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Assembly of Aminopropyltetrasiloxane Cu2+-Induced in Aqueous Solution
Corresponding Author(s) : Lei Tao
Asian Journal of Chemistry,
Vol. 25 No. 15 (2013): Vol 25 Issue 15
Abstract
A Cu2+-induced vesicle phase was prepared from a mixture of 3-aminopropyltetrasiloxane and CuCl2 or Cu(NO3)2 in aqueous solutions. Cu2+ coordinated with 3-aminopropyltetrasiloxane resulting in the formation of molecular bilayers, because Cu2+ can firmly bind to the amino groups of 3-aminopropyltetrasiloxane which reduced the area of the head-group. In this system, no counter ions in aqueous solution exist because of the Cu2+-ligand coordination and the bilayer membranes are not shielded by salts. The vesicles were determined by transmission electron microscopy images and dynamic light scattering measurements.
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- Y. Talmon, D.F. Evans and B.W. Ninham, Science, 221, 1047 (1983).
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- J. Hao, J. Wang, W. Liu, R. Abdel-Rahem and H. Hoffmann, J. Phys. Chem. B, 108, 1168 (2004).
- A. Song, X. Jia, M. Teng and J. Hao, Chem.-A Eur. J., 13, 496 (2007).
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References
P.P. Chullikkattil, F.M. Mauricio, L. Feng-Yan, Z. Jie, X. Lin, L. DeLiang, L. Tianbo and C. Leroy, Angew. Chem. Int. Ed., 48, 8309 (2009).
D.E. Discher and A. Eisenberg, Nature, 297, 967 (2002).
S. Egota and D. Tezak, Adv. Colloid Interf. Sci., 121, 51 (2006).
E.W. Kaler, A.K. Murthy, B.E. Rodriguez and J.A. Zasadzinski, Science, 245, 1371 (1989).
J.B. Huang, Y. Zhu, B.Y. Zhu, R.K. Li and H.I Fu, J. Colloid Interf. Sci., 236, 201 (2001).
S. Zhou, C. Burger, B. Chu, M. Sawamura, N. Nagahama, M. Toganoh, U.E. Hackler, H. Isobe and E. Nakamura, Nature, 291, 1944 (2001).
T. Kunitake, Angew. Chem. Int. Ed., 31, 709 (1992).
F.M. Menger and Y. Yamasaki, J. Am. Chem. Soc., 115, 3840 (1993).
B. Zu Putlitz, K. Landfester, S. Frster and M. Antonietti, Langmuir, 16, 3003 (2000).
A. Pasc-Banu, M. Blanzat, M. Belloni, E. Perez, C. Mingotaud, I. RicoLattes, T. Labrot and R. Oda, J. Fluorine Chem., 126, 33 (2005).
G. Wang, Z. Du, Q. Li and W. Zhang, J. Phys. Chem. B, 114, 6872 (2010).
Z.P. Du, L. Wang, G.Y. Wang and S.J. Wang, Colloids Surf. A, 381, 55 (2011).
G.Y. Wang, W.S. Qu, Z.P. Du, Q.Y. Cao and Q.X. Li, J. Phys. Chem. B, 115, 3811 (2011).
L. Wang, D.L. Zhang, Z.P. Du, G.Y. Wang, S.J. Wang and Y. Cao, Tenside Surfact. Deterg., 48, 281 (2011).
Y. Talmon, D.F. Evans and B.W. Ninham, Science, 221, 1047 (1983).
C. Groth, K. Tollgerdt and M. Nyden, Colloids Surf. A, 281, 23 (2006).
K. Nyuta, T. Yoshimura, K. Tsuchiya, T. Ohkubo, H. Sakai, M. Abe and K. Esumi, Langmuir, 22, 9187 (2006).
F. Yan, M. Huo, M. Wang, H. Yao, L. Zhang and J. Yu, Chem. Lett., 38, 316 (2009).
D.S. Yin, W.Y. Yang, Z.Q. Ge and Y.J. Yuan, Carbohydr. Res., 340, 1201 (2005).
J. Hao, J. Wang, W. Liu, R. Abdel-Rahem and H. Hoffmann, J. Phys. Chem. B, 108, 1168 (2004).
A. Song, X. Jia, M. Teng and J. Hao, Chem.-A Eur. J., 13, 496 (2007).
J. Wang, A. Song, X. Jia, J. Hao, W. Liu and H. Hoffmanns, J. Phys. Chem. B, 109, 11126 (2005).
X. Luo, S. Wu and Y. Liang, Chem. Commun., 2002, 492 (2002).
D.L. Zhang, C.H. Wang and G.Y. Wang, Tenside Surfact. Deterg., 49, 151 (2012).
J.N. Israelachvili, D.J. Mitchell and B.W. Ninham, J. Chem. Soc. Faraday Trans. I, 72, 1525 (1970).