Copyright (c) 2013 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Synthesis and Crystal Structure of a New Copper Complex: [Cu(Phen)(H2O)2SO4]
Corresponding Author(s) : Jing Hu
Asian Journal of Chemistry,
Vol. 25 No. 11 (2013): Vol 25 Issue 11
Abstract
A novel copper complex [Cu(Phen)(H2O)2SO4] was synthesized and characterized by IR spectra and single-crystal X-ray analysis. The crystal structure analysis shows that the Cu(II) has five coordinates in square-pyramid geometry. The complex forms bimolecular chains through hydrogen bonding interactions. In addition, an intermolecular p-p interaction is observed between the two parallel 1,10-phenanthroline rings of the neighboring molecules. The crystal is monoclinic and has space group C2/c with the following unit cell parameters: a = 14.9269(15) Å, b = 13.8821(13) Å, c = 7.0490(8) Å, a = 90º, b = 108.6190(10)º, g = 90º, V = 1384.2(2) Å3, Z = 4, Mr = 375.84, Dc = 1.803 Mg/cm3, μ = 1.760 mm-1, F(000) = 764, T = 298(2) K, R = 0.0358, wR = 0.0875 for 1220 reflections with I > 2s(I).
Keywords
Download Citation
Endnote/Zotero/Mendeley (RIS)BibTeX
- D.D. Li, F.P. Huang, G.J. Chen, C.Y. Gao, J.L. Tian, W. Gu, X. Liu and S.P. Yan, J. Inorg. Biochem., 104, 431 (2010).
- M.K. Paira, T.K. Mondal, E. López-Torres, J. Ribas and C. Sinha, Polyhedron, 29, 3147 (2010).
- X.L. Wang, Y.Q. Chen, G.C. Liu, J.X. Zhang, H.Y. Lin and B.K. Chen, Inorg. Chim. Acta, 363, 773 (2010).
- Z. Li, W.H. Chen, H.L. Wang, Q. Ding, H.W. Hou, J.M. Zhang, L.W. Mi and Z. Zheng, Mater. Lett., 65, 1785 (2011).
- Q.R. Cheng, H. Zhou, Z.Q. Pan and J.Z. Chen, Polyhedron, 30, 1171 (2011).
- H.Z. Dong, W.B. Tao, J.H. Bi, V. Milway, Z.Q. Xu, S.Y. Zhang, X.C. Meng, J. Li and M. Li, Nanoscale Res. Lett., 6, 484 (2011).
- S.S. Bhat, A.A. Kumbhar, H. Heptullah, A.A. Khan, V.V. Gobre, S.P. Gejji and V.G. Puranik, Inorg. Chem., 50, 545 (2011).
- K. Tschulik, C. Cierpka, A. Gebert, L. Schultz, C.J. Kähler and M. Uhlemann, Anal. Chem., 83, 3275 (2011).
- D.L. Reger, A. Debreczeni, B. Reinecke, V. Rassolov, M.D. Smith and R.F. Semeniuc, Inorg. Chem., 50, 4669 (2011).
- L. Tian and X.Y. Long, Chin. J. Struct. Chem., 19, 363 (2000).
- H. Masuda, T. Sugimori, A. Odani and O. Yamauchi, Inorg. Chim. Acta, 180, 73 (1991).
References
D.D. Li, F.P. Huang, G.J. Chen, C.Y. Gao, J.L. Tian, W. Gu, X. Liu and S.P. Yan, J. Inorg. Biochem., 104, 431 (2010).
M.K. Paira, T.K. Mondal, E. López-Torres, J. Ribas and C. Sinha, Polyhedron, 29, 3147 (2010).
X.L. Wang, Y.Q. Chen, G.C. Liu, J.X. Zhang, H.Y. Lin and B.K. Chen, Inorg. Chim. Acta, 363, 773 (2010).
Z. Li, W.H. Chen, H.L. Wang, Q. Ding, H.W. Hou, J.M. Zhang, L.W. Mi and Z. Zheng, Mater. Lett., 65, 1785 (2011).
Q.R. Cheng, H. Zhou, Z.Q. Pan and J.Z. Chen, Polyhedron, 30, 1171 (2011).
H.Z. Dong, W.B. Tao, J.H. Bi, V. Milway, Z.Q. Xu, S.Y. Zhang, X.C. Meng, J. Li and M. Li, Nanoscale Res. Lett., 6, 484 (2011).
S.S. Bhat, A.A. Kumbhar, H. Heptullah, A.A. Khan, V.V. Gobre, S.P. Gejji and V.G. Puranik, Inorg. Chem., 50, 545 (2011).
K. Tschulik, C. Cierpka, A. Gebert, L. Schultz, C.J. Kähler and M. Uhlemann, Anal. Chem., 83, 3275 (2011).
D.L. Reger, A. Debreczeni, B. Reinecke, V. Rassolov, M.D. Smith and R.F. Semeniuc, Inorg. Chem., 50, 4669 (2011).
L. Tian and X.Y. Long, Chin. J. Struct. Chem., 19, 363 (2000).
H. Masuda, T. Sugimori, A. Odani and O. Yamauchi, Inorg. Chim. Acta, 180, 73 (1991).