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Surface Chemistry of Super-Hydrophilic SiO2-Doped TiO2 Photo-Catalysts for Self-Cleaning Glass
Corresponding Author(s) : Shui-Yang Lien
Asian Journal of Chemistry,
Vol. 25 No. 11 (2013): Vol 25 Issue 11
Abstract
The self-cleaning of glass surface can be enhanced by coating the photoinduced super-hydrophilic nanoporous thin film based on TiO2 photocatalysts via sol-gel process. In this article, a new method has been introduced to enhance the photocatalytic activity of TiO2 thin film, directly coated on the glass, developed by doping SiO2. The effects of post-annealing and the SiO2 content in TiO2 film on the photocatalytic activity were investigated. The microstructure and hydrophilic properties of the film were studied by using differential X-ray diffraction, field-emission scanning electron microscope. After illuminated by ultraviolet light, the SiO2 doped TiO2 film is super-hydrophilic with water contact angle less than 1º, this favours greatly the self-cleaning purpose of the glass surface.
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References
A. Fujishima and K. Honda, Nature, 238, 37 (1972).
T. Yui, Y. Mori, T. Tsuchino, T. Itoh, T. Hattori, A. Fukushima and K. Takagi, Chem. Mater., 206, 17 (2005).
J.G. Yu, Rare Metals, 289, 23 (2004).
B.S. Richards, Solar Energy Mater. Solar Cells, 79, 369 (2003).
K. Guan, Surf. Coat. Technol., 191, 155 (2005).
M. Houmard, D. Riassetto, F. Roussel, A. Bourgeois, G. Berthome, J.C. Joud and M. Langlet, Appl. Surf. Sci., 254, 1405 (2007).
S. Permpoon, M. Houmard, D. Riassetto, L. Rapenne, G. Berthome, B. Baroux, J.C. Joud and M. Langlet, Thin Solid Films, 516, 957 (2008).
T. Yuranova, R. Mosteo, J. Bandara, D. Laub and J. Kiwi, J. Mol. Catal. A, 244, 160 (2006).
L. Zhou, S. Yan, B. Tian, J. Zhang and M. Anpo, Mater. Lett., 60, 396 (2006).
Y.Y. Liu, L.Q. Qian, C. Guo, X. Jia, J.W. Wang and W.H. Tang, J. Alloys Comp., 479, 532 (2009).
M. Nakamura, M. Kobayashi, N. Kuzuya, T. Komatsu and T. Mochizuka, Thin Solid Films, 502, 121 (2005).
S.Y. Lien, D.S. Wuu, W.C. Yeh and J.C. Liu, Solar Energy Mater. Solar Cells, 90, 2710 (2006).
H. Kin, J.F. Yang, T. Sekino and S.W. Lee, Mater. Sci. Forum, pp. 620-622 (2009).
A. matsuda, Y. Kotani, T. Kogure, M. Tatsumisago and T. Minami, J. Am. Ceram. Soc., 83, 229 (2000).
G.H. Tian, H.G. Fu, L.Q. Jing and C.G. Tian, J. Hazard. Mater., 161, 1122 (2009).
T. Longenbach and Y. Gogotsi, Int. J. Appl. Glass Sci., 2, 108 (2011).