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Liquid Chromatographic Determination of Imazosulfuron in Food Commodity, Water and Soil Using Photo Diode Array Detector
Corresponding Author(s) : Shobha Sondhia
Asian Journal of Chemistry,
Vol. 28 No. 5 (2016): Vol 28 Issue 5
Abstract
An analytical procedure for detecting residues of a new herbicide imazosulfuron 1-(2-chloroimidazo[1,2-a]pyridin-3-ylsulfonyl)-3-(4,6-dimethoxy-2-pyrimidinyl)urea in soil, water, rice grains and straw by reversed-phase liquid chromatography method using various solvents and extraction methods was standardized. The best results were obtained when imazosulfuron fortified at 0.50 and 0.10 μg g-1 was extracted with acetonitrile:dichloromethane:ammonium hydroxide; ethyl acetate and acetonitrile:water solvent systems for soil, water and plant samples, respectively. The method makes use of Phenomenex C-18 (ODS) column (250 × 4.6 mm i.d.) and acetonitrile:water (70:30 v/v) as mobile phase and diode array detection at 230 nm. Recovery of imazosulfuron from water at 0.10 to 0.50 μg mL-1 was 80-94 %. Whereas it was 30-98 %, 70-90 % from soil and plant samples respectively. The retention time of imazosulfuron was found approximately 3.72 min.
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- H.M. Brown and J.C. Cotterman, in eds.: J. Stetter and W. Eding, Chemistry of Plant Protection-herbicides Inhibiting Branched Chain Amino Acid Biosynthesis, Springer-Verleg, Berlin, Germany, pp. 47-81 (1994)..
- T.R. Roberts, Metabolic Pathway of Agrochemicals, Part 1, Royal Society of Chemistry, Cambride, UK (1998).
- C.D.S. Tomlin, The Pesticide Manual, British Crop Council, Surrey, UK, edn 12 (2000).
- S. Sondhia, Environ. Monit. Assess., 137, 205 (2008); doi:10.1007/s10661-007-9741-z.
- S. Sondhia, B. Singhai, V.P. Singh and P. Verma, International Rice Research Congress, New Delhi, p. 555 (2006).
- Y. Akiyama, N. Yoshioka and M. Tsuji, Shokuhin Eiseigaku Zasshi, 43, 99 (2002); doi:10.3358/shokueishi.43.99.
- P. Morrica, F. Barbato, A. Giordano, S. Seccia and F. Ungaro, J. Agric. Food Chem., 48, 6132 (2000); doi:10.1021/jf000152d.
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- K. Mikata, F. Schnöder, C. Braunwarth, K. Ohta and S.I. Tashiro, J. Agric. Food Chem., 51, 177 (2003); doi:10.1021/jf025824+.
- P. Morrica, F. Barbato, S. Seccia and F. Ungaro, J. Agric. Food Chem., 49, 3816 (2001); doi:10.1021/jf010088f.
- A.G.S. Prado, E.M. Vieira and M.O.O. Rezende, J. Braz. Chem. Soc., 12, 485 (2001); doi:10.1590/S0103-50532001000400007.
- S. Hyun and L.S. Lee, J. Environ. Qual., 33, 1354 (2004); doi:10.2134/jeq2004.1354.
- J. Rouchaud, O. Neus and K. Cools, Bull. Environ. Contam. Toxicol., 64, 651 (2000); doi:10.1007/s001280000053.
- S. Sondhia, Geobios, 28, 140 (2001).
- E. Oleszewska, Acta Chromatogr., 4, 231 (2004).
- G. Ozhan, S. Ozden and B. Alpertunga, J. Environ. Health B, 40, 827 (2005); doi:10.1080/03601230500227517.
- T.S. Thompson and R.G. Treble, Bull. Environ. Contam. Toxicol., 57, 525 (1996); doi:10.1007/s001289900221.
