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Synthesis and Characterization of Antimicrobial Metal Based Polymeric Ligand Derived from 4,4'-Methylene-bis(furfuraldehyde)
Corresponding Author(s) : G. Zuhra Memon
Asian Journal of Chemistry,
Vol. 25 No. 11 (2013): Vol 25 Issue 11
Abstract
The present study examines synthesis of a new monomer, 4,4'-methylene-bis(furfuraldehyde), by a general method. The monomer was further condensed with a 1,3-propylenediamine in (1:1) molar ratio to yield a Schiff base polymer ligand poly(4,4'-methylene-bis(furfuraldehyde)-1,3-propylenediimine (PMBFPR). The monomer (MBF) was prepared by the reaction of furfuraldehyde with 1,3,5-trioxane in the presence of acetic acid. The Schiff base polymer (PMBFPR) was found to react readily with Cu(II) acetate monohydrate and Ni(II) acetate, yielding polymer metal complexes (PMBFPRCu) and (PMBFPRNi) respectively. The monomer (MBF), the polymer (PMBFPR) and the polymetal chelates, (PMBFPRCu) and (PMBFPRNi) were characterized by elemental micro analysis, FT-IR, 1H NMR, ultraviolet visible spectrophotometry, thermal analysis and viscosity measurements. The newly synthesized polymer and polymer metal complexes were screened against various microorganisms. For antibacterial activity Shigella flexneri, Micrococcus flavus, Staphylococcus aureus, Bacillus Cirroflgellosus, Escherichia Coli and for antifungal activity Candida albicans, A. Niger, Aspergillus flavus, were investigated by using 'agar well diffusion method'.
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- S. Banerjee, C. Saxena and P.K. Gutch, Eur. Polym. J., 32, 661 (1996).
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References
I.A. Kamal and A.A Khalaf, J. Appl. Polym. Sci., 77, 1218 (2000).
O. Catanescu, M. Grigoras, G. Cololin, A. Dobreanu, N. Hurduc and C.I. Simionescu, Eur. Polym. J., 37, 2213 (2001).
M. Grigoras, C.O. Catenescu and G. Colotin, Macromol. Chem. Phys., 202, 2262 (2001).
X. Luo, X. Wang, S. Wu and Y. Liang, J. Collid. Interf. Sci., 258, 432 (2003).
S. Destri, M. Pasini, C. Pelizzi, W. Porzio, G. Pridieri and C. Vignali, Macromolecules, 32, 353 (1999).
M. Cazacu, M. Marcu, A. Vlad, A. Toth and C. Racles, J. Polym. Sci. Part A, Polym. Chem., 41, 3169 (2003).
K. Naka, A. Azuma and Y. Chujo, Macromol. Rapid. Commun., 19, 523 (1998).
M.Y. Khuhawar, A.H. Channar and S.W. Shah, Eur. Polym. J., 34, 133 (1998).
M.Y. Khuhawar, M.A. Mughal and A.H. Channar, Eur. Polym. J., 40, 805 (2004).
M.Y. Khuhawar, A. Shah and M.A. Mughal, Chin. J. Polym. Sci., 25, 399 (2007).
S. Banerjee, C. Saxena and P.K. Gutch, Eur. Polym. J., 32, 661 (1996).
P.K. Gutch, S. Banerjee, D.C. Gupta and D.K. Jaiswal, J. Polym. Sci. Polym. Chem. Ed., 39, 383 (2001).
M.R. Maurya, A. Kumar, P. Manikandan and S. Chand, Appl. Catal. A, 277, 45 (2004).
R. Grunes and W. Sawondy, J. Chromatogr., 322, 63 (1985).
W. Li and M. Wan, J. Appl. Polym. Sci., 62, 941 (1996).
D.H. Sutaria, J.R. Patel and M.N. Patel, J. Indian Chem. Soc., 73, 309 (1996).
C.S. Marvell and N. Torkoy, J. Am. Chem. Soc., 79, 6000 (1957).
M.R. Filipovic, K. Duerr, M. Mojovic, V. Simeunovic, R. Zimmermann, V. Niketic and I. Ivanovic-Burmazovic, Angew. Chem. Int. Ed., 47, 8735 (2008).
K.I. Vilayetoglu and A.R. Topak, J. Appl. Polym. Sci., 85, 2002 (2004).
K.I. Demir and H.O. Vilayetoglu, Synth. Met., 126, 183 (2002).
R. Olar, M. Baded, E. Cristiana, V. Lazar, R. Cernat and C. Balotescu, J. Thermal. Anal. Calorim., 80, 451 (2005).
C.M. Sharaby, Spectrochim. Acta A, 66, 1271 (2007).
H.L. Singh, S. Varshney and A.K. Varshney, Appl. Organomet.Chem., 14, 212 (2000).