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Vol. 25 No. 14 (2013): Vol 25 Issue 14

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Hydrothermal Synthesis and Crystal Structure of a Ni(II) Complex with Diacetyl Dihydrazone Ligand

https://doi.org/10.14233/ajchem.2013.15354A
Jian-Hong Bi
Deparment of Chemistry and Chemical Engineering, Hefei Normal University, Hefei, P.R. China
Hua-Ze Dong
1Deparment of Chemistry and Chemical Engineering, Hefei Normal University, Hefei, P.R. China
Zi-Xian Huang
Fujian Institute of Research on the Structure of Matter, Chinese Academy of Science, Fuzhou, P.R. China

Corresponding Author(s) : Jian-Hong Bi

bi010101@126.com

Asian Journal of Chemistry, Vol. 25 No. 14 (2013): Vol 25 Issue 14

Abstract

A novel nickel(II) complex NiL3·(ClO4)2 (L = diacetyl dihydrazone) has been synthesized by hydrothermal method and characterized by IR spectra and single-crystal X-ray method. The crystal is trigonal, space P-3c1 with unit cell parameters: a = 9.5922(5) Å, b = 9.5922(5) Å, c = 15.1871(14) Å, a = 90º, b = 90º, g = 120º, V = 1210.16(14) Å3, Z = 2, Mr = 600.09, Dc = 1.647 Mg/cm3, μ = 1.087 mm-1, F(000) =624, T = 293(2) K, R = 0.0474, wR = 0.1276 for 8580 reflections with I > 2s(I).

Keywords

Nickel(II) complex Diacetyl dihydrazone Crystal structure
Bi, J.-H., Dong, H.-Z., & Huang, Z.-X. (2013). Hydrothermal Synthesis and Crystal Structure of a Ni(II) Complex with Diacetyl Dihydrazone Ligand. Asian Journal of Chemistry, 25(14), 8239–8240. https://doi.org/10.14233/ajchem.2013.15354A
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