- S. Sondhia, Toxicol. Environ. Chem., 91, 425 (2009); doi:10.1080/02772240802269096.
- S. Winrow, S. Hird and P. Brown, Food Addit. Contam., 20, 1064 (2003); doi:10.1080/02652030310001615159.
- S. Sondhia, U. Waseem and R.K. Varma, Chemosphere, 93, 2140 (2013); doi:10.1016/j.chemosphere.2013.07.066.
- S. Sondhia, Bull. Environ. Contam. Toxicol., 89, 1032 (2012); doi:10.1007/s00128-012-0804-7.
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References
H.M. Brown and J.C. Cotterman, in eds.: J. Stetter and W. Eding, Chemistry of Plant Protection-herbicides Inhibiting Branched Chain Amino Acid Biosynthesis, Springer-Verleg, Berlin, Germany, pp. 47-81 (1994)..
T.R. Roberts, Metabolic Pathway of Agrochemicals, Part 1, Royal Society of Chemistry, Cambride, UK (1998).
C.D.S. Tomlin, The Pesticide Manual, British Crop Council, Surrey, UK, edn 12 (2000).
S. Sondhia, Environ. Monit. Assess., 137, 205 (2008); doi:10.1007/s10661-007-9741-z.
S. Sondhia, B. Singhai, V.P. Singh and P. Verma, International Rice Research Congress, New Delhi, p. 555 (2006).
Y. Akiyama, N. Yoshioka and M. Tsuji, Shokuhin Eiseigaku Zasshi, 43, 99 (2002); doi:10.3358/shokueishi.43.99.
P. Morrica, F. Barbato, A. Giordano, S. Seccia and F. Ungaro, J. Agric. Food Chem., 48, 6132 (2000); doi:10.1021/jf000152d.
M. Ventriglia, P. Restani, P. Morrica, P. David, L. De Angelis and C.L. Galli, J. Chromatogr. A, 857, 327 (1999); doi:10.1016/S0021-9673(99)00730-X.
K. Mikata, F. Schnöder, C. Braunwarth, K. Ohta and S.I. Tashiro, J. Agric. Food Chem., 51, 177 (2003); doi:10.1021/jf025824+.
P. Morrica, F. Barbato, S. Seccia and F. Ungaro, J. Agric. Food Chem., 49, 3816 (2001); doi:10.1021/jf010088f.
A.G.S. Prado, E.M. Vieira and M.O.O. Rezende, J. Braz. Chem. Soc., 12, 485 (2001); doi:10.1590/S0103-50532001000400007.
S. Hyun and L.S. Lee, J. Environ. Qual., 33, 1354 (2004); doi:10.2134/jeq2004.1354.
J. Rouchaud, O. Neus and K. Cools, Bull. Environ. Contam. Toxicol., 64, 651 (2000); doi:10.1007/s001280000053.
S. Sondhia, Geobios, 28, 140 (2001).
E. Oleszewska, Acta Chromatogr., 4, 231 (2004).
G. Ozhan, S. Ozden and B. Alpertunga, J. Environ. Health B, 40, 827 (2005); doi:10.1080/03601230500227517.
T.S. Thompson and R.G. Treble, Bull. Environ. Contam. Toxicol., 57, 525 (1996); doi:10.1007/s001289900221.
S. Sondhia, Toxicol. Environ. Chem., 91, 425 (2009); doi:10.1080/02772240802269096.
S. Winrow, S. Hird and P. Brown, Food Addit. Contam., 20, 1064 (2003); doi:10.1080/02652030310001615159.
S. Sondhia, U. Waseem and R.K. Varma, Chemosphere, 93, 2140 (2013); doi:10.1016/j.chemosphere.2013.07.066.
S. Sondhia, Bull. Environ. Contam. Toxicol., 89, 1032 (2012); doi:10.1007/s00128-012-0804-7.
S. Sondhia, Pesticide Res. J., 19, 248 (2007).