School of Chemistry and Chemical Engineering, Ningxia University, Yinchuan, Ningxia Province, P.R. China ; Jiangsu Key Laboratory for the Chemistry of Low-Dimensional Materials, School of Chemistry and Chemical Engineering, Huaiyin Normal University, Huai'an, Jiangsu Province, P.R. China
Rong-Qing Li
School of Chemistry and Chemical Engineering, Ningxia University, Yinchuan, Ningxia Province, P.R. China ; Jiangsu Key Laboratory for the Chemistry of Low-Dimensional Materials, School of Chemistry and Chemical Engineering, Huaiyin Normal University, Huai'an, Jiangsu Province, P.R. China
Zai-Chao Zhang
Jiangsu Key Laboratory for the Chemistry of Low-Dimensional Materials, School of Chemistry and Chemical Engineering, Huaiyin Normal University, Huai'an, Jiangsu Province, P.R. China
Zheng-Jing Jiang
Jiangsu Key Laboratory for the Chemistry of Low-Dimensional Materials, School of Chemistry and Chemical Engineering, Huaiyin Normal University, Huai'an, Jiangsu Province, P.R. China
Chang-Mei Wei
Jiangsu Key Laboratory for the Chemistry of Low-Dimensional Materials, School of Chemistry and Chemical Engineering, Huaiyin Normal University, Huai'an, Jiangsu Province, P.R. China
Corresponding Author(s) : Rong-Qing Li
rongqingli333@yahoo.com
Asian Journal of Chemistry,
Vol. 25 No. 14 (2013): Vol 25 Issue 14
Two copper(II) complexes of the tridentate Schiff-base ligands (L1)– and (L2)–, [CuL1(μ-Br)]¥ (1) and [CuL2(μ1,3-N3)]¥ (2), have been synthesized and characterized. The ligands [(L1)– and (L2)– are the deprotonated forms of 2-[(2-morpholin-4-ylethylimino)methyl]phenol (HL1) and 2-[(2-piperidin-1-ylethylimino)methyl]phenol (HL2), respectively]. X-Ray structure determinations carried out on complexes 1 and 2 reveal that both complexes are mono(μ-bromo)-bridged (for 1) or mono(μ1,3-azido)-bridged (for 2) square pyramidal copper(II) one-dimensional chain polymeric complexes.
Zhang, M., Li, R.-Q., Zhang, Z.-C., Jiang, Z.-J., & Wei, C.-M. (2013). Synthesis and Crystal Structures of One-Dimensional Chain Copper(II) Complexes of Two Phenol-Containing Schiff-Base Ligands. Asian Journal of Chemistry, 25(14), 7867–7870. https://doi.org/10.14233/ajchem.2013.14663
