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Bengal Gram Seed Husk an Adsorbent for Removal of Reactive Blue 25 Dye from Aqueous Solution
Corresponding Author(s) : U.B. Deshannavar
Asian Journal of Chemistry,
Vol. 28 No. 5 (2016): Vol 28 Issue 5
Abstract
Dyes are carcinogenic and toxic chemicals that affect aquatic life and human beings even at lower concentrations. Treatment of industrial effluents containing dyestuffs is therefore important for wastewater treatment engineers. In this study, batch adsorption experiments were conducted to study the adsorption of Reactive Blue 25 dye from aqueous solution using agricultural solid waste e.g., Bengal gram seed husk. The operating parameters are initial solution pH, initial dye concentration, adsorbent dosage and adsorbent-adsorbate contact time affecting dye adsorption were investigated. Experimental data were fitted to Langmuir and Freundlich isotherm models. Lagergren’s kinetic models were used to explain the adsorption kinetics and predict the theoretical adsorption capacity of adsorbent.
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- E. Clarke and R. Anliker, Organic Dyes and Pigments, The Handbook of Environmental Chemistry (Part A), Vol. 3, p. 81 (1980).
- G. Mishra and M.A. Tripathy, Colourage, 40, 35 (1993).
- S. Chakraborty, S. De, S. DasGupta and J.K. Basu, Chemosphere, 58, 1079 (2005); doi:10.1016/j.chemosphere.2004.09.066.
- H. Gao, T. Kan, S. Zhao, Y. Qian, X. Cheng, W. Wu, X. Wang and L. Zheng, J. Hazard. Mater., 261, 83 (2013); doi:10.1016/j.jhazmat.2013.07.001.
- U.J. Etim, S.A. Umoren and U.M. Eduok, J. Saudi Chem. Soc.; doi:10.1016/j.jscs.2012.09.014.
- V.K. Garg, R. Gupta, A.B. Yadav and R. Kumar, Bioresour. Technol., 89, 121 (2003); doi:10.1016/S0960-8524(03)00058-0.
- U.B. Deshannavar, G.M. Ratnamala, P.B. Kalburgi, M. El-Harbawi, A. Agarwal, M. Shet, M. Teli and P. Bhandare, Indian Chem. Eng.; doi:10.1080/00194506.2014.987831.
- G.M. Ratnamala, U.B. Deshannavar, S. Munyal, K. Tashildar, S. Patil and A. Shinde, Arab. J. Sci. Eng., doi:10.1007/s13369-015-1666-1.
- S. Chatterjee, A. Kumar, S. Basu and S. Dutta, Chem. Eng. J., 181–182, 289 (2012); doi:10.1016/j.cej.2011.11.081.
- 10 E.S.Z. El Ashtoukhy, J. Environ. Manage., 90, 2755 (2009); doi:10.1016/j.jenvman.2009.03.005 .
- N.K. Amin, Desalination, 223, 152 (2008); doi:10.1016/j.desal.2007.01.203.
- C.P. Kaushik, R. Tuteja, N. Kaushik and J.K. Sharma, Chem. Eng. J., 155, 234 (2009); doi:10.1016/j.cej.2009.07.042.
- K. Kadirvelu, M. Kavipriya, C. Karthika, M. Radhika, N. Vennilamani and S. Pattabhi, Bioresour. Technol., 87, 129 (2003); doi:10.1016/S0960-8524(02)00201-8.
- S. Irem, Q. Mahmood Khan, E. Islam, A. Jamal Hashmat, M. Anwar ul Haq, M. Afzal and T. Mustafa, Ecol. Eng., 58, 399 (2013); doi:10.1016/j.ecoleng.2013.07.005.
- Z. Aksu and I.A. Isoglu, J. Hazard. Mater., 137, 418 (2006); doi:10.1016/j.jhazmat.2006.02.019.
- M.E. Argun, D. Guclu and M. Karatas, J. Ind. Eng. Chem., 20, 1079 (2014); doi:10.1016/j.jiec.2013.06.045.
- H.N. Bhatti, N. Akhtar and N. Saleem, Arab. J. Sci. Eng., 37, 9 (2012); doi:10.1007/s13369-011-0158-1.
- L.B.L. Lim, N. Priyantha, C.M. Chan, D. Matassan, H.I. Chieng and M.R.R. Kooh, Arab. J. Sci. Eng., 39, 6757 (2014); doi:10.1007/s13369-014-1224-2.
- M.C. Somashekar Reddy, V. Nirmala and C. Ashwini, Arabian J. Chem.; doi:10.1016/j.arabjc.2013.09.029.
- APHA, Standard Methods for the Examination of Water and Wastewater, American Public Health Association, Washington, DC, edn 20 (1980).
- A.E. Ofomaja and Y.S. Ho, Bioresour. Technol., 99, 5411 (2008); doi:10.1016/j.biortech.2007.11.018.
- C. Namasivayam, D. Prabha and M. Kumutha, Bioresour. Technol., 64, 77 (1998); doi:10.1016/S0960-8524(97)86722-3.
