Issue

Vol. 25 No. 11 (2013): Vol 25 Issue 11

Copyright (c) 2013 AJC

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

A Novel Three-Dimensional Chiral Cadmium-Tartrate Compound: Hydrothermal Synthesis and Crystal Structures

https://doi.org/10.14233/ajchem.2013.14352
Guo-Dong Feng
Key Laboratory of Functional Coordination Compounds, Department of Chemistry and Chemical Engineering, Baoji University of Arts and Science, No. 1 Hi-Tech Avenue, Baoji 721013, Shaanxi Province, P.R. China
Luan Jiang
Key Laboratory of Functional Coordination Compounds, Department of Chemistry and Chemical Engineering, Baoji University of Arts and Science, No. 1 Hi-Tech Avenue, Baoji 721013, Shaanxi Province, P.R. China

Corresponding Author(s) : Guo-Dong Feng

fengguodong00805@163.com

Asian Journal of Chemistry, Vol. 25 No. 11 (2013): Vol 25 Issue 11

Abstract

One novel cadmium-tartrate compound exhibiting three-dimensional chiral structure, namely {[Cd3(TTA)3(H2O)](H2O)2}n (1) (H2TTA = tartaric acid), was obtained by the reactions of the cadmium salts with corresponding H2TTA under hydrothermal conditions and characterized by X-ray single-crystal diffraction and elemental analysis. The crystal belongs to the orthorhombic system, space group P212121 with a = 0.63507(8) nm, b = 1.7116(2) nm, c = 1.8492(2) nm, a = b = g = 90º, V = 2.0101(4) nm3, Dc = 2.717 g cm-3, Z = 4, F(000) = 1556, Goof = 1.033, R1 = 0.0326, wR2 = 0.0703. The compound 1 shows an interesting three-dimensional network with left helical chains. CCDC: 837585.

Keywords

Cadmium(II) polymer Crystal structure Tartaric acid
Feng, G.-D., & Jiang, L. (2013). A Novel Three-Dimensional Chiral Cadmium-Tartrate Compound: Hydrothermal Synthesis and Crystal Structures. Asian Journal of Chemistry, 25(11), 6270–6272. https://doi.org/10.14233/ajchem.2013.14352
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. O.M. Yaghi, M. O'Keeffe, N.W. Ockwig, H.K. Chae, M. Eddaoudi and J. Kim, Nature, 423, 705 (2003).
  2. P. Kanoo, K.L. Gurunatha and T.K. Maji, Cryst. Growth Design, 9, 4147 (2009).
  3. W.H. Wang, P.H. Xi, X.Y. Su, J.B. Lan, Z.H. Mao, J.S. You and R.G. Xie, Cryst. Growth Design, 7, 741 (2007).
  4. Y.J. Kim, M. Suh and D.Y. Jung, Inorg. Chem., 43, 245 (2004).
  5. N.L. Rosi, M. Eddaoudi, J. Kim, M. O'Keeffe and O.M. Yaghi, Angew. Chem. Int. Ed., 41, 284 (2002).
  6. C. Serre, F. Millange, C. Thouvenot, N. Gardant, F. Pelle and G. Ferey, J. Mater. Chem., 14, 1540 (2004).
  7. S. Thushari, J.A.K. Cha, H.H.Y. Sung, S.S.Y. Chui, A.L.F. Leung, Y.F. Yen and I.D. Williams, Chem. Commun., 44, 5515 (2005).
  8. T. Higashi, Program for Absorption Correction, Rigaku Corporation, Tokyo, Japan (1995).
  9. SHELXTL, Version 5.1, Siemens Industrial Automation, Inc. (1997).
  10. G.M. Sheldrick, SHELXL-97, Program for the Refinement of Crystal Structure, University of Göttingen, Germany (1997).
  11. H.X. Guo, Q.Y. Liu, L. Yang and W. Weng, Inorg. Chem. Commun., 11, 859 (2008).
  12. H.G. Yao, M. Ji, S.H. Ji, Y.S. Jiang, L. Li and Y.L. An,Inorg. Chem. Commun., 10, 440 (2007).
  13. Y. Wang, G.X. Liu and Y.C. Chen,Chin. J. Inorg. Chem., 28, 1084 (2009).
  14. Y. Wang, G. Liu, Y. Chen and K. Wang, Inorg. Chim. Acta, 363, 2668 (2010).
Read More
Author biographies is not available.
Download
PDF
Statistic
Read Counter : 0 Download : 0