliveira, M. Di Luccio, C. Faccio, C.D. Rosa, J.P. Bender, N. Lipke, C. Amroginski, C. Dariva and J.V. de Oliveira , Appl. Biochem. Biotechnol., 122, 553 (2005).
- M. Mittelbach and S. Gangl, J. Am. Oil Chem. Soc., 78, 6 (2001).
- M. Mittelbach, M. Wörgetter, J. Pernkopf and H. Junek, Energy Agric., 2, 369 (1983).
- P.C. Narvaez, S.M. Rincon and F.J. Sanchez, J. Am. Oil Chem. Soc., 84, 971 (2007).
- Schuchardt, U.R. Sercheli and R.M. Vargas, J. Braz. Chem. Soc., 9, 199 (1998).
- S.K. Karmee, D. Chandna, R. Ravi and A. Chadha, J. Am. Oil Chem. Soc., 83, 10 (2006).
- B. Freedman, R.O. Butterfield and E.H. Pryde, J. Am. Oil Chem. Soc., 63, 1375 (1986).
- A.T. Erciyes, L. Dandik and O.S. Kabasakal, J. Am. Oil Chem. Soc., 68, 639 (1991).
- S.R. Moore and J. Davies, J. Am. Oil Chem. Soc., 71, 526 (1994).
- H. Noureddini and D. Zhu, J. Am. Oil Chem. Soc., 74, 1457 (1997).
- D. Darnoko and M. Cheryan, J. Am. Oil Chem. Soc., 77, 1263 (2000).
- S.K. Karmee, P. Mahesh, R. Ravi and A. Chadha, J. Am. Oil Chem. Soc., 81, 425 (2004).
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- L. Yun, Y. Yunjun, H. Fang, Y. Anna, W. Zhicheng and W. Fuxiang, AIChE J., 56, 1659 (2010).
- U. Rashid and F. Anwar, Fuel, 86, 265 (2008).
- U. Rashid, F. Anwar, M.A. Tariq, A. Muhammad and A. Mushtaq, J. Chem. Technol. Biotechnol., 84, 1364 (2009).
- J.M. Encinar, J.F. Gonzalez, J.J. Rodriguez and A. Tejedor, Energy Fuels, 16, 443 (2002).
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- C. Jech-Wei and W. Wen-Teng, J. Biosci. Bioeng., 95, 466 (2003).
- M. Holcapek, P. Jandera, J. Fisher and B. Prokes, J. Chromatogr. A, 858, 13 (1999).
- I. Titipong, M.Sc. Thesis, Biodiesel Production from Fryer Grease, Department of Chemical Engineering, University of Saskatchewan, Saskatoon, Saskatchewan, Thailand, p. 104 (2006).
- A.S. Abdel-Latif and A.M.A. Lamiaa, Am. J. Appl. Sci., 7, 509 (2010).
- L. Theerayut, W. Worawut, P. Gumpon, T. Charktir and A. Michael, A Second Order Kinetics of Palm Oil Transesterification, The Joint International Conference on Sustainable Energy and Environment (SEE) 1-3 December, Hua Hin, Thailand, pp. 3-25, (2004)
References
J. Tickell, From the Fryer to the Fuel Tank: The Complete Guide to Using Vegetable Oil as an Alternative Fuel, Tickell Energy Consultants, edn. 3, p. 162 (2003)
A.B. Chhetri and M.R. Islam, Energy Sources A, 30, 754 (2008).
M.B. Dantas, M.M. Conceição, V.J. Fernandes Jr, N.A. Santos, R. Rosenhaim, A.L.B. Marques, I.M.G. Santos and A.G. Souza, J. Thermal Anal. Calorim., 87, 835 (2007).
W. Kapila, C.S. Jeremiah, R.W. John, O.S. Steven and N.K.Y. Simon, J. Am. Oil Chem. Soc., 85, 1073 (2008).
M.J. Haas, K.M. Scott, T.L. Alleman and R.L. McCormcik, Energy Fuels, 15, 1207 (2001).
C.M. Simone, R. Elizabeth, R.S.V. Lachter, J.A. Nascimento, J. Rodrigues and G.R. Marcelli, J. Am. Oil Chem. Soc., 82, 9 (2005).
F. Ma and M.A. Hanna, Bioresour. Technol., 70, 1 (1999).
D. de Oliveira, M. Di Luccio, C. Faccio, C.D. Rosa, J.P. Bender, N. Lipke, C. Amroginski, C. Dariva and J.V. de Oliveira , Appl. Biochem. Biotechnol., 122, 553 (2005).
M. Mittelbach and S. Gangl, J. Am. Oil Chem. Soc., 78, 6 (2001).
M. Mittelbach, M. Wörgetter, J. Pernkopf and H. Junek, Energy Agric., 2, 369 (1983).
P.C. Narvaez, S.M. Rincon and F.J. Sanchez, J. Am. Oil Chem. Soc., 84, 971 (2007).
Schuchardt, U.R. Sercheli and R.M. Vargas, J. Braz. Chem. Soc., 9, 199 (1998).
S.K. Karmee, D. Chandna, R. Ravi and A. Chadha, J. Am. Oil Chem. Soc., 83, 10 (2006).
B. Freedman, R.O. Butterfield and E.H. Pryde, J. Am. Oil Chem. Soc., 63, 1375 (1986).
A.T. Erciyes, L. Dandik and O.S. Kabasakal, J. Am. Oil Chem. Soc., 68, 639 (1991).
S.R. Moore and J. Davies, J. Am. Oil Chem. Soc., 71, 526 (1994).
H. Noureddini and D. Zhu, J. Am. Oil Chem. Soc., 74, 1457 (1997).
D. Darnoko and M. Cheryan, J. Am. Oil Chem. Soc., 77, 1263 (2000).
S.K. Karmee, P. Mahesh, R. Ravi and A. Chadha, J. Am. Oil Chem. Soc., 81, 425 (2004).
M.M. Conceição, V.J. Fernandes Jr, A.F. Bezerra, M.C.D. Silva, I.M.G. Santos, F.C. Silva and A.G. Souza, J. Thermal Anal. Calorim., 87, 865 (2007).
L. Yun, Y. Yunjun, H. Fang, Y. Anna, W. Zhicheng and W. Fuxiang, AIChE J., 56, 1659 (2010).
U. Rashid and F. Anwar, Fuel, 86, 265 (2008).
U. Rashid, F. Anwar, M.A. Tariq, A. Muhammad and A. Mushtaq, J. Chem. Technol. Biotechnol., 84, 1364 (2009).
J.M. Encinar, J.F. Gonzalez, J.J. Rodriguez and A. Tejedor, Energy Fuels, 16, 443 (2002).
U. Rashid and F. Anwar, Energy Fuels, 22, 1306 (2008).
C. Jech-Wei and W. Wen-Teng, J. Biosci. Bioeng., 95, 466 (2003).
M. Holcapek, P. Jandera, J. Fisher and B. Prokes, J. Chromatogr. A, 858, 13 (1999).
I. Titipong, M.Sc. Thesis, Biodiesel Production from Fryer Grease, Department of Chemical Engineering, University of Saskatchewan, Saskatoon, Saskatchewan, Thailand, p. 104 (2006).
A.S. Abdel-Latif and A.M.A. Lamiaa, Am. J. Appl. Sci., 7, 509 (2010).
L. Theerayut, W. Worawut, P. Gumpon, T. Charktir and A. Michael, A Second Order Kinetics of Palm Oil Transesterification, The Joint International Conference on Sustainable Energy and Environment (SEE) 1-3 December, Hua Hin, Thailand, pp. 3-25, (2004)