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Solubility of Dilute Sulfur Dioxide in Aqueous Poly-Ethylene Glycol 1000 Solutions at 298.15 K and 123.15 kPa
Corresponding Author(s) : Jinrong Liu
Asian Journal of Chemistry,
Vol. 25 No. 15 (2013): Vol 25 Issue 15
Abstract
In present work, solubility data were measured for dilute sulfur dioxide in various aqueous poly-ethylene glycol 1000 (PEG) solutions at 298.15 K and 123.15 kPa and SO2 partial pressures in the range of (0-120) Pa. Measurements were carried out by a saturation method using a glass absorption apparatus, which were controlled at constant temperature by a thermostatic circulation bath with a Beckmann thermometer. Both the gas phase was recirculated in the glass absorption apparatus by an airpump to obtain a series of solubility data. The measurement showed that the solubility of SO2 in the aqueous poly-ethylene glycol 1000 solutions (PEGWs) system increased with the increasing PEG concentration in the whole range of mass fraction.
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References
H.C. Porter, Ind. Eng. Chem., 15, 335 (1923).
X. Esteve, A. Conesa and A. Coronas, J. Chem. Eng. Data, 48, 392 (2003).
H.C. Ku and C.H. Tu, J. Chem. Eng. Data, 45, 391 (2000).
A. Valtz, C. Coquelet and D. Richon, Fluid Phase Equilib., 220, 77 (2004).
D. Nagel, R. de Kermadec, H.G. Lintz, C. Roizard and F. Lapicque, Chem. Eng. Sci., 57, 4883 (2002).
R. De Kermadec, F. Lapicque, D. Roizard and C. Roizard, Ind. Chem. Eng. Res., 41, 153 (2002).
C.N. Schubert and W.I. Echter, The Method of Polymer Ethylene Glycol for Removal Pollution from Gases, CN Patent 1364096A (2002).
X. Li, Y. Liu and X. Wei, Chinese J. Chem. Eng., 13, 234 (2005).
X. Wei, Desulfurization & Decarburization Solution Activities. CN. Patent 02130605.2 (2002).
X. Wei, J. Zhang, P. Zhang, L. Zhang, X. Li and M. Wan, Removal of SOx from Flue Gas by Ethylene Glycol, CN Patent 101053746 (2007).
J.B. Zhang, P.Y. Zhang, G.H. Chen, F. Han and X.H. Wei, J. Chem. Eng. Data, 53, 1479 (2008).