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Nanosized Ferric Hydroxide Catalyzed C-O Cross-Coupling of Phenol and Halides to Generate Phenoxy Ether
Corresponding Author(s) : Hongbin Sun
Asian Journal of Chemistry,
Vol. 25 No. 11 (2013): Vol 25 Issue 11
Abstract
The iron-based catalyst can effectively catalyze the phenolic hydroxyl C-O bond formation reaction to give the corresponding phenoxy ethers. The reaction of phenol and methyl chloroacetate, for example, gives phenoxy acetic acid methyl ester in 98 % yield under the optimal reaction conditions. Among the iron-based catalysts, nanosized ferric hydroxide prepared through sol-gel method gives the best catalytic activity.
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- D.A. Evans and J.L. Katz, Tetrahedron Lett., 39, 2937 (1998).
- R.A. Altman, A. Shafir and S.L. Buchwald, J. Org. Chem., 73, 284 (2008).
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References
D.A. Evans and J.L. Katz, Tetrahedron Lett., 39, 2937 (1998).
R.A. Altman, A. Shafir and S.L. Buchwald, J. Org. Chem., 73, 284 (2008).
B.J. Li, L. Xu and Z.H. Wu, J. Am. Chem. Soc., 131, 14656 (2009).
W. Liu, H. Cao and A. Lei, Angew. Chem. Int. Ed., 49, 2004 (2010).
H.W. Lee and S.C. Albert, Tetrahedron Lett., 50, 5868 (2009).
K. Swapna,A.V. Kumar and V.P. Reddy, J. Org. Chem., 74, 7514 (2009).
N. YoshiKai, A. Mieczkowski and A. Matsumoto, J. Am. Chem. Soc., 132, 5568 (2010).
D.M.T. Chan, K.L. Monaco, R.P. Wang and M.P. Winters, Tetrahedron Lett., 39, 2933 (1998).
R. Cao, X. Chen and W. Shen, Inorg. Chem. Ind., 43, 6 (2011) (In Chinese).
H. Liu, Y. Wei and Y. Sun, J. Mol. Catal. A, 226, 135 (2005).