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Vol. 25 No. 14 (2013): Vol 25 Issue 14

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Synthesis and Crystal Structure of Phosphorus Vanadium Heteropoly Acid Potassium Compound: (K12P4V72O172)·24Cl·24(OH)·14.4H2O

https://doi.org/10.14233/ajchem.2013.14607
Hai-Xing Liu
Chemistry and Chemical and Environmental Engineering College, Weifang University, Weifang 261061, P.R. China
Qing Liu
College of Chemistry, State Key Laboratory of Supramolecular Structure and Materials, Jilin University, Changchun 130012, P.R. China
Lin-Tong Wang
Chemistry and Chemical and Environmental Engineering College, Weifang University, Weifang 261061, P.R. China
Huan-Mei Guo
Chemistry and Chemical and Environmental Engineering College, Weifang University, Weifang 261061, P.R. China
Kai-Qi Ye
College of Chemistry, State Key Laboratory of Supramolecular Structure and Materials, Jilin University, Changchun 130012, P.R. China
Guang Zeng
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P.R. China
Xi-Shi Tai
Chemistry and Chemical and Environmental Engineering College, Weifang University, Weifang 261061, P.R. China

Corresponding Author(s) : Hai-Xing Liu

haixingliu@tom.com

Asian Journal of Chemistry, Vol. 25 No. 14 (2013): Vol 25 Issue 14

Abstract

Phosphorus vanadium heteropoly acid potassium: (K12P4V72O172)·24Cl·24(OH)·14.4(H2O), is prepared by the hydrothermal method. Cubic, Fm-3m. a = b = c = 21.866(2) Å a = b = g = 90º. V = 10454.6(17) Å3. Z = 2. R1 = 0.0479, wR2 = 0.1191. T = 291(2) K. The V atoms are linked with O atom bridge. It is striking that the structure of the phosphorus vanadium heteropoly acid potassium exhibits extensive hydrogen-bonding interactions.

Keywords

Heteropoly acid Structure analysis
Liu, H.-X., Liu, Q., Wang, L.-T., Guo, H.-M., Ye, K.-Q., Zeng, G., & Tai, X.-S. (2013). Synthesis and Crystal Structure of Phosphorus Vanadium Heteropoly Acid Potassium Compound: (K12P4V72O172)·24Cl·24(OH)·14.4H2O. Asian Journal of Chemistry, 25(14), 8217–8218. https://doi.org/10.14233/ajchem.2013.14607
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