Extraction of Gelatin from Bovine Bone and its Use as Template in Synthesis of Mesoporous Silica

W. Trisunaryanti; P.S. Lisna; I. Kartini; Sutarno; I.I. Falah; Triyono

doi:10.14233/ajchem.2016.19561

Issue

Vol. 28 No. 5 (2016): Vol 28 Issue 5

Issue Published : January 30, 2016

This work is licensed under a Creative Commons Attribution 4.0 International License.

Extraction of Gelatin from Bovine Bone and its Use as Template in Synthesis of Mesoporous Silica

https://doi.org/10.14233/ajchem.2016.19561

W. Trisunaryanti

Department of Chemistry, Faculty of Mathematic and Natural Sciences, University of Gadjah Mada, Yogyakarta, Indonesia

P.S. Lisna

Department of Chemistry, University of Gadjah Mada, Yogyakarta, Indonesia

I. Kartini

Department of Chemistry, University of Gadjah Mada, Yogyakarta, Indonesia

Sutarno

Department of Chemistry, University of Gadjah Mada, Yogyakarta, Indonesia

I.I. Falah

Department of Chemistry, University of Gadjah Mada, Yogyakarta, Indonesia

Triyono

Department of Chemistry, University of Gadjah Mada, Yogyakarta, Indonesia

Corresponding Author(s) : W. Trisunaryanti

wegatri@yahoo.com

Asian Journal of Chemistry, Vol. 28 No. 5 (2016): Vol 28 Issue 5
Article Published : January 30, 2016

Abstract

Extraction of gelatin from bovine bone and its application as a template for synthesis of mesoporous silica have been studied. The bone was pretreated with acetic acid 4 % for 9 days, followed by sodium hydroxide 0.1 M for 24 h and hydrochloric acid 1 M for 1 h. The pretreated bovine bone was then refluxed in demineralized water for 5 h at 70, 80, 90 and 100 °C to extract gelatin. The gelatin was analyzed by FTIR and SDS-PAGE. The synthesis of mesoporous silica was performed by hydrothermal method. The product was analyzed by FT-IR, XRD, nitrogen gas adsorption and TEM. The result showed that the gelatin extracted at 80, 90 and 100 °C contained a and b-chains. However, the gelatin extracted at 70 °C contained only a-chains. The silica had pore diameter, specific surface area and pore volume of 6.08 nm, 384.21 m²/g and 0.75 cm³/g, respectively. The silica had wormhole-like mesoporous structure.

Keywords

Gelatin Bovine bone Mesoporous silica Wormhole-like structure

Trisunaryanti, W., Lisna, P., Kartini, I., Sutarno, ., Falah, I., & Triyono, . (2016). Extraction of Gelatin from Bovine Bone and its Use as Template in Synthesis of Mesoporous Silica. Asian Journal of Chemistry, 28(5), 996–1000. https://doi.org/10.14233/ajchem.2016.19561

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References

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References

G. Boran, S.J. Mulvaney and J.M. Regenstein, J. Food Sci., 75, 565 (2010); doi:10.1111/j.1750-3841.2010.01543.x.

J.H. Bowes, R.G. Elliott and J.A. Moss, Biochem. J., 61, 143 (1955); doi:10.1042/bj0610143.

B.H. Leuenberger, Food Hydrocoll., 5, 353 (1991); doi:10.1016/S0268-005X(09)80047-7.

P.J.A. Sobral and A.M. Habitante, Food Hydrocoll., 15, 377 (2001); doi:10.1016/S0268-005X(01)00060-1.

L. Niu, X. Zhou, C. Yuan, Y. Bai, K. Lai, F. Yang and Y. Huang, Food Hydrocoll., 33, 336 (2013); doi:10.1016/j.foodhyd.2013.04.014.

M.C. Gomez-guillœn and P. Montero, J. Food Sci., 66, 213 (2001); doi:10.1111/j.1365-2621.2001.tb11319.x.

P. Zhou and J.M. Regenstein, J. Food Sci., 70, C392 (2005); doi:10.1111/j.1365-2621.2005.tb11435.x.

X. Wang, G. Zhou, H. Zhang, S. Du, Y. Xu and C. Wang, J. Non-Cryst. Solids, 357, 3027 (2011); doi:10.1016/j.jnoncrysol.2011.04.009.

C.H. Hsu, H.P. Lin, C.Y. Tang and C.-Y. Lin, Stud. Surf. Sci. Catal., 165, 385 (2007); doi:10.1016/S0167-2991(07)80341-7.

X. Yang, S. Liao, Z. Liang, Y. Li and L. Du, Micropor. Mesopor. Mater., 143, 263 (2011); doi:10.1016/j.micromeso.2011.02.027.

Y. Wan and D. Zhou, Chem. Rev., 107, 2821 (2007); doi:10.1021/cr068020s.

E. Zelechowska, M. Sadowska and M. Turk, Food Hydrocoll., 24, 325 (2010); doi:10.1016/j.foodhyd.2009.10.010.

P.F. de Almeida, S.C. da Silva Lannes, F.A. Calarge, T.M. de Brito Farias and J.C.C. Santana, J. Chem. Eng., 6, 1029 (2012).

P. Kaewruang, S. Benjakul and T. Prodpran, Food Chem., 138, 1431 (2013); doi:10.1016/j.foodchem.2012.09.114.

M. Ahmad and S. Benjakul, Food Hydrocoll., 25, 381 (2011); doi:10.1016/j.foodhyd.2010.07.004.

J.H. Muyonga, C.G.B. Cole and K.G. Duodu, Food Chem., 86, 325 (2004); doi:10.1016/j.foodchem.2003.09.038.

I.J. Haug and K.I. Draget, in eds.: G.O. Phillips and P.A. Williams, Gelatin, In: Handbook of Hydrocolloids, Woodhead Publishing, Cambridge, edn 2 (2009).

H. Setyawan and R. Balgis, Asia-Pac. J. Chem. Eng., 7, 448 (2012); doi:10.1002/apj.593.

Issue

Vol. 28 No. 5 (2016): Vol 28 Issue 5

Extraction of Gelatin from Bovine Bone and its Use as Template in Synthesis of Mesoporous Silica

Corresponding Author(s) : W. Trisunaryanti

Abstract

Keywords

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