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Vol. 25 No. 15 (2013): Vol 25 Issue 15

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Synthesis and Crystal Structure of O-Methyldithiophosphato Nickel Complex [Ni(S2P{O}OCH3)(dppe)]

https://doi.org/10.14233/ajchem.2013.15232
Yu-Long Li
Key Laboratory of Green Catalysis of Higher Education Institutes of Sichuan, Sichuan University of Science & Engineering, Zigong 643000, P.R. China ; Institute of Functional Materials, Sichuan University of Science & Engineering, Zigong 643000, P.R. China
Bin Xie
Institute of Functional Materials, Sichuan University of Science & Engineering, Zigong 643000, P.R. China
Li-Ke Zou
Key Laboratory of Green Catalysis of Higher Education Institutes of Sichuan, Sichuan University of Science & Engineering, Zigong 643000, P.R. China
Xiao Lin
Institute of Functional Materials, Sichuan University of Science & Engineering, Zigong 643000, P.R. China

Corresponding Author(s) : Yu-Long Li

yu_longli@yahoo.cn

Asian Journal of Chemistry, Vol. 25 No. 15 (2013): Vol 25 Issue 15

Abstract

O-Methyldithiophosphato nickel complex [Ni(S2P{O}OCH3)(dppe)] (I) (dppe = Ph2PCH2CH2PPh2) has been synthesized by treatment of (dppe)NiCl2 with (CH2O)2P{S}SH·Et2NH in THF solution. The new complex (I) was fully characterized by elemental analysis, TGA, IR, 1H, 13C, 31P NMR spectroscopies. In addition the molecular structure of the complex was established by X-ray crystallography. The crystal of [Ni(S2P{O}OCH3)(dppe)] crystallizes in monoclinic, spacegroup P21/n with a = 9.2762(3), b = 17.1214(5), c = 18.8627(6) Å, a = 90.00, b = 96.813(3), g =90.00º, V = 2974.66(15) Å3, Z = 4, C27H27O2P3S2Ni, Mr = 599.23, Dc = 1.338 g/cm3, F(000) = 1240 and μ(MoKa) = 0.976 mm-1. The final R = 0.0521 and wR = 0.1303 for 6073 observed reflections [I > 2s(I)].

Keywords

Ph2PCH2CH2PPh2 Dithiophosphate Synthesis X-ray crystallography
Li, Y.-L., Xie, B., Zou, L.-K., & Lin, X. (2013). Synthesis and Crystal Structure of O-Methyldithiophosphato Nickel Complex [Ni(S2P{O}OCH3)(dppe)]. Asian Journal of Chemistry, 25(15), 8697–8700. https://doi.org/10.14233/ajchem.2013.15232
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