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Synthesis and Properties of Novel Organic-Inorganic Hybrid Polyamides
Corresponding Author(s) : Fang Xie
Asian Journal of Chemistry,
Vol. 25 No. 15 (2013): Vol 25 Issue 15
Abstract
Four novel organic-inorganic hybrid polyamides containing cyclophosphazene groups in the main chain were synthesized and their properties had been characterized and compared with those of ordinary polyamides. The chemical structures of all samples were characterized by FT-IR technique and their thermal properties were determined by DSC and TGA. The four polyamides with amorphous structure exhibit an enhanced solubility in polar aprotic solvents and a superior thermal stability with initial decomposition temperature being at about 198-259 ºC. All polyamides exhibited two-step thermal decomposition behaviour and present a maximum char residue at 600 ºC in their thermal decomposition.
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- N.V. Karyakin and I.B. Rabinovich, Polym. Sci. USSR, 29, 747 (1987).
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- Z. Li, C. Huang, J.L. Hua, J.G. Qin, Z. Yang and C. Ye, Macromolecules, 37, 371 (2004).
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References
N.V. Karyakin and I.B. Rabinovich, Polym. Sci. USSR, 29, 747 (1987).
F.A. Bottino, G.D. Pasquale, L. Scalia and A. Pollicino, Polymer, 42, 3323 (2011).
K.A. Joseph and M. Srinivasan, Polym. Int., 30, 327 (1993).
M.K. Scholl, Z.Z. Kadlecova and H.A. Klok, Prog. Polym. Sci., 34, 24 (2009).
A. Melendez, J. de la Campa and J. de Abajo, Polymer, 29, 1142 (1988).
I. Sava, M.-D. Iosip, M. Bruma, C. Hamciuc, J. Robison, L. Okrasa and T. Pakula, Eur. Polym. J., 39, 725 (2003).
B.H. Tamami and H.M. Yeganeh, Eur. Polym. J., 38, 933 (2002).
R. Gill, M. Mazhar and M. Siddiq, Polym. Int., 59, 1598 (2010).
Y. Rao, A.J. Waddon and R.J. Farris, Polymer, 42, 5937 (2001).
H. Yagci and L.J. Mathias, Polymer, 39, 3779 (1998).
H.R. Allcock, L.B. Steely and A. Singh, Polym. Int., 55, 621 (2006).
H.R. Allcock, C.G. Cameron, T.W. Skloss, S. Taylor-Meyers and J.F. Haw, Macromolecules, 29, 233 (1996).
Z. Li, C. Huang, J.L. Hua, J.G. Qin, Z. Yang and C. Ye, Macromolecules, 37, 371 (2004).
H.R. Allcock, S.M. Coley, I. Manners, O. Nuyken and G. Renner, Macromolecules, 24, 2024 (2004).
S.B. Lee and S.C. Song, Polym. Int., 54, 1225 (2005).
Z.P. Zhao, Q. Guo, X. Li, J.L. Sun and Z.J. Nie, eXPRESS Polym. Lett., 6, 308 (2012).
G.L. Mario and R.D. Jaeger, Top. Curr. Chem., 250, 165 (2005).
V. Kute and S. Banerjee, J. Appl. Polym. Sci., 103, 3025 (2007).
M. El-Gouri, A. El-Bachiri, S.E. Hegazi, M. Rafik and A. El-Harfi, Polym. Degrad. Stab., 94, 2101 (2009).
H.S. Wu and D.Y. Ke, J. Polym. Res., 5, 95 (1998).
H.R. Allcock, Chem. Rev., 72, 315 (1972).