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Synthesis and Crystal Structure of o-Methoxyethyldithiocarbonato Nickel(II) Complex involving Tetramethylethylenediamine
Corresponding Author(s) : Adnan M. Qadir
Asian Journal of Chemistry,
Vol. 28 No. 5 (2016): Vol 28 Issue 5
Abstract
A new nickel(II) complex of type [Ni(xan)2(tmen)] (1) (xan = o-methoxyethyldithiocarbonate, tmen = tetramethylethylenediamine) has been synthesized and characterized by single crystal X-ray diffraction analysis. The compound crystallizes in orthorhombic space group Fdd2 with a = 13.956 (3), b = 38.342 (6), c = 8.1611 (12) Å, a = 90, b = 90, g = 90°, V = 4367.2(12) Å3, Z = 8, F(000) = 2016.0, Dc = 1.452 Mg/m3, μ = 1.291 mm-1. Ni(II) ion is in distorted octahedral geometry. The xanthate ligand acted as isobidentate.
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- O.V. Bakbardina, I.Y. Pukhnyarskaya, M.A. Gazalieva, S.D. Fazylov and E.M. Makarov, Russ. J. Appl. Chem., 79, 1726 (2006); doi:10.1134/S1070427206100375.
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- M.C. Gimeno, E. Jambrina, A. Laguna, M. Laguna, H.H. Murray and R. Terroba, Inorg. Chim. Acta, 249, 69 (1996); doi:10.1016/0020-1693(96)05027-X.
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References
O.V. Bakbardina, I.Y. Pukhnyarskaya, M.A. Gazalieva, S.D. Fazylov and E.M. Makarov, Russ. J. Appl. Chem., 79, 1726 (2006); doi:10.1134/S1070427206100375.
Neerupama, R. Sachar, N. Sambyal, K. Kapoor, K. Singh, V.K. Gupta and Rajnikant, Acta Chim. Slov., 60, 397 (2013).
B. Gupta, N. Kalgotra, S. Andotra and S.K. Pandey, Monatsh. Chem., 143, 1087 (2012); doi:10.1007/s00706-011-0704-2.
M. Scendo, Corros. Sci., 47, 1738 (2005); doi:10.1016/j.corsci.2004.08.015.
E. Amtmann, Drugs Exp. Clin. Res., 22, 287 (1996).
M. Perluigi, G. Joshi, R. Sultana, V. Calabrese, C. De Marco, R. Coccia and D.A. Butterfield, Neurosci., 138, 1161 (2006); doi:10.1016/j.neuroscience.2005.12.004.
S. Shahzadi, S. Ali, R. Jabeen and M.K. Khosa, Turk. J. Chem., 33, 307 (2009).
W. Friebolin, G. Schilling, M. Zöller and E. Amtmann, J. Med. Chem., 48, 7925 (2005); doi:10.1021/jm040899l.
M.C. Gimeno, E. Jambrina, A. Laguna, M. Laguna, H.H. Murray and R. Terroba, Inorg. Chim. Acta, 249, 69 (1996); doi:10.1016/0020-1693(96)05027-X.
F.H. Allen and O. Kennard, Chem. Des. Autom. News, 8, 31 (1993).
A.L. Johnson, M.S. Hill, G. Kociok-Köhn, K.C. Molloy and A.L. Sudlow, Inorg. Chem. Commun., 49, 8 (2014); doi:10.1016/j.inoche.2014.09.003.
G.M. Sheldrick, Acta Crystallogr. A, 64, 112 (2008); doi:10.1107/S0108767307043930.