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N-Arylation of Amines with o-Silylaryl Triflate
Corresponding Author(s) : D.I. Jung
dijung@dau.ac.kr
Asian Journal of Chemistry,
Vol. 25 No. 12 (2013): Vol 25 Issue 12
Abstract
An efficient, transition-metal-free procedure for the N-arylation of amines 1 has been achieved by allowing those substrates to react with o-silylaryl triflate 2 in the presence of CsF. Good to excellent yields of arylated products 3 are obtained under very mild reaction conditions. This chemistry readily tolerates a variety of functional groups.
Keywords
N-Arylation
o-Silylaryl triflate
CsF
Amines
Lee, Y., Jung, D., & Hahn, J. (2013). N-Arylation of Amines with o-Silylaryl Triflate. Asian Journal of Chemistry, 25(12), 6690–6692. https://doi.org/10.14233/ajchem.2013.14423
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