- I. Langmuir, J. Am. Chem. Soc., 40, 1361 (1918); doi:10.1021/ja02242a004.
- H. Freundlich, Z. Phys. Chem. A, 57, 385 (1906).
- S. Lagergren, Kungliga Svenska Vetenskapsakademiens Handlingar, 24, 1 (1898).
- Y.S. Ho and G. Mckay, Process Biochem., 34, 451 (1999); doi:10.1016/S0032-9592(98)00112-5.
References
E. Clarke and R. Anliker, Organic Dyes and Pigments, The Handbook of Environmental Chemistry (Part A), Vol. 3, p. 81 (1980).
G. Mishra and M.A. Tripathy, Colourage, 40, 35 (1993).
S. Chakraborty, S. De, S. DasGupta and J.K. Basu, Chemosphere, 58, 1079 (2005); doi:10.1016/j.chemosphere.2004.09.066.
H. Gao, T. Kan, S. Zhao, Y. Qian, X. Cheng, W. Wu, X. Wang and L. Zheng, J. Hazard. Mater., 261, 83 (2013); doi:10.1016/j.jhazmat.2013.07.001.
U.J. Etim, S.A. Umoren and U.M. Eduok, J. Saudi Chem. Soc.; doi:10.1016/j.jscs.2012.09.014.
V.K. Garg, R. Gupta, A.B. Yadav and R. Kumar, Bioresour. Technol., 89, 121 (2003); doi:10.1016/S0960-8524(03)00058-0.
U.B. Deshannavar, G.M. Ratnamala, P.B. Kalburgi, M. El-Harbawi, A. Agarwal, M. Shet, M. Teli and P. Bhandare, Indian Chem. Eng.; doi:10.1080/00194506.2014.987831.
G.M. Ratnamala, U.B. Deshannavar, S. Munyal, K. Tashildar, S. Patil and A. Shinde, Arab. J. Sci. Eng., doi:10.1007/s13369-015-1666-1.
S. Chatterjee, A. Kumar, S. Basu and S. Dutta, Chem. Eng. J., 181–182, 289 (2012); doi:10.1016/j.cej.2011.11.081.
10 E.S.Z. El Ashtoukhy, J. Environ. Manage., 90, 2755 (2009); doi:10.1016/j.jenvman.2009.03.005 .
N.K. Amin, Desalination, 223, 152 (2008); doi:10.1016/j.desal.2007.01.203.
C.P. Kaushik, R. Tuteja, N. Kaushik and J.K. Sharma, Chem. Eng. J., 155, 234 (2009); doi:10.1016/j.cej.2009.07.042.
K. Kadirvelu, M. Kavipriya, C. Karthika, M. Radhika, N. Vennilamani and S. Pattabhi, Bioresour. Technol., 87, 129 (2003); doi:10.1016/S0960-8524(02)00201-8.
S. Irem, Q. Mahmood Khan, E. Islam, A. Jamal Hashmat, M. Anwar ul Haq, M. Afzal and T. Mustafa, Ecol. Eng., 58, 399 (2013); doi:10.1016/j.ecoleng.2013.07.005.
Z. Aksu and I.A. Isoglu, J. Hazard. Mater., 137, 418 (2006); doi:10.1016/j.jhazmat.2006.02.019.
M.E. Argun, D. Guclu and M. Karatas, J. Ind. Eng. Chem., 20, 1079 (2014); doi:10.1016/j.jiec.2013.06.045.
H.N. Bhatti, N. Akhtar and N. Saleem, Arab. J. Sci. Eng., 37, 9 (2012); doi:10.1007/s13369-011-0158-1.
L.B.L. Lim, N. Priyantha, C.M. Chan, D. Matassan, H.I. Chieng and M.R.R. Kooh, Arab. J. Sci. Eng., 39, 6757 (2014); doi:10.1007/s13369-014-1224-2.
M.C. Somashekar Reddy, V. Nirmala and C. Ashwini, Arabian J. Chem.; doi:10.1016/j.arabjc.2013.09.029.
APHA, Standard Methods for the Examination of Water and Wastewater, American Public Health Association, Washington, DC, edn 20 (1980).
A.E. Ofomaja and Y.S. Ho, Bioresour. Technol., 99, 5411 (2008); doi:10.1016/j.biortech.2007.11.018.
C. Namasivayam, D. Prabha and M. Kumutha, Bioresour. Technol., 64, 77 (1998); doi:10.1016/S0960-8524(97)86722-3.
I. Langmuir, J. Am. Chem. Soc., 40, 1361 (1918); doi:10.1021/ja02242a004.
H. Freundlich, Z. Phys. Chem. A, 57, 385 (1906).
S. Lagergren, Kungliga Svenska Vetenskapsakademiens Handlingar, 24, 1 (1898).
Y.S. Ho and G. Mckay, Process Biochem., 34, 451 (1999); doi:10.1016/S0032-9592(98)00112-